Atomic Spectra and Atomic Structure


Book Description

For beginners and specialists in other fields: the Nobel Laureate's introduction to atomic spectra and their relationship to atomic structures, stressing basics in a physical, rather than mathematical, treatment. 80 illustrations.




The Theory of Atomic Spectra


Book Description

The standard comprehensive work on the theory of atomic spectra. "...a work of the first rank...." Nature




Atomic Spectra and Radiative Transitions


Book Description

My previous book on the theory of atomic spectra was published in Russian about fifteen years ago. Besides the traditional problems usually included in a book on atomic spectroscopy, some other problems arising in various applications of spectroscopic methods were also discussed in the book. These include, for example, continuous spectrum radiation, excitation of atoms, and spectral line broadening. Extensive revisions were made in the English version of the book published by the Pergamon Press in 1972, especially in the chapter devoted to the problem of excitation of atoms. This book is intended as the first part of a two-volume presentation of the theory of atomic spectra, atomic radiative transitions, excitation of atoms, and spectral line broadening. The aim in preparing these new books has been to stress the problems connected with the most interesting applications of atomic spectroscopy to plasma diagnostics, astrophysics, laser physics, and other fields, which have been developed very intensively in recent years. The content of this first volume, devoted to the systematics of atomic spectra and radiative transitions, is similar to that of Chapters 1-6, 8 and 9 of the old book, but considerable revision has been made. Some sections, such as those on the Hartree-Fock method, the Dirac equation, and relativistic corrections, have been deleted. At the same time, more attention is paid to radiative transitions. More extensive tables of oscillator strengths, prob abilities, and effective cross sections of radiative transitions in discrete and continuous spectra are given.




Introduction to the Theory of Atomic Spectra


Book Description

Introduction to the Theory of Atomic Spectra is a systematic presentation of the theory of atomic spectra based on the modern system of the theory of angular momentum. Many questions which are of interest from the point of view of using spectroscopic methods for investigating various physical phenomena, including continuous spectrum radiation, excitation of atoms, and spectral line broadening, are discussed. This volume consists of 11 chapters organized into three sections. After a summary of elementary information on atomic spectra, including the hydrogen spectrum and the spectra of multi-electron atoms, the reader is methodically introduced to angular momentum, systematics of the levels of multi-electron atoms, and hyperfine structure of spectral lines. Relativistic corrections are also given consideration, with particular reference to the use of the Dirac equation to determine the stationary states of an electron in an arbitrary electromagnetic field. In addition, the book explores the Stark effect and the Zeeman effect, the interaction between atoms and an electromagnetic field, and broadening of spectral lines. The final chapter is devoted to the problem of atomic excitation by collisions. This book is intended for advanced-course university students, postgraduate students and scientists working on spectroscopy and spectral analysis, and also in the field of theoretical physics.







The Theory of Atomic Structure and Spectra


Book Description

Both the interpretation of atomic spectra and the application of atomic spectroscopy to current problems in astrophysics, laser physics, and thermonuclear plasmas require a thorough knowledge of the Slater-Condon theory of atomic structure and spectra. This book gathers together aspects of the theory that are widely scattered in the literature and augments them to produce a coherent set of closed-form equations suitable both for computer calculations on cases of arbitrary complexity and for hand calculations for very simple cases.




Isotope Shifts in Atomic Spectra


Book Description

Atomic and nuclear physics are two flourishing but distinct branches of physics; the subject of isotope shifts in atomic spectra is one of the few that links these two branches. It is a subject that has been studied for well over fifty years, but interest in the subject, far from flagging, has been stimulated in recent years. Fast computers have enabled theoreticians to evaluate the properties of many-electron atoms, and laser spectroscopy has made it possible to measure isotope shifts in the previously unmeasurable areas of very rare isotopes, short-lived radioactive isotopes, weak transitions, and transitions involving high-lying atomic levels. Isotope shifts can now be measured with greater accuracy than before in both optical transitions and x-ray transitions of muonic atoms; this improved accuracy is revealing new facets of the subject. I am very grateful to Dr. H. G. Kuhn, F. R. S. , for having introduced me to the subject in the 1950s, and for supervising my efforts to measure isotope shifts in the spectrum of ruthenium. I thus approach the subject as an experimental atomic spectroscopist. This bias is obviously apparent in my use of the spectroscopist's notation of lower-upper for a transition, rather than the nuclear physicist's upper-lower. My reasons are given in Section 1. 3 and I hope that nuclear physicists will forgive me for using this notation even for muonic x-ray transitions.




Atomic Spectra


Book Description

The text starts off by looking at quantum mechanics and the relationship of quantum mechanics with light. The next chapter considers the structure and spectrum of the hydrogen atoms. The text also covers the spectrum of the helium atom. Finally, the text examines the spectra of many-electron atoms.




Spectra of Atoms and Molecules


Book Description

Spectra of Atoms and Molecules, 2nd Edition is designed to introduce advanced undergraduates and new graduate students to the vast field of spectroscopy. Of interest to chemists, physicists, astronomers, atmospheric scientists, and engineers, it emphasizes the fundamental principles of spectroscopy with its primary goal being to teach students how to interpret spectra. The book includes a clear presentation of group theory needed for understanding the material and a large number of excellent problems are found at the end of each chapter. In keeping with the visual aspects of the course, the author provides a large number of diagrams and spectra specifically recorded for this book. Topics such as molecular symmetry, matrix representation of groups, quantum mechanics, and group theory are discussed. Analyses are made of atomic, rotational, vibrational, and electronic spectra. Spectra of Atoms and Molecules, 2nd Edition has been updated to include the 1998 revision of physical constants, and conforms more closely to the recommended practice for the use of symbols and units. This new edition has also added material pertaining to line intensities, which can be confusing due to the dozens of different units used to report line and band strengths. Another major change is in author Peter Bernath's discussion of the Raman effect and light scattering, where the standard theoretical treatment is now included. Aimed at new students of spectroscopy regardless of their background, Spectra of Atoms and Molecules will help demystify spectroscopy by showing the necessary steps in a derivation.