New Types of Persistent Halogenated Compounds


Book Description

Environmental Chemistry is a relatively young science. Interest in this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and limits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives of Environ mental Chemistry must be the study of the environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environment and chemical reactions occurring in the environment. The industrial activities of man have given a new dimension to Environ mental Chemistry. We have now synthesized and described over five million chemical compounds and chemical industry produces about hundred and fifty million tons of synthetic chemicals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas of up to 15 million inhabitants produce large quantities of waste in relatively small and confined areas. Much of the chemical products and waste products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently lead to interference and disturbance of natural systems.







Toxicological Risks of Selected Flame-Retardant Chemicals


Book Description

Ignition of upholstered furniture by small open flames from matches, cigarette lighters, and candles is one of the leading causes of residential-fire deaths in the United States. These fires accounted for about 16% of civilian fire deaths in 1996. On average, each year since 1990, about 90 deaths (primarily of children), 440 injuries, and property losses amounting to 50 million dollars have resulted from fires caused by the ignition of upholstered furniture by small open flames. Certain commercial seating products (such as aircraft and bus seats) are subject to flammability standards and sometimes incorporate FR-treated upholstery cover materials, but there is no federal-government requirement for residential upholstered furniture, and it is generally not treated with FR chemicals. It is estimated that less than 0.2% of all U.S. residential upholstery fabric is treated with flame-retardant (FR) chemicals. The Consumer Product Safety Act of 1972 created the U.S. Consumer Product Safety Commission (CPSC) as an independent federal regulatory agency whose mission is to protect the public from unreasonable risks of injury and death associated with consumer products. CPSC also administers the Flammable Fabrics Act, under which it regulates flammability hazards and the Federal Hazardous Substances Act (FHSA), which regulates hazardous substances including chemicals. In 1993, the National Association of State Fire Marshals petitioned CPSC to issue a performance-based flammability standard for upholstered furniture to reduce the risk of residential fires. The Commission granted that portion of the petition relating to small open flame ignition risks. In response to concerns regarding the safety of FR chemicals, Congress, in the fiscal year 1999 appropriations report for CPSC, requested that the National Research Council conduct an independent study of the health risks to consumers posed by exposure to FR chemicals that are likely to be used in residential upholstered furniture to meet a CPSC standard. The National Research Council assigned the project to the Committee on Toxicology (COT) of the Commission on Life Sciences' Board on Environmental Studies and Toxicology. COT convened the Subcommittee on Flame-Retardant Chemicals, which prepared this report. Subcommittee members were chosen for their recognized expertise in toxicology, pharmacology, epidemiology, chemistry, exposure assessment, risk assessment, and biostatistics. Toxicological Risks of Selected Flame-Retardant Chemicals is organized into 18 chapters and two appendices. Chapter 2 describes the risk assessment process used by the subcommittee in determining the risk associated with potential exposure to the various FR chemicals. Chapter 3 describes the method the subcommittee used to measure and estimate the intensity, frequency, extent, and duration of human exposure to FR chemicals. Chapters 4-19 provide the subcommittee's review and assessment of health risks posed by exposure to each of the 16 FR chemicals. Data gaps and research needs are provided at the end of these chapters.




The Non-halogenated Flame Retardant Handbook


Book Description

A one-stop, practical handbook containing all of the current commercial non-halogenated flame retardant technologies as well as experimental systems near commercialization In response to the emphasis on replacing halogenated flame retardants with alternate technologies, this handbook focuses on existing non-halogenated flame retardants and the experimental close-to-production systems that are available today. The Non-Halogenated Flame Retardant Handbook starts with an overview of the regulations and customer perceptions driving non-halogenated flame retardant selections over older halogenated technologies. It then moves on to cover the known major classes of non-halogenated flame retardants, before concluding with the current niche-performing technologies and untried commercial contenders of the future. The Non-Halogenated Flame Retardant Handbook: Takes a practical approach to addressing the narrow subject of non-halogenated flame retardancy—placing more emphasis on flame retardant selection for specific plastics, practical considerations in flame retardant material design, and the various technologies’ strengths and limits Focuses on the proper use of non-halogenated flame retardants, rather than the mechanics of how they work Discusses important future trends in flame retardancy Features sections written by industrial and chemical experts who know how to apply the technology to polymers for fire safety needs




Fire Retardancy of Polymers


Book Description

The use of polymers is restricted by their flammability - they may indeed initiate or propagate fire. Fire Retardancy of Polymers focuses on mineral additives from either micro- or nano-composites for application in fire retardants. With the use of fire retardant additives containing halogen or phosphorus compounds in decline, the need for other systems is evident. The major materials that are used are alumina trihydrate or magnesium hydroxide which account for more than 50% by weight of the world-wide sales of fire retardants. Recent works have shown that such halogen-free compounds may give enhanced fire retardancy to polymeric materials when used in low levels, alone, or in synergistic mixtures. The corresponding fire performance depends on the dispersion of the mineral filler, with micrometer-scale dispersion leading to the best performances. Specialists discuss these new applications of mineral fillers with particular emphasis on action mechanisms, new materials including textiles, toxicology and hazards. With extensive references, this book provides a comprehensive and up-to-date view of these applications. This book will appeal to professionals, materials scientists and engineers looking for novel ways to eliminate fire hazards and improve flame retardancy of materials, with a special interest in sustainable development.




Theory of Flame Retardation of Polymeric Materials


Book Description

Flame retardant materials are of vital importance in guaranteeing personal security. Especially the demand for non-toxic, low smoking, polymerized flame retardants increases and new materials enter the market. The authors present the fundamental theory of polymer combustion, compare different flame retardants, describe smoke suppression mechanisms, and explain analyzing techniques for new materials.




Fire Retardant Materials


Book Description

"This authoritative reference work will provide a comprehensive source of information for readers concerned with the highly diverse subject of fire retardance. The emphasis is on the burning behaviour and flame retarding properties of polymeric materials. It covers combustion, flame retardants, smoke and toxic products generally and goes on to concentrate on more material-specific aspects of combustion in relation to textiles, composites and bulk polymers. A wide range of fire retardant materials are covered including research in the new field of nanocomposites."--Knovel.




Polymer Green Flame Retardants


Book Description

Polymer Green Flame Retardants covers key issues regarding the response of polymers during fire, the mechanisms of their flame retardation, the regulations imposed on their use, and the health hazards arising from their combustion. Presenting the latest research developments, the book focuses in particular on nanocomposites, believed to be the most promising approach for producing physically superior materials with low flammability and ecological impact. The fire properties of nanocomposites of various matrixes and fillers are discussed, the toxicological characteristics of these materials are analyzed, addressing also their environmental sustainability. Edited by distinguished scientists, including an array of international industry and academia experts, this book will appeal to chemical, mechanical, environmental, material and process engineers, upper-level undergraduate and graduate students in these disciplines, and generally to researchers developing commercially attractive and environmentally friendly fire-proof products. - Provides recent findings on the manufacture of environmentally sustainable flame retardant polymeric materials - Covers legislation and regulations concerning flame retarded polymeric material use - Includes tables containing the fire properties of the most common polymeric materials




Fire Retardancy of Polymers


Book Description

Globally, fire retardants are needed to satisfy a multibillion dollar market and fire retardancy of polymetric materials is an important component of fire safety. This book covers the latest developments in new fire retardancy systems for engineers needing to use fire safe materials in their projects.




Health Impacts of Developmental Exposure to Environmental Chemicals


Book Description

This book provides concise and cutting-edge studies on threats resulting from exposure to environmental chemicals that can affect human health and development, with a particular emphasis on the DOHaD concept. The book is divided into five main parts, the first of which includes an introduction to the impacts of developmental exposure to environmental chemicals and historical perspectives, while the second focuses on how environmental chemicals can affect human organs, including neurodevelopment, immune functions, etc. In turn, the third part addresses the characteristics of specific chemicals and their effects on human health and development, while the fourth part provides a basis for future studies by highlighting the latest innovations in toxicology, remaining challenges, and promising strategies in children’s environmental health research, as well as ideas on how to bridge the gap between research evidence and practical policymaking. The fifth and last part outlines further research directions and related policymaking aspects. Health Impacts of Developmental Exposure to Environmental Chemicals will appeal to young and veteran researchers, students, and physicians (especially gynecologists and pediatricians) who are seeking comprehensive information on how children’s health can be affected by harmful chemicals and other environmental toxicants.