Atomic Absorption Spectrometry in Geology


Book Description

Atomic Absorption Spectrometry in Geology focuses on the applications of atomic absorption spectrometry in geology, including the analysis of metals, rocks, sediments, and minerals. The manuscript first offers information on the theory of atomic absorption spectrophotometry and instrumentation. Discussions focus on the relationship of atomic absorption with atomic concentration; variations in shapes and widths of atomic spectral lines; variations in atomic spectral lines; sample vaporization; and light sources. The book then examines interferences, including spectral, ionization, chemical, and molecular interferences. The publication takes a look at hydrogeochemistry and ore analysis. Topics include freshwater and seawater, zinc and cadmium, mercury, silver, gold, copper, lead, and nickel. The text also ponders on rock and mineral analysis, sediments, isotopes and noble gases, as well as silicate and sulfide minerals, organic fraction of sediments, and lithium, uranium, boron, and mercury isotopes. The manuscript is a dependable reference for readers interested in atomic absorption spectrometry.




Applied Atomic Spectroscopy


Book Description

From the first appearance of the classic The Spectrum Analysis in 1885 to the present the field of emission spectroscopy has been evolving and changing. Over the last 20 to 30 years in particular there has been an explosion of new ideas and developments. Of late, the aura of glamour has supposedly been transferred to other techniques, but, nevertheless, it is estimated that 75% or more of the analyses done by the metal industry are accomplished by emission spectroscopy. Further, the excellent sensitivity of plasma sources has created a demand for this technique in such divergent areas as direct trace element analyses in polluted waters. Developments in the replication process and advances in the art of pro ducing ruled and holographic gratings as well as improvements in the materials from which these gratings are made have made excellent gratings available at reasonable prices. This availability and the development of plane grating mounts have contributed to the increasing popularity of grating spectrometers as com pared with the large prism spectrograph and concave grating mounts. Other areas of progress include new and improved methods for excitation, the use of controlled atmospheres and the extension of spectrometry into the vacuum region, the widespread application of the techniques for analysis of nonmetals in metals, the increasing use of polychrometers with concave or echelle gratings and improved readout systems for better reading of spectrographic plates and more efficient data handling.




CRC Handbook of Furnace Atomic Absorption Spectroscopy


Book Description

This book addresses Furnace Atomic Absorption Spectroscopy (FAAS), which has gained worldwide acceptance as an analytical technique. FAAS offers 100-1000 times better determination and detection limits than other techniques for a majority of the elements. This technique requires a small sample size, and demands less sample-preparation time than others. The handbook is a collection of thousands of references for detection and determination of various elements in agricultural products, biological and clinical samples, and metallurgical and electronic materials. Each chapter is devoted to an element or a similar group of elements. Included are instrumental setup parameters, references, and author and subject indexes. Also presented are detailed appendixes covering glossary, list of manufacturers of spectrophotometers and its accessories, list of chemical suppliers, and list of reviews and abstracts. The handbook covers topics such as heavy metals, clinical products, and trace metal analysis. This desk-top reference is meant for chemists who handle day-to-day analysis problems in laboratories in government, clinical, industrial and academic settings. It is invaluable for those involved in research in environmental science, analytical chemistry, clinical chemistry and forensic science.







Modern Methods of Geochemical Analysis


Book Description

The founders of geology at the beginning of the last century were suspicious oflaboratories. Hutton's well-known dictum illustrates the point: "There are also superficial reasoning men . . . they judge of the great oper ations of the mineral kingdom from having kindled a fire, and looked into the bottom of a little crucible. " The idea was not unreasonable; the earth is so large and its changes are so slow and so complicated that labo ratory tests and experiments were of little help. The earth had to be studied in its own terms and geology grew up as a separate science and not as a branch of physics or chemistry. Its practitioners were, for the most part, experts in structure, stratigraphy, or paleontology, not in silicate chemistry or mechanics. The chemists broke into this closed circle before the physicists did. The problems of the classification of rocks, particularly igneous rocks, and of the nature and genesis of ores are obviously chemical and, by the mid- 19th century, chemistry was in a state where rocks could be effectively analyzed, and a classification built up depending partly on chemistry and partly on the optical study of thin specimens. Gradually the chemical study of rocks became one of the central themes of earth science.







CRC Handbook of Furnace Atomic Absorption Spectroscopy


Book Description

This book addresses Furnace Atomic Absorption Spectroscopy (FAAS), which has gained worldwide acceptance as an analytical technique. FAAS offers 100-1000 times better determination and detection limits than other techniques for a majority of the elements. This technique requires a small sample size, and demands less sample-preparation time than others. The handbook is a collection of thousands of references for detection and determination of various elements in agricultural products, biological and clinical samples, and metallurgical and electronic materials. Each chapter is devoted to an element or a similar group of elements. Included are instrumental setup parameters, references, and author and subject indexes. Also presented are detailed appendixes covering glossary, list of manufacturers of spectrophotometers and its accessories, list of chemical suppliers, and list of reviews and abstracts. The handbook covers topics such as heavy metals, clinical products, and trace metal analysis. This desk-top reference is meant for chemists who handle day-to-day analysis problems in laboratories in government, clinical, industrial and academic settings. It is invaluable for those involved in research in environmental science, analytical chemistry, clinical chemistry and forensic science.




Acoustic and Elastic Wave Fields in Geophysics


Book Description

This book is a continuation of 'Acoustic and Elastic Wave Fields in Geophysics, Part I' published in 2000. The second volume is dedicated to propagation of linear plane, spherical and cylindrical acoustic waves in different media. Chapter 1 is devoted to principles of geometric acoustic in plane wave approximation. The eikonal and transport equations are derived. Ray tracing and wavefront construction techniques are explained. Chapter 2 deals with dynamic properties of wave fields. The behavior of pressure and displacements amplitudes in zero approximation is analysed in two ways: using Poynting vector and solving the transport equation. This chapter contains several examples related to shadow zones and caustics. In Chapter 3 using the results of analysis of high-frequency wave kinematics and dynamics some fundamental aspects of Kirchhoff migration are described. Chapters 4 and 5 are devoted to propagation of plane waves in media with flat boundaries in the case of normal and oblique incidence. Special attention is paid to the case when an incident angle exceeds the critical angles. Formation of normal modes in the waveguide is discussed. Chapter 6 deals with a spherical wave reflection and refraction. The steepest descent method is introduced to describe the behavior of reflected, transmitted, head and evanescent waves. In Chapter 7 propagation of stationary and transient waves in a waveguide formed by a flat layer with low velocity are investigated. Normal modes and waves related to the branch points of integrands under consideration are studied. Dispersive properties of normal modes are discussed. Chapter 8 describes wave propagation inside cylinder in acoustic media. Several appendices are added to help the reader understand different aspects of mathematics used in the book.