An Introduction to Nonlinear Chemical Dynamics


Book Description

Just a few decades ago, chemical oscillations were thought to be exotic reactions of only theoretical interest. Now known to govern an array of physical and biological processes, including the regulation of the heart, these oscillations are being studied by a diverse group across the sciences. This book is the first introduction to nonlinear chemical dynamics written specifically for chemists. It covers oscillating reactions, chaos, and chemical pattern formation, and includes numerous practical suggestions on reactor design, data analysis, and computer simulations. Assuming only an undergraduate knowledge of chemistry, the book is an ideal starting point for research in the field. The book begins with a brief history of nonlinear chemical dynamics and a review of the basic mathematics and chemistry. The authors then provide an extensive overview of nonlinear dynamics, starting with the flow reactor and moving on to a detailed discussion of chemical oscillators. Throughout the authors emphasize the chemical mechanistic basis for self-organization. The overview is followed by a series of chapters on more advanced topics, including complex oscillations, biological systems, polymers, interactions between fields and waves, and Turing patterns. Underscoring the hands-on nature of the material, the book concludes with a series of classroom-tested demonstrations and experiments appropriate for an undergraduate laboratory.




Nonlinear Dynamics and Chaos


Book Description

This textbook is aimed at newcomers to nonlinear dynamics and chaos, especially students taking a first course in the subject. The presentation stresses analytical methods, concrete examples, and geometric intuition. The theory is developed systematically, starting with first-order differential equations and their bifurcations, followed by phase plane analysis, limit cycles and their bifurcations, and culminating with the Lorenz equations, chaos, iterated maps, period doubling, renormalization, fractals, and strange attractors.




Nonlinear Dynamics


Book Description

This book uses a hands-on approach to nonlinear dynamics using commonly available software, including the free dynamical systems software Xppaut, Matlab (or its free cousin, Octave) and the Maple symbolic algebra system. Detailed instructions for various common procedures, including bifurcation analysis using the version of AUTO embedded in Xppaut, are provided. This book also provides a survey that can be taught in a single academic term covering a greater variety of dynamical systems (discrete versus continuous time, finite versus infinite-dimensional, dissipative versus conservative) than is normally seen in introductory texts. Numerical computation and linear stability analysis are used as unifying themes throughout the book. Despite the emphasis on computer calculations, theory is not neglected, and fundamental concepts from the field of nonlinear dynamics such as solution maps and invariant manifolds are presented.




Introduction to Nonlinear Science


Book Description

The aim of this book is to develop a unified approach to nonlinear science, which does justice to its multiple facets and to the diversity and richness of the concepts and tools developed in this field over the years. Nonlinear science emerged in its present form following a series of closely related and decisive analytic, numerical and experimental developments that took place over the past three decades. It appeals to an extremely large variety of subject areas, but, at the same time, introduces into science a new way of thinking based on a subtle interplay between qualitative and quantitative techniques, topological and metric considerations and deterministic and statistical views. Special effort has been made throughout the book to illustrate both the development of the subject and the mathematical techniques, by reference to simple models. Each chapter concludes with a set of problems. This book will be of great value to graduate students in physics, applied mathematics, chemistry, engineering and biology taking courses in nonlinear science and its applications.




Perspectives of Nonlinear Dynamics: Volume 1


Book Description

The dynamics of physical, chemical, biological, or fluid systems generally must be described by nonlinear models, whose detailed mathematical solutions are not obtainable. To understand some aspects of such dynamics, various complementary methods and viewpoints are of crucial importance. In this book the perspectives generated by analytical, topological and computational methods, and interplays between them, are developed in a variety of contexts. This book is a comprehensive introduction to this field, suited to a broad readership, and reflecting a wide range of applications. Some of the concepts considered are: topological equivalence; embeddings; dimensions and fractals; Poincaré maps and map-dynamics; empirical computational sciences vis-á-vis mathematics; Ulam's synergetics; Turing's instability and dissipative structures; chaos; dynamic entropies; Lorenz and Rossler models; predator-prey and replicator models; FPU and KAM phenomena; solitons and nonsolitons; coupled maps and pattern dynamics; cellular automata.




Instabilities, Chaos and Turbulence


Book Description

This book is an introduction to the application of nonlinear dynamics to problems of stability, chaos and turbulence arising in continuous media and their connection to dynamical systems. With an emphasis on the understanding of basic concepts, it should be of interest to nearly any science-oriented undergraduate and potentially to anyone who wants to learn about recent advances in the field of applied nonlinear dynamics. Technicalities are, however, not completely avoided. They are instead explained as simply as possible using heuristic arguments and specific worked examples.




Chemical Oscillations, Waves, and Turbulence


Book Description

Tbis book is intended to provide a few asymptotic methods which can be applied to the dynamics of self-oscillating fields of the reaction-diffusion type and of some related systems. Such systems, forming cooperative fields of a large num of interacting similar subunits, are considered as typical synergetic systems. ber Because each local subunit itself represents an active dynamical system function ing only in far-from-equilibrium situations, the entire system is capable of showing a variety of curious pattern formations and turbulencelike behaviors quite unfamiliar in thermodynamic cooperative fields. I personally believe that the nonlinear dynamics, deterministic or statistical, of fields composed of similar active (Le., non-equilibrium) elements will form an extremely attractive branch of physics in the near future. For the study of non-equilibrium cooperative systems, some theoretical guid ing principle would be highly desirable. In this connection, this book pushes for ward a particular physical viewpoint based on the slaving principle. The dis covery of tbis principle in non-equilibrium phase transitions, especially in lasers, was due to Hermann Haken. The great utility of this concept will again be dem onstrated in tbis book for the fields of coupled nonlinear oscillators.




Chaos


Book Description

BACKGROUND Sir Isaac Newton hrought to the world the idea of modeling the motion of physical systems with equations. It was necessary to invent calculus along the way, since fundamental equations of motion involve velocities and accelerations, of position. His greatest single success was his discovery that which are derivatives the motion of the planets and moons of the solar system resulted from a single fundamental source: the gravitational attraction of the hodies. He demonstrated that the ohserved motion of the planets could he explained hy assuming that there is a gravitational attraction he tween any two ohjects, a force that is proportional to the product of masses and inversely proportional to the square of the distance between them. The circular, elliptical, and parabolic orhits of astronomy were v INTRODUCTION no longer fundamental determinants of motion, but were approximations of laws specified with differential equations. His methods are now used in modeling motion and change in all areas of science. Subsequent generations of scientists extended the method of using differ ential equations to describe how physical systems evolve. But the method had a limitation. While the differential equations were sufficient to determine the behavior-in the sense that solutions of the equations did exist-it was frequently difficult to figure out what that behavior would be. It was often impossible to write down solutions in relatively simple algebraic expressions using a finite number of terms. Series solutions involving infinite sums often would not converge beyond some finite time.




Nonlinear Dynamics with Polymers


Book Description

Closing a gap in the literature, this is the first comprehensive handbook on this modern and important polymer topic. Edited by highly experienced and top scientists in the field, this ready reference covers all aspects, including material science, biopolymers, gels, phase separating systems, frontal polymerization and much more. The introductory chapter offers the perfect starting point for the non-expert.




Introduction to Nonlinear Optical Effects in Molecules and Polymers


Book Description

Molecular Dynamics in Restricted Geometries Edited by Joseph Klafter and J. M. Drake This investigation of the chemistry and physics of complex systems focuses on the role of spatial restrictions on molecular movement. A practical source-book for researchers in chemical physics, chemical engineering, and condensed matter physics, and for graduate students in these fields, it covers a broad range of topics and critically evaluates methods as they are employed. Among the many topics it covers are: relaxation and diffusion in restricted geometries, excitation energy transfer and photoinduced electron transfer phenomena in some confined systems, electron excitation transport in micelles, polymers and multilayers, and electron excitation transport on polymer chains. 1989 (0 471-60176-4) 437 pp.