Atom Resolved Surface Reactions


Book Description

This book offers a unique perspective of the impact of scanning probe microscopies on our understanding of the chemistry of the surface at the nanoscale. Research oriented, with the concepts gleaned from Scanning Tunnelling Microscopy being related to the more established and accepted views in surface chemistry and catalysis the authors have addresses the question "How do the models based on classical spectroscopic and kinetic studies stand up to scrutiny at the atom - resolved level?". In taking this approach the reader, new to the field of surface chemistry, should be able to obtain a perspective on how the evidence from STM confirms or questions long standing tenets. An emphasis is given to "how did we get to where we are now" and a large number of figures from the literature are included along with suggestions for further reading. Topics discussed include: - the dynamics of oxygen chemisorption at metal surfaces - control of oxygen states and surface reconstruction - dissociative chemisorption of diatomic and hydrocarbon molecules - nanoparticles and chemical reactivity - STM at high pressures - structural studies of sulfur containing molecules and molecular templating This book will appeal to all those who wish to become familiar with the contribution Scanning Tunnelling Microscopy has made to the understanding of the field of surface chemistry and heterogeneous catalysis and also to those who are new to catalysis, a fascinating and important area of chemistry.




Phase Transitions and Adsorbate Restructuring at Metal Surface


Book Description

The objective in initiating this series in 1980 was to provide an in-depth review of advances made in the understanding key aspects of surface chemistry and physics through the application of new techniques to the study of well-defined surfaces. Since then the field of surface science has greatly matured, and further important techniques, particularly scanning probe microscopies, have been successfully assimilated into the applications armoury of the surface scientist. The present volume is a series of timely reviews by many of the current experts in the field of phase transitions and adsorbate-induced surface restructuring. No aspect of the science of solid surfaces can be fully understood without accounting for the structural diversity of surfaces, now revealed in atomic detail by techniques based on diffraction and scanning probe microscopies. For example, it is now clear to those working in heterogeneous catalysis that adsorbate-induced restructuring of surfaces can play a critical role in phenomena such as bistability, kinetic oscillations, and promotion and poisoning. Structural transitions at surfaces can also play a key role in determining the electronic properties of surfaces, reviewed in volume 5.




Highlights in Condensed Matter Physics and Future Prospects


Book Description

This volume contains the proceedings of the first NATO Science Forum "Highlights of the Eighties and Future Prospects in Condensed Matter Physics" (sponsored by the NATO Scientific Affairs Division), which took place in September, 1990, in the pleasant surroundings provided by the Hotel du Palais at Biarritz, France. One hundred distinguished physicists from seventeen countries, including six Nobellaureates, were invited to participate in the four and a half day meeting. Focusing on three evolving frontiers: semiconductor quantum structures, including the subject of the quantumHall effect (QHE), high temperature superconductivity (HiTc) and scanning tunneling microscopy (STM), the Forum provided an opportunity to evaluate, in depth, each of the frontiers, by reviewing the progress made during the last few years and, more importantly, exploring their implications for the future. Though serious scientists are not "prophets," all of the participants showed a strong interest in this unique format and addressed the questions of future prospects, either by extrapolating from what has been known, or by a stretch of their "educated" imagination.




Physics Of Semiconductors - Proceedings Of The 20th International Conference (In 3 Volumes)


Book Description

Gathering top experts in the field, the 20th ICPS proceedings reviews the progress in all aspects of semiconductor physics. The proceedings will include state-of-the-art lectures with special emphasis on exciting new developments. It should serve as excellent material for researchers in this and related fields.




Advances in Catalysis


Book Description

Surface science emerged in the 1960s with the development of reliable ultrahigh vacuum apparatus, providing exact structures of surfaces of metal single crystals, information about their compositions, and relationships between surface structure and composition and catalytic reaction rates. Catalysis, the acceleration of a chemical reaction by a catalyst (substance), provided much of the driving force for the early development of surface science. As surface science continues its rapid development, this book illustrates how it is still driven by the challenges of catalysis and how both theory and scanning tunneling microscopy have forcefully emerged as essential tools. It is also evident how surface science continues to serve as the foundation of catalytic science. This is a compendium written by leading surface scientists presenting an incisive assessment of up-to-date theoretical and experimental results constituting the foundation of fundamental understanding of surface catalysis. This paperback.




Chemistry and Physics of Solid Surfaces VIII


Book Description

This volume contains review articles written by the invited speakers at the ninth International Summer Institute in Surface Science (ISISS 1989), held at the Uni versity of Wisconsin-Milwaukee in August of 1989. During the course of ISISS, invited speakers, all internationally recognized experts in the various fields of surface science, present tutorial review lectures. In addition, these experts are asked to write review articles on their lecture topic. Former ISISS speakers serve as advisors concerning the selection of speakers and lecture topics. Emphasis is given to those areas which have not been covered in depth by recent Summer Institutes, as well as to areas which have recently gained in significance and in which important progress has been made. Because of space limitations, no individual volume of Chemistry and Physics of Solid Surfaces can possibly cover the whole area of modern surface science, or even give a complete survey of recent progress in this field. However, an attempt is made to present a balanced overview in the series as a whole. With its comprehensive literature references and extensive subject indices, this series has become a valuable resource for experts and students alike. The collected articles, which stress particularly the gas-solid interface, have been published under the following titles: Surface Science: Recent Progress and Perspectives, Crit. Rev. Solid State Sci.




Principles and Practice of Heterogeneous Catalysis


Book Description

This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved.




Fundamentals of Picoscience


Book Description

Now ubiquitous in public discussions about cutting-edge science and technology, nanoscience has generated many advances and inventions, from the development of new quantum mechanical methods to far-reaching applications in electronics and medical diagnostics. Ushering in the next technological era, Fundamentals of Picoscience focuses on the instrumentation and experiments emerging at the picometer scale. One picometer is the length of a trillionth of a meter. Compared to a human cell of typically ten microns, this is roughly ten million times smaller. In this state-of-the-art book, international scientists and researchers at the forefront of the field present the materials and methods used at the picoscale. They address the key challenges in developing new instrumentation and techniques to visualize and measure structures at this sub-nanometer level. With numerous figures, the book will help you: Understand how picoscience is an extension of nanoscience Determine which experimental technique to use in your research Connect basic studies to the development of next-generation picoelectronic devices The book covers various approaches for detecting, characterizing, and imaging at the picoscale. It then presents picoscale methods ranging from scanning tunneling microscopy (STM) to spectroscopic approaches at sub-nanometer spatial and energy resolutions. It also covers novel picoscale structures and picometer positioning systems. The book concludes with picoscale device applications, including single molecule electronics and optical computers. Introductions in each chapter explain basic concepts, define technical terms, and give context to the main material.




Surface and Interface Science, Volumes 1 and 2


Book Description

Covering interface science from a novel surface science perspective, this unique handbook offers a comprehensive overview of this burgeoning field. Eight topical volumes cover basic concepts and methods, elemental and composite surfaces, solid-gas, solid-liquid and inorganic biological interfaces, as well as applications of surface science in nanotechnology, materials science and molecular electronics. With its broad scope and clear structure, it is ideal as a reference for scientists in the field, as well as an introduction for newcomers.