Atomic Mechanisms of Flow and Fracture at Metal-Ceramic Interfaces and Their Role in the Design of Metal Matrix Composites


Book Description

This report describes new and significant results that can be applied in the microstructure design for optimum mechanical performance of metal-ceramic composites and laminates. There are three elements to these recommendations: (1) the design of the atomic structure of metal-ceramic interfaces, (2) identification of the critical length scale in the two phase microstructure, and (3) prediction of the microstructural conditions under which the thermal conductivity of the composite becomes significantly influenced by the thermal boundary resistance of interfaces. In the first topic we show that the beneficial effect of titanium interlayers at a copper/alumina interface is accomplished with only about one monolayer; with further increase in the titanium interlayer thickness having an insignificant effect on the interfacial strength. In the second topic we show that the metal ligament size is the key microstructural parameter in controlling the flow stress, the fracture stress and the fracture toughness of metal-ceramic composites. The metal ligament size is important because dislocation activity in the metal, which produces pile ups against the interface, is the critical event in flow and fracture of composites. In the third area we show that the interfacial thermal boundary resistance plays a dominant role in the overall thermal conductivity of the composite when the microstructural scale becomes smaller than about 1um.




Metal-Ceramic Interfaces


Book Description

As engineering materials and structures often contain a metal or metallic alloy bonded to a ceramic, the resultant interface must be able to sustain mechanical forces without failure. They also play an important role in oxidation or reduction of materials. The workshop on 'Bonding, Structure and Mechanical Properties of Metal/Ceramic Interfaces' was held in January 1989 within the Acta/Scripta Metallurgica conference series. It drew together an international collection of 70 scientists who discussed a wide range of issues related to metal-ceramic interfaces. The sessions were divided into 7 categories: structure and bonding, chemistry at interfaces, formation of interfaces, structure of interfaces, thermodynamics/atomistics of interface fracture, mechanics of interface cracks, and fracture resistance of bimaterial interfaces. Within these headings attention was paid to grain boundaries, the influence of chemical processes on the behaviour of interfaces, diffusion bonding, characterization of fracture, and crack propagation by fatigue and by stress corrosion. The book presents a useful reference source for materials scientists, physicists, chemists, and mechanical engineers who are concerned with the roles and properties of interfaces.




Surfaces and Interfaces in Ceramic and Ceramic — Metal Systems


Book Description

The 17th University Conference on Ceramics, which also was the 7th LBL/MMRD International Materials Symposium, was held on the campus of the University of California at Berkeley from July 28 to August 1, 1980. It was devoted to the subject of surfaces and interfaces in ceramic and ceramic-metal systems. The program was timely and of great interest, as indicated by the large number of contributed papers, which included contributions from ten foreign countries. These proceedings are divided into the following categories dealing with the chemistry and physics of interfaces: calculations of interface/surface states, characterization of surfaces and inter faces, thermodynamics of interfaces, influence of surface and inter faces on selected ceramic processes, grain boundary structures, effects of grain boundaries on deformation and fracture, interfacial phenomena, formation of interfaces, development of adhesion, and reactions at interfaces. A number of papers deal specifically with the Si-Si02 interface, which probably has received more attention than any other because of its importance in the electronics industry. This coverage fulfills the principal objective of the symposium which was to explore and assess the current fundamental understand ing of interfaces and surfaces. A parallel objective of the symposium was fulfilled by a group of papers dealing with the correlation of interfacial characteris tics with mechanical behavior. This group includes papers dealing with the adherence of dissimilar materials at interfaces.







Nonlinear Behavior of Ceramic-Matrix Composites


Book Description

Nonlinear Damage Behavior of Ceramic Matrix Composites help readers [researchers, material scientists and design engineers] gain greater understanding on the damage mechanisms inside CMCs so they can better design components used in aeronautics and astronautics. Key areas addressed in the book include: the nonlinear damage behavior of ceramic-matrix composites, including damage mechanisms and models, nonlinear damage behavior of ceramic-matrix composites under tensile and fatigue loading, strain-rate dependent, stochastic loading dependent, and time dependent nonlinear damage behavior, and the effect of pre-exposure and thermal fatigue on non-linear damage behavior of ceramic-matrix composites. - Provides comprehensive coverage on damage mechanisms and models under tensile and cyclic fatigue loading which ultimately control nonlinear behavior - Covers nonlinear damage analyses of CMC components and experimental observations of damage evolution - Presents extensive knowledge on fracture mechanic principles used in the design of aerospace propulsion systems




Time-Dependent Mechanical Behavior of Ceramic-Matrix Composites at Elevated Temperatures


Book Description

This book investigates the time-dependent behavior of fiber-reinforced ceramic-matrix composites (CMCs) at elevated temperatures. The author combines the time-dependent damage mechanisms of interface and fiber oxidation and fracture with the micromechanical approach to establish the relationships between the first matrix cracking stress, matrix multiple cracking evolution, tensile strength, tensile stress-strain curves and tensile fatigue of fiber-reinforced CMCs and time. Then, using damage models of energy balance, the fracture mechanics approach, critical matrix strain energy criterion, Global Load Sharing criterion, and hysteresis loops he determines the first matrix cracking stress, interface debonded length, matrix cracking density, fibers failure probability, tensile strength, tensile stress-strain curves and fatigue hysteresis loops. Lastly, he predicts the time-dependent mechanical behavior of different fiber-reinforced CMCs, i.e., C/SiC and SiC/SiC, using the developed approaches, in order to reduce the failure risk during the operation of aero engines. The book is intended for undergraduate and graduate students who are interested in the mechanical behavior of CMCs, researchers investigating the damage evolution of CMCs at elevated temperatures, and designers responsible for hot-section CMC components in aero engines.







Damage, Fracture, and Fatigue of Ceramic-Matrix Composites


Book Description

This book focuses on the damage, fracture and fatigue of ceramic-matrix composites. It investigates tensile damage and fracture, fatigue hysteresis, and the properties of interfaces subjected to cyclic fatigue loading. Further, it predicts fatigue life at room and elevated temperatures using newly developed damage models and methods, and it analyzes and compares damage, fracture and fatigue behavior of different fiber performs: unidirectional, cross-ply, 2D and 2.5D woven. The developed models and methods can be used to predict the damage and lifetime of ceramic-matrix composites during applications on hot section components.Ceramic-matrix composites (CMCs) are high-temperature structural materials with the significant advantages of high specific strength, high specific modulus, high temperature resistance and good thermal stability, which play a crucial role in the development of high thrust weight ratio aero engines. The critical nature of the application of these advanced materials makes comprehensive characterization a necessity, and as such this book provides designers with essential information pertaining not only to the strength of the materials, but also to their fatigue and damage characteristics.




Microstructure And Properties Of Materials (Volume 1)


Book Description

This is an advanced text on the microstructure and properties of materials, the first volume of a possible 3-volume set. While there are many elementary texts in materials science, there are very few advanced texts. Chapter 1 on aluminum alloys presents microstructural optimization and critical considerations in design applications. Chapter 2 on Nickel-base superalloys reviews the compositional, microstructural and processing advances in increasing their maximum use temperature. Chapter 3 on metal matrix composites discusses the strengthening mechanisms of metals dispersed with short fibers or particles. Chapter 4 on polymer matrix composites contains the details of the microsturcture property relationships of high performance fibers, polymer matrix material and the advanced composites made therewith. Chapter 5 on ceramics matrix composites describes the fibers and matrix materials used, the processing techniques involved and the mechanical properties under different loading conditions. Chapter 6 on inorganic glasses describes the influence of second phases, both glassy and cyrstalline on their properties. Chapter 7 on superconducting materials shows the importance of twins, grain boundaries, dislocations and stacking faults. Chapter 8 on magnetic materials introduces the domain structure and its effects on the soft and hard magnetic properties.




Processing of Ceramic and Metal Matrix Composites


Book Description

Emphasis is on the discussion and analysis of the processing and properties of multiphase structural ceramic materials and metal matrix composites reinforced with ceramic particulates or fibers. This volume represents the state-of-the-art in our understanding of the processing-structure-property interrelationships for these materials which possess unique and useful mechanical and thermal properties as a result of their multiphase nature. Additionally, the reader will find useful information on many new materials and processes currently under investigation.