Clay Mineral Catalysis of Organic Reactions


Book Description

Clay minerals are layer silicates with a large propensity for adsorbing and intercalating simple and polymeric organic molecules. Because of their fine particle size, extensive surface area, layer structure, and peculiar charge characteristics, clay minerals can also act as efficient solid acid catalysts and catalyst carriers/supports. Besides being easy to separate from the reaction mixture and recyclable, clay minerals are abundant, inexpensive, and nonpolluting. Moreover, layer silicates offer a reduced dimensionality of reaction space in which introduced organic species can meet and collide. This book provides an insight into the relationship between the surface properties of clay minerals and their catalytic activity. Organized into eight comprehensive chapters, the volume describes and discusses the ability of clay minerals to serve as solid acid catalysts for a large range and variety of organic conversions and transformations. This book is a valuable reference for research scientists and industrial chemists who use, or contemplate using, clay minerals as catalysts for targeted organic reactions and syntheses. The present text will also be of interest to environmental and soil chemists as well as teachers and postgraduate students of organic geochemistry and solid acid catalysis. Book jacket.







Clay Mineral Catalysis of Organic Reactions


Book Description

The book provides insight into the working of clays and clay minerals in speeding up a variety of organic reactions. Clay minerals are known to have a large propensity for taking up organic molecules and can catalyse numerous organic reactions due to fine particle size, extensive surface area, layer structure, and peculiar charge characteristics. They can be used as heterogeneous catalysts and catalyst carriers of organic reactions because they are non-corrosive, easy to separate from the reaction mixture, and reusable. Clays and clay minerals have an advantage over other solid acids as they are abundant, inexpensive, and non-polluting.




Natural Microporous Materials in Environmental Technology


Book Description

Proceedings of the NATO Advanced Research Workshop on the Application of Natural Microporous Materials for Environmental Technology, Smolenice Castle, Slovakia, 26-30 October 1998




Inorganic Materials


Book Description

Given the recent expansion in materials chemistry, this book addresses several of the vigorous areas of research in this field, where inorganic materials are central to the research. Each chapter provides an introduction to the subject under discussion and then develops the field to provide a sensible overview, with certain topics being expanded. Written by an international group of researchers the nine chapters cover such important areas as inorganic superconductors, magnetic materials, biogenic inorganic materials, polymeric co-ordination compounds, liquid crystals and precursors for electronic materials.




Evolutionary Biology


Book Description

Since 1997, scientists of different disciplines sharing a deep interest in concepts and knowledge related to evolutionary biology have held the annual Evolutionary Biology Meetings in Marseille in order to discuss their research and promote collaboration. Lately scientists especially focusing on applications have also joined the group. This book starts with the report of the "12th Evolutionary Biology Meeting", which gives a general idea of the meeting’s epistemological stance. This is followed by 22 chapters, a selection of the most representative contributions, which are grouped under the following four themes: Part I Concepts and Knowledge - Part II Modelization - Part III Applied Evolutionary Biology - Part IV Applications in Other Fields -Part IV transcends the field of biology, presenting applications of evolutionary biology in economics and astronomy.




Zinc Catalysis


Book Description

Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.




Environmentally Benign Catalysts


Book Description

Over the past twenty years, Catalysis by Heteropolyacids (HPAs) has received wide attention and led to new and promising developments both at academic and industrial level. In particular, heterogeneous catalysis is particularly attractive because it generally satisfies most of green chemistry’s requirements. By emphasizing the development of third generation catalysts, this volume presents trends and opportunities in academic and industrial research. The book appeals to postgraduates, researchers, and chemists working in the field of environmentally benign catalysts as well as catalytic processes.




Chemistry of Clays and Clay Minerals


Book Description

Bringing together information widely distributed throughout scientific and industrial journals, here is an overview of the chemical consititution and properties of clay minerals and the environmental conditions that lead to their formation. Provides a detailed picture of the chemical consititution of the eight main groups of clay minerals containing silica and of the non-siliceous oxide clays. The central section of the book deals with the properties of clays: their colloidal behavior, cation exchange, interaction with water, reactions on heating, catalytic properties, and reactions with organic compounds. Also discusses the chemical conditions that favor the formation of clays and their evolution or decomposition into other materials.




CO2 as a Building Block in Organic Synthesis


Book Description

A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2as an attractive C1 building block. With contributions from an international panel of experts, CO2 as a Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.