An Overview of Nickel Metal Hydride Battery Technology for Aerospace Applications


Book Description

For thirty years, the scientific community has investigated using intermetallic metal hydrides as hydrogen reservoirs and electrodes for secondary batteries. They are now replacing nickel-cadmium batteries in small electronics and may become attractive for aerospace applications. Metal hydride batteries do not require high-pressure containers, and prismatic cell designs are possible. With alloying, a wide range of operational temperatures can be achieved; however, large batteries require thermal control to dissipate and supply heat during high-rate charging and discharging. Recent investigations have concentrated on optimizing electrode capacity and cycle life by manipulating alloy compositions, microstructures, particle sizes, crystallinity, and surface chemistry. Despite intensive efforts, the discharge capacity of the metal hydrides has not improved beyond 250-400 mAh/g, and inherent deterioration processes apparently related to the formation of the hydride phase make metal hydrides unreliable choices for satellite applications demanding more than 500-2000 cycles. Additionally, the long-term effects of exposure of these materials to the potassium-hydroxide electrolyte during low-cycle, long-life missions is not known. This review surveys the status of research and commercial development of metal-hydride cells and evaluates the potential advantages and applications of metal-hydride batteries for aerospace use.




Overview of the Design, Development, and Application of Nickel-Hydrogen Batteries


Book Description

This document provides an overview of the design, development, and application of nickel-hydrogen (Ni-H2) battery technology for aerospace applications. It complements and updates the information presented in NASA RP-1314, NASA Handbook for Nickel- Hydrogen Batteries, published in 1993. Since that time, nickel-hydrogen batteries have become widely accepted for aerospace energy storage requirements and much more has been learned. The intent of this document is to capture some of that additional knowledge. This document addresses various aspects of nickel-hydrogen technology including the electrochemical reactions, cell component design, and selection considerations; overall cell and battery design considerations; charge control considerations; and manufacturing issues that have surfaced over the years that nickel-hydrogen battery technology has been the major energy storage technology for geosynchronous and low-Earth-orbiting satellites.Thaller, Lawrence H. and Zimmerman, Albert H.Glenn Research CenterNICKEL HYDROGEN BATTERIES; HYDROGEN; MANUFACTURING; TECHNOLOGY UTILIZATION; DESIGN ANALYSIS; ELECTRIC BATTERIES; EARTH ORBITS; AEROSPACE ENGINEERING; ENERGY STORAGE; HANDBOOKS




A Review of Nickel Hydrogen Battery Technology


Book Description

This paper on nickel hydrogen batteries is an overview of the various nickel hydrogen battery design options, technical accomplishments, validation test results and trends. There is more than one nickel hydrogen battery design, each having its advantage for specific applications. The major battery designs are individual pressure vessel (IPV), common pressure vessel (CPV), bipolar and low pressure metal hydride. State-of-the-art (SOA) nickel hydrogen batteries are replacing nickel cadmium batteries in almost all geosynchronous orbit (GEO) applications requiring power above 1 kW. However, for the more severe low earth orbit (LEO) applications (greater than 30,000 cycles), the current cycle life of 4000 to 10,000 cycles at 60 percent DOD should be improved. A NASA Lewis Research Center innovative advanced design IPV nickel hydrogen cell led to a breakthrough in cycle life enabling LEO applications at deep depths of discharge (DOD). A trend for some future satellites is to increase the power level to greater than 6 kW. Another trend is to decrease the power to less than 1 kW for small low cost satellites. Hence, the challenge is to reduce battery mass, volume and cost. A key is to develop a light weight nickel electrode and alternate battery designs. A common pressure vessel (CPV) nickel hydrogen battery is emerging as a viable alternative to the IPV design. It has the advantage of reduced mass, volume and manufacturing costs. A 10 Ah CPV battery has successfully provided power on the relatively short lived Clementine Spacecraft. A bipolar nickel hydrogen battery design has been demonstrated (15,000 LEO cycles, 40 percent DOD). The advantage is also a significant reduction in volume, a modest reduction in mass, and like most bipolar designs, features a high pulse power capability. A low pressure aerospace nickel metal hydride battery cell has been developed and is on the market. It is a prismatic design which has the advantage of a significant reduction in volume and a ...










Nickel-Metal Hydride Battery Technology Evaluation


Book Description

Available cylindrical and prismatic commercial Ni-MH batteries using AB5 and AB2 cathodes were evaluated for application to military aircraft batteries. Self discharge, capacity, and constant discharge and charge current tests were conducted along with some equipment limited internal resistance tests. Commercial AB5 technology is further advanced than AB2 technology and would require less development for near term (3-5 years) applications. Cylindrical and prismatic AB5 cells will require alloy, electrolyte and single cell/battery development to increase discharge and charge current capability to 10C and 5C respectively; and extend the low temperature limit to at least -20 deg C. Tested AB2 technology appears inadequate to meet the near term military requirements and would require a major advance in the alloy to overcome the irreversible capacity loss incurred at temperatures above 49 deg C. In addition, alloy, electrolyte and single cell/battery development would be needed to extend the low temperature limit by 30 degrees to at least -20 deg C, and to double the charge and quadruple the discharge current capabilities of this technology. p3.




Products and Services Catalog


Book Description




Nickel-hydrogen Batteries


Book Description

Nickel-hydrogen battery cells provide one of the longest-lived and most reliable rechargeable battery systems ever developed. The Aerospace Corporation was instrumental in the research, development, and testing of such batteries. Primarily developed for use in satellite and space power systems, their exceptionally long life was well worth the high cost associated with the technology, and they rapidly replaced most of the nickel-cadmium batteries used in earlier satellites. This book provides the reader with an in-depth view of nickel-hydrogen cell technology: how it was developed, how and why it works, how to implement it and realize its ultimate capability, and what can go wrong if it is not properly managed.