CdTe/ZnTe Quantum Dots - Growth and Optical Properties


Book Description

This paper gives an overview of molecular beam epitaxy (MBE) growth of and the optical properties of Cadmium Telluride (CdTe) quantum dots grown on Zinc Telluride (ZnTe) by self-assembly. It is shown that quantum dots in this material system can be obtained either by depositing CdTe at a high substrate temperature or by subjecting CdTe layer to a healing process, up to 70 seconds long before its capping or, eventually, by applying these two methods simultaneously. Moreover, it is found that one can also use the atomic layer epitaxy method to achieve the formation. From optical measurements performed on large quantum dot ensembles it is found that the quantum dot emission is much broader than that of quantum wells, and that it is observable up to much higher temperatures, which indicates strong exciton localization. The latter is also evidenced by an insensitivity of the decay time of the exciton recombination (^3O0 ps) to the temperature. From the presence of a second, very long decay time (^5 ns) and from disappearance of the sharp lines related to recombination in single dots, the acoustic phonon scattering of excitons is found to play an important role in these quantum dot structures. From a magnetic field dependence of the single dot emission energy, the exciton effective g-factor and spatial extension of the exciton wave function are deduced to be equal to -3 and 3 nanometers, respectively. Both the g-factor and the value of the diamagnetic shift are found to be independent of the energy of the quantum dot emission at Beta=Omicron Tau and of the in-plane symmetry of its potential. (11 figures, 35 refs.).




Cadmium Telluride Quantum Dots


Book Description

In the last two decades, semiconductor quantum dots-small colloidal nanoparticles-have garnered a great deal of scientific interest because of their unique properties. Among nanomaterials, CdTe holds special technological importance as the only known II-VI material that can form conventional p-n junctions. This makes CdTe very important for the dev




An Optical Study of the Electronic Structure of CdSe/ZnSe and CdTe/ZnTe Self Assembled Quantum Dots


Book Description

We study the excitonic structure and optical properties of single quantum dots in three different II-VI semiconductor structure systems: as-grown CdSe/ZnSe, as-grown CdTe/ZnTe, and annealed CdTe/ZnTe self-assembled quantum dots(QD) using photoluminescence(PL), micro-PL, micro-PL obtained using a sub-wavelength aperture, and PL images obtained using a Solid Immersion Lens (SIL). These experiments are performed both at zero field and magnetic field up to 3 Tesla. While in zero field, linear polarized PL are used to find exchange splitting and QD asymmetry direction of the three QD samples, in a 3 Tesla magnetic field, circular polarized PL is used to determine the g-factor and diamagnetic shift. With a solid immersion lens (SIL), we are able to directly image a large number of single QD at 6K with 400 nm spatial resolution. Using zero field measurements, we find that while the some of the QDs are symmetric, and emit completely unpolarized light, over half of the QDs are antisymmetric which are typically aligned along one of the in-plane crystallographic directions, and so emit linear polarized PL. Since polarization properties as well as spin properties such as exchange splitting, g-factor and diamagnetic coefficient are different from dot to dot due to their size and asymmetry variations, we have carried out a statistical study of these properties in order to understand what changes occur in the QDs between these three samples. The major result from this work shows that thermal annealing of CdTe dots significantly reduces the statistical variation of exchange splittings for asymmetric dots as well as the g-factors for symmetric dots. We infer that these changes result from enlargement of the CdTe dots due to interdiffusion of Zn between the barriers and the dots. This enlargement is reflected in the increase of the median distributions of the diamagnetic shifts. Moreover, in CdSe dots, where the dot size is comparable or slightly larger than the exciton Bohr diameter, we find that the variation of these parameters is reduced as well.




Investigations of Electronic Structure and Optical Properties of Ii-Vi Self-assembled Quantum Dots


Book Description

In this dissertation, we use different optical and imaging spectroscopy techniques to study electronic structure and optical properties of CdTe/ZnTe and CdSe/ZnSe self-assembled quantum dots (SAQDs). We perform single dot photoluminescence excitation experiments to identify carrier excitation mechanisms in CdTe/ZnTe QDs. The first mechanism is direct excitation into the QD excited states followed by relaxation to the ground state and the second mechanism is direct excitation into the QD ground states through LO phonon-assisted absorption. We then execute resonant PL measurements for both CdTe and CdSe QD ensembles to study the dependence of exciton-LO phonon coupling on QD size in these II-VI SAQDs. We shown that the strength of exciton-LO phonon coupling increases significantly for QDs with lateral sizes smaller than the exciton Bohr radius (e.g. as-grown CdTe QDs) while for larger QDs (e.g. CdSe or CdTe annealed) it is almost independent of the QD emission energy, and therefore presumably of the QD size. In order to study electronic coupling between SAQDs, we setup imaging experiments with the use of a hemisphere solid immersion lens. While the PLE imaging measurements show the existence two-dimensional platelets with a typical size of about 500 nm which provide spatially extended but strong localized states through which different QDs could be populated simultaneously, the spatially resolved imaging data demonstrates a complete 2D map of those platelets. These results are further supported by computational calculations based on finite element analysis. Low temperature exciton spin relaxation in symmetric CdTe SAQDs has been thoroughly studied by means of cw polarized magneto-PL and polarized time-resolved PL spectroscopies. We find that the degeneracy of exciton energy levels has a strong influence on the spin transition. When the exciton spin states in QDs are degenerate, the spin relaxation time is much shorter than the exciton recombination time. In contrast, if this degeneracy is removed, either by asymmetry or an external magnetic field, the spin relaxation time becomes much longer than the exciton recombination time. Using simple rate equation models, we estimate exciton spin relaxation times equal to 4.8 ns and 50 ps for non-degenerate and degenerate QD states, respectively.




Molecular Beam Epitaxy


Book Description

Molecular Beam Epitaxy (MBE): From Research to Mass Production, Second Edition, provides a comprehensive overview of the latest MBE research and applications in epitaxial growth, along with a detailed discussion and ‘how to’ on processing molecular or atomic beams that occur on the surface of a heated crystalline substrate in a vacuum. The techniques addressed in the book can be deployed wherever precise thin-film devices with enhanced and unique properties for computing, optics or photonics are required. It includes new semiconductor materials, new device structures that are commercially available, and many that are at the advanced research stage. This second edition covers the advances made by MBE, both in research and in the mass production of electronic and optoelectronic devices. Enhancements include new chapters on MBE growth of 2D materials, Si-Ge materials, AIN and GaN materials, and hybrid ferromagnet and semiconductor structures. Condenses the fundamental science of MBE into a modern reference, speeding up literature review Discusses new materials, novel applications and new device structures, grounding current commercial applications with modern understanding in industry and research Includes coverage of MBE as mass production epitaxial technology and how it enhances processing efficiency and throughput for the semiconductor industry and nanostructured semiconductor materials research community







Applied Crystallography


Book Description

This proceedings volume contains research data from structural investigation of materials of high industrial value. Contents: Determination of Crystal Structure from Powder Diffraction by Rietveld Method; Development of Methods and Techniques in X-Ray, Electron and Neutron Diffraction; Crystallography of Phase Transformation, Martensitic Transformation in Shape Memory Alloys; Texture Studies, Defect Structure and Microstructure Characterisation; Material Structure: Metals, Ceramic, Polymers, Amorphous Materials, Nanomaterials and Thin Films. Readership: Graduate students and researchers in crystallography and materials science.




Quantum Dots


Book Description

Quantum dots: Emerging materials for versatile applications is an introduction to the fundamentals and important advances of research of this important category of semiconductor nanostructured materials. After a brief review of relevant nanotechnology concepts and the unique properties of nanomaterials, the book describes the fundamentals of quantum dots with definitions of the primary classifications of quantum dots. There is an emphasis on practical considerations of the commercial translation of quantum dots such as their toxicity, stability, and disposal. Moreover, the book focuses on a review of the advances in research in emerging quantum dot materials along with the latest innovations in materials design and fabrication methods. Quantum Dots is suitable for materials scientists and engineers in academia or industry R&D who are looking for an introduction to this research topic or a key reference on the latest advances and applications. Introduces the primary classifications, properties, synthesis, characterization and fabrication strategies of quantum dots Reviews the latest applications of quantum dots for LEDs, displays, energy storage devices, photovoltaic cells, medicine, and more Discusses the practical barriers to commercial translation of quantum dots, including toxicity, stability, and their safe disposal




Core/Shell Quantum Dots


Book Description

This book outlines various synthetic approaches, tuneable physical properties, and device applications of core/shell quantum dots (QDs). Core/shell QDs have exhibited enhanced quantum yield (QY), suppressed photobleaching/blinking, and significantly improved photochemical/physical stability as compared to conventional bare QDs. The core-shell structure also promotes the easy tuning of QDs’ band structure, leading to their employment as attractive building blocks in various optoelectronic devices. The main objective of this book is to create a platform for knowledge sharing and dissemination of the latest advances in novel areas of core/shell QDs and relevant devices, and to provide a comprehensive introduction and directions for further research in this growing area of nanomaterials research.




Optical Properties of Nanostructures


Book Description

This book discusses electrons and photons in and through nanostructures by the first-principles quantum mechanical theories and fundamental concepts (a unified coverage of nanostructured electronic and optical components) behind nanoelectronics and optoelectronics, the material basis, physical phenomena, device physics, as well as designs and applications. The combination of viewpoints presented in the book can help foster further research and cross-disciplinary interaction needed to surmount the barriers facing future generations of technology design.