Applied Sonochemistry


Book Description

Power ultrasound has been used for many years in two specific industrial areas: cleaning and plastic welding. Over the last ten years an increasing interest has been shown in its potential for use over a much wider range of chemistry and processing which has been grouped together under the general title of sonochemistry. Most of these uses depend on the generation of acoustic cavitation in liquid media but this text, while underlining the importance of the physics and mathematics of cavitation, mainly concentrates on applications of the technology. After an introduction to the topic and some historical background to the uses of power ultrasound the general principles of acoustic cavitation are explored including some background physics, bubble dynamics and factors which influence cavitation. The remainder of the book incorporates a series of applications of sonochemistry which illustrate the types of physical and chemical effects of ultrasonically induced cavitation which will interest chemists and engineers alike. Amongst the major topics included are chemical synthesis, environmental protection and remediation of water, sewage and soils, polymer synthesis and processing, electrochemistry including both analytical and synthetic aspects and plating. The final chapter reviews the range of ultrasonic equipment available in the laboratory and the progress made towards the scale-up of sonochemistry. The level is introductory to semi-advanced and no topic has been taken to a particularly specialist level since it is intended that this should be of general interest to readers with a scientific background.




Sonochemistry


Book Description

There is an increasing interest in the exploitation of power ultrasound in chemistry and processing (sonochemistry). This text was written as a result of the many requests from potential sonochemists for a practical introduction to the topic.




Sonochemistry


Book Description

In the 1980’s sonochemistry was considered to be a rather restricted branch of chemistry involving the ways in which ultrasound could improve synthetic procedures, predominantly in heterogeneous systems and particularly for organometallic reactions. Within a few years the subject began to expand into other disciplines including food technology, environmental protection and the extraction of natural materials. Scientific interest grew and led to the formation of the European Society of Sonochemistry in 1990 and the launch of a new journal Ultrasonics Sonochemistry in 1994. The subject continues to develop as an exciting and multi-disciplinary science with the participation of not only chemists but also physicists, engineers and biologists. The resulting cross-fertilisation of ideas has led to the rapid growth of interdisciplinary research and provided an ideal way for young researchers to expand their knowledge and appreciation of the ways in which different sciences can interact. It expands scientific knowledge through an opening of the closed doors that sometimes restrict the more specialist sciences. The journey of exploration in sonochemistry and its expansion into new fields of science and engineering is recounted in "Sonochemistry Evolution and Expansion" written by two pioneers in the field. It is unlike other texts about sonochemistry in that it follows the chronological developments in several very different applications of sonochemistry through the research experiences of the two authors Tim Mason and Mircea Vinatoru. Designed for chemists and chemical engineers Written by two experts and practitioners in the subject Volume 1 covers the historical background and evolution of sonochemistry Volume 2 explains the wider applications and expansion of the subject VOLUME 1 Fundamentals and Evolution This volume traces the evolution of sonochemistry from the very beginning when the effects of acoustic cavitation were first reported almost as a scientific curiosity. The major developments of the subject from the 1980’s are described by the authors who became active participants in the field during that period. A chapter is devoted to ultrasonically assisted extraction (UAE) which illustrates the different ways in which sonochemical technologies can be applied in both batch and flow modes leading to the development of large-scale processing. The chapter on environmental protection shows the wide range of applications of sonochemistry in this important field for both biological and chemical decontamination.




Sonochemistry and Sonoluminescence


Book Description

Sonochemistry is studied primarily by chemists and sonoluminescence mainly by physicists, but a single physical phenomenon - acoustic cavitation - unites the two areas. The physics of cavitation bubble collapse, is relatively well understood by acoustical physicists but remains practically unknown to the chemists. By contrast, the chemistry that gives rise to electromagnetic emissions and the acceleration of chemical reactions is familiar to chemists, but practically unknown to acoustical physicists. It is just this knowledge gap that the present volume addresses. The first section of the book addresses the fundamentals of cavitation, leading to a more extensive discussion of the fundamentals of cavitation bubble dynamics in section two. A section on single bubble sonoluminescence follows. The two following sections address the new scientific discipline of sonochemistry, and the volume concludes with a section giving detailed descriptions of the applications of sonochemistry. The mixture of tutorial lectures and detailed research articles means that the book can serve as an introduction as well as a comprehensive and detailed review of these two interesting and topical subjects.




Introduction to Ultrasound, Sonochemistry and Sonoelectrochemistry


Book Description

This book provides an introduction to the fundamental and applied aspects of sonochemistry, discussing a number of basic concepts in sonochemistry, such as how ultrasonic waves interact with gas bubbles in liquids to generate cavitation, and how the high temperatures generated within cavitation bubbles could be estimated. It explains how redox radicals are produced and how to make use of both the physical and chemical forces generated during cavitation for various applications. Intended for academic researchers, industry professionals as well as undergraduate and graduate students, especially those starting on a new research topic or those new to the field, it provides a clear understanding of the concepts and methodologies involved in ultrasonic and sonochemistry.




Handbook on Applications of Ultrasound


Book Description

Ultrasonic irradiation and the associated sonochemical and sonophysical effects are complementary techniques for driving more efficient chemical reactions and yields. Sonochemistry—the chemical effects and applications of ultrasonic waves—and sustainable (green) chemistry both aim to use less hazardous chemicals and solvents, reduce energy consumption, and increase product selectivity. A comprehensive collection of knowledge, Handbook on Applications of Ultrasound covers the most relevant aspects linked to and linking green chemistry practices to environmental sustainability through the uses and applications of ultrasound-mediated and ultrasound-assisted biological, biochemical, chemical, and physical processes. Chapters are presented in the areas of: Medical applications Drug and gene delivery Nanotechnology Food technology Synthetic applications and organic chemistry Anaerobic digestion Environmental contaminants degradation Polymer chemistry Industrial syntheses and processes Reactor design Electrochemical systems Combined ultrasound−microwave technologies While the concepts of sonochemistry have been known for more than 80 years, in-depth understanding of this phenomenon continues to evolve. Through a review of the current status of chemical and physical science and engineering in developing more environmentally friendly and less toxic synthetic processes, this book highlights many existing applications and the enormous potential of ultrasound technology to upgrade present industrial, agricultural, and environmental processes.




Sonochemistry


Book Description

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.




Sonochemistry


Book Description

Traditionally heat and light are thought as energy sources to drive a particular chemical reaction, but now ultrasound is a promising energy source for this purpose. The collapse of a bubble generates a wide range of high temperatures and pressures, and therefore, use of ultrasound has a considerable potential in chemical and allied sciences. Ultrasound-assisted reactions are green and economically viable alternatives to conventional techniques. This new volume presents a complete picture of ultrasound-assisted reactions and technologies that can be used in organic synthesis, polymer synthesis and degradation, nanomaterials, wastewater treatment, food ingredients and products, pharmaceutical applications, bioenergy applications, and more. This volume aims to shed light on the diversified applications of ultrasound and its significant role as a green chemical pathway. Sonochemistry deals with the effect of ultrasonic waves on chemical systems. It has green value because of non-hazardous acoustic radiation and is therefore duly recognized as a green chemistry by synthetic chemists as well as environmentalists. There is no direct interaction of ultrasound with molecular species, but the observed chemical and physical effects of ultrasound are due to the cavitational collapse, which produces drastic conditions of temperature and pressure locally. It induces the formation of various chemical species, which cannot be easily attained under conventional conditions. Sometimes, these species are responsible for driving towards an unusual reactivity in molecular entities. This book, Sonochemistry: An Emerging Green Technology, provides the complete development of sonochemistry, starting with an introduction and basic concepts of sonochemistry and proceeding on to different types of sonochemical reactions, instrumentation, use of ultrasound in driving particular chemical reactions, and its applications in various fields, such as polymer synthesis, decontamination of water and wastewater, preparation of nanomaterials, food technology, pharmaceutical sciences, etc. The book also briefly discusses some areas that utilize ultrasounds of different frequencies. These include food products and their processing; anaerobic digestion of waste; and medical applications such as ultrasonography, sonodynamic therapy, drug delivery, etc. Sonochemistry will be successfully used on an industrial scale in pharmaceutical drugs, polymers, nanomaterials, food technology, material science, biogas production, etc. in years to come and will be an established green chemical technology of the future.




Advances in Sonochemistry


Book Description

Ultrasound in Environmental Protection focuses on one of the more significant developments in the subject - environmental remediation - providing an overview on both the fundamentals and applications of ultrasound in environmental protection, incorporating recent research and state-of-the-art information on the scientific basis, modes of use, and engineering developments. A broad spectrum of topics are covered: reactor design, sonochemical pollutant degradation, integrated unltrasonic/ biological treatment, ultrasound in disinfection, leaching by ultrasound, and ultrasonically enhanced removal of suspended solids.Ultrasound is generated and applied at frequencies from 20 kHz to several MHz. The physio-chemical parameters of the sonicated media, reactor design, applied intensity, and duration of sonication, dramatically influence the effects that can be achieved. It is hoped that this compilation will contribute to a better understanding and further development of sonochemistry as a clean technology not only for environmental remediation but also more generally.The foundation of this compilation was formed during a workshop that was held at the Technical University of Hamburg-Harburg, Germany, in March 1999. This was the first workshop to be devoted to 'Ultrasound in Environmental Engineering' and brought together experience and knowledge from a broad spectrum of disciplines including chemistry, biology, engineering, equipment manufacturing, and plant design.




Organic Sonochemistry


Book Description

This book provides informative, useful, and stimulating reading on the topic of organic sonochemistry – the core of ultrasound-based applications. Given the increasing interest in new and improved technologies, allied to their green and sustainable character (not always a valid premise), there is a great attraction for organic chemists to apply these protocols in synthesis and process chemistry. Unfortunately, as with other enabling technologies, many researchers new to the field have received a simple and dishonest message: just switch on! Therefore a significant portion of sonochemical syntheses lack reproducibility (surprisingly cavitation control and/or ultrasonic parameters are omitted) and the actual role of sonication remains uncertain. While this book does not provide a detailed description of fundamentals, the introductory remarks highlight the importance of cavitational effects and their experimental control. It presents a number of concepts of sonochemical reactivity and empirical rules with pertinent examples, often from classical and recent literature. It then focuses on scenarios of current interest where organic chemistry, and synthesis in particular, may benefit from sonication in terms of both chemical and mechanical activation. The “sustainable corner” of this field is largely exemplified through concepts like atom economy, renewable sources, wasteless syntheses, and benign solvents as reaction media. This book is useful for both researchers and graduate students, especially those familiar with the field of sonochemistry and applications of ultrasound in general. However, it is also of interest to a broader audience as it discusses the fundamentals, techniques, and experimental skills necessary for scientists wishing to initiate the use of ultrasound in their domain of expertise.