Bioinspired Chemistry for Energy


Book Description

Faced with the steady rise in energy costs, dwindling fossil fuel supplies, and the need to maintain a healthy environment - exploration of alternative energy sources is essential for meeting energy needs. Biological systems employ a variety of efficient ways to collect, store, use, and produce energy. By understanding the basic processes of biological models, scientists may be able to create systems that mimic biomolecules and produce energy in an efficient and cost effective manner. On May 14-15, 2007 a group of chemists, chemical engineers, and others from academia, government, and industry participated in a workshop sponsored by the Chemical Sciences Roundtable to explore how bioinspired chemistry can help solve some of the important energy issues the world faces today. The workshop featured presentations and discussions on the current energy challenges and how to address them, with emphasis on both the fundamental aspects and the robust implementation of bioinspired chemistry for energy.




Bioinspired Chemistry: From Enzymes To Synthetic Models


Book Description

The observation of Nature is an inexhaustible source of inspiration to promote innovations in chemistry. The bioinspired approach is a revolution in our paradigms because it is not based on what we can take to nature, but on what we can learn from it. Enzymatic systems involved in solar energy conversion (photosystem), hydrogen production (hydrogenases), dioxygen activation (oxydases et oxygenases), CO₂ reduction (CO dehydrogenase) use abundant and cheap starting material such as O₂, H₂O and CO₂. Inspiration of these biological systems is a solution to make our chemical processes greener. These are some of the many challenges that bioinspired chemistry is able to take up.A number of the recent developments in bioinspired chemistry are discussed, including some descriptions on the biological systems that are the source of inspiration. This book is a guide to where bioinspired chemistry will be in the near future and provides a thoughtful perspective on how bioinspiration could change our world.




Bioinspiration and Biomimicry in Chemistry


Book Description

Can we emulate nature's technology in chemistry? Through billions of years of evolution, Nature has generated some remarkable systems and substances that have made life on earth what it is today. Increasingly, scientists are seeking to mimic Nature's systems and processes in the lab in order to harness the power of Nature for the benefit of society. Bioinspiration and Biomimicry in Chemistry explores the chemistry of Nature and how we can replicate what Nature does in abiological settings. Specifically, the book focuses on wholly artificial, man-made systems that employ or are inspired by principles of Nature, but which do not use materials of biological origin. Beginning with a general overview of the concept of bioinspiration and biomimicry in chemistry, the book tackles such topics as: Bioinspired molecular machines Bioinspired catalysis Biomimetic amphiphiles and vesicles Biomimetic principles in macromolecular science Biomimetic cavities and bioinspired receptors Biomimicry in organic synthesis Written by a team of leading international experts, the contributed chapters collectively lay the groundwork for a new generation of environmentally friendly and sustainable materials, pharmaceuticals, and technologies. Readers will discover the latest advances in our ability to replicate natural systems and materials as well as the many impediments that remain, proving how much we still need to learn about how Nature works. Bioinspiration and Biomimicry in Chemistry is recommended for students and researchers in all realms of chemistry. Addressing how scientists are working to reverse engineer Nature in all areas of chemical research, the book is designed to stimulate new discussion and research in this exciting and promising field.




Bioinspired Chemistry for Energy


Book Description

Faced with the steady rise in energy costs, dwindling fossil fuel supplies, and the need to maintain a healthy environment - exploration of alternative energy sources is essential for meeting energy needs. Biological systems employ a variety of efficient ways to collect, store, use, and produce energy. By understanding the basic processes of biological models, scientists may be able to create systems that mimic biomolecules and produce energy in an efficient and cost effective manner. On May 14-15, 2007 a group of chemists, chemical engineers, and others from academia, government, and industry participated in a workshop sponsored by the Chemical Sciences Roundtable to explore how bioinspired chemistry can help solve some of the important energy issues the world faces today. The workshop featured presentations and discussions on the current energy challenges and how to address them, with emphasis on both the fundamental aspects and the robust implementation of bioinspired chemistry for energy.




Bioinspired Nanomaterials


Book Description

Biological synthesis employing microorganisms, fungi or plants is an alternative method to produce nanoparticles in low-cost and eco-friendly ways. The book covers the synthesis of metal nanoparticles, metal oxide nanostructures and nanocomposite materials, as well as the stability and characterization of bioinspired nanomaterials. Applications include optical and electrochemical sensors, packaging, SERS and drug delivery processes. Keywords: Bioinspired Nanomaterials, Metal Nanoparticles, Metal Oxide Nanostructures, Nanocomposite Materials, Microbicidal Activity, Drug Delivery, Packaging Applications, SERS Applications, Fluorescent Biosensing, Quantum Dots. Bio-Imaging, Electrochemical Sensors.




Materials Research to Meet 21st-Century Defense Needs


Book Description

In order to achieve the revolutionary new defense capabilities offered by materials science and engineering, innovative management to reduce the risks associated with translating research results will be needed along with the R&D. While payoff is expected to be high from the promising areas of materials research, many of the benefits are likely to be evolutionary. Nevertheless, failure to invest in more speculative areas of research could lead to undesired technological surprises. Basic research in physics, chemistry, biology, and materials science will provide the seeds for potentially revolutionary technologies later in the 21st century.




Research Frontiers in Bioinspired Energy


Book Description

In May 2007, the National Academies Chemical Sciences Roundtable held a public workshop on the topic of Bioinspired Chemistry for Energy, where government, academic, and industry representatives discussed promising research developments in solar-generated fuels, hydrogen-processing enzymes, artificial photosynthetic systems, and biological-based fuel cells. Workshop participants identified the need for a follow-up activity that would explore bioinspired energy processes in more depth and involve a wider array of disciplines as speakers and participants. Particularly, workshop participants stressed the importance of holding a workshop that would include more researchers from the biological sciences and engineering, as well as those involved in technological advances that enable progress in understanding these systems. Building upon the 2007 workshop, the National Academies Board on Chemical Sciences and Technology convened the Committee on Research Frontiers in Bioinspired Energy to organize a second workshop in 2011 which, according to the statement of task, would explore the molecular-level frontiers of energy processes in nature through an interactive, multidisciplinary, and public format. Specifically, the committee was charged to feature invited presentations and include discussion of key biological energy capture, storage, and transformation processes; gaps in knowledge and barriers to transitioning the current state of knowledge into applications; and underdeveloped research opportunities that might exist beyond disciplinary boundaries. Research Frontiers in Bioinspired Energy is an account of what occurred at the 2011 workshop, and does not attempt to present any consensus findings or recommendations of the workshop participants. It summarizes the views expressed by workshop participants, and while the committee is responsible for the overall quality and accuracy of the report as a record of what transpired at the workshop, the views contained in the report are not necessarily those of the committee.




Out-of-Equilibrium (Supra)molecular Systems and Materials


Book Description

A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.




Carbon-Neutral Fuels and Energy Carriers


Book Description

Concerns over an unstable energy supply and the adverse environmental impact of carbonaceous fuels have triggered considerable efforts worldwide to find carbon-free or low-carbon alternatives to conventional fossil fuels. Carbon-Neutral Fuels and Energy Carriers emphasizes the vital role of carbon-neutral energy sources, transportation fuels, and associated technologies for establishing a sustainable energy future. Each chapter draws on the insight of world-renowned experts in such diverse fields as photochemistry and electrochemistry, solar and nuclear energy, biofuels and synthetic fuels, carbon sequestration, and alternative fuel vehicles. After an introductory chapter on different energy options in a carbon-constrained world and proposed measures to stabilize atmospheric CO2, the book analyzes the advantages and challenges facing the introduction of hydrogen fuel to the marketplace. It then examines the role of nuclear power in the production of carbon-free energy and fuels as well as the efficient use and storage of renewable energy resources, emphasizing the production of solar fuels from water and CO2. The book also discusses different aspects of bioenergy and biofuels production and use and the potential role of bio-inspired energy systems and industrial processes. The final chapters present a thorough overview and analysis of state-of-the-art fossil fuel decarbonization technologies and clean transportation options. This authoritative work provides the information needed to make more informed choices regarding available clean energy and fuel alternatives. It helps readers to better understand the interconnection between energy and the environment as well as the potential impact of human activities on climate.




Green Nanomaterials


Book Description

This book covers emerging bioinspired green methods for preparing inorganic nanomaterials. The book starts with an introduction to the principles of green chemistry and engineering, and highlights the special properties that nanomaterials possess, their applications and ways to characterise them. It describes conventional methods of synthesising and manufacturing inorganic nanomaterials, and introduces biological and biomimetic/bioinspired synthetic methods as a solution to precisely control nanomaterials and design sustainable manufacturing routes. The book elaborates on various mechanisms and examples of green nanomaterials, including the role of organic matrix and natural self-assembly, and advantages and opportunities with green nanomaterials. Two case studies of magnetic and silica materials are provided for advanced readers. The book is an insightful reference text for researchers focusing on synthetic biology and nanomaterials. It is an essential title for postgraduates and final-year undergraduates studying advanced materials, sustainable engineering or environmental chemistry.