Chemical-physical-mechanical Charactization of Aging and Restoration of Asphaltic Materials in Different Length Scales


Book Description

Asphalt binder is a highly heterogeneous organic material; thus, its aging and restoration phenomena are very complex. Since the effects of aging and restoration on behavior of asphaltic materials are considered chemo-physical and mechanical in multiple length scales, a multiscale experimental approach can provide some significant insights to the understanding of the complex phenomenon. This study aims to investigate the laboratory aging protocol and compare it with the field aging process as well as to examine the short and long-term effects of different restorators on the mechanical, rheological, and chemical characteristics of asphaltic materials. To meet the objectives of this study, a multiscale experimental method was proposed and conducted. Three different binders (i.e. two virgin binders and one field aged binder) and restorators, a blend of different source of aggregates, and reclaimed asphalt pavement were selected/used. Test-analysis results showed that the mechanical/rheological properties and chemical analyses of the laboratory aged binders presented good correlations between aging indicators (e.g., carbonyl and colloidal index). It was also found that the long-term laboratory aging process has a limited ability to properly simulate long-term field aging. The kinetic analysis indicated that a mixed control regime, chemical reaction together with diffusion, governs the binder laboratory aging process. Test-analysis results from binders restored due to additives showed that the addition of restorators improve viscoelastic properties and fatigue resistance while they diminish rutting resistance. However, the petroleum-based restorator might contribute to maintaining the performance of the binder after another round of long-term aging. The chemical analysis indicated that the tall oil restorator contained many hydrogen bond-forming functional groups (-OH), which may increase the moisture sensitivity of the mixture. Outcomes from this study are expected to help more sustainable and energy-efficient civil infrastructure engineering due to the better selection/development of mixture components and more engineered blending of those.




Microstructural Characterization of the Chemo-mechanical Behavior of Asphalt in Terms of Aging and Fatigue Performance Properties


Book Description

The study of asphalt chemo-mechanics requires a basic understanding of the physical properties and chemical composition of asphalt and how these properties are linked to changes in performance induced by chemical modifications. This work uniquely implements the framework of chemo-mechanics by investigating two types of chemical modification processes, natural (oxidative aging) and synthetic (chemical doping) as they relate not only to macro-scale properties of asphalt binder but also to the asphalt microstructure and nanorheology. Furthermore, this study demonstrates the application of atomic force microscopy (AFM) imaging and the extraction of nano-scale engineering properties, i.e. elastic modulus, relaxation modulus, and surface energy, as a method to predict performance related to the fatigue characteristics of asphalt binders by modeling intrinsic material flaws present amongst phase interfaces. It was revealed that oxidative aging induces substantial microstructural changes in asphalt, including variations in phase structure, phase properties, and phase distribution. It has also been shown that certain asphalt chemical parameters have a consistent and measureable effect on the asphalt microstructure that is observed with AFM. In fact, particular phases that emerged via chemical doping revealed a surprising correlation between oxidative aging and the saturates chemical parameter of asphalt in terms of how they explicitly impact durability and performance of asphalt. By implementing a crack initiation model -- which requires measureable microstructural characteristics as an input parameter -- it was found that microstructural flaws (depending on the extremity) can have a more profound impact on asphalt performance than the properties of the material located between the flaws. It was also discovered by comparing the findings to performance data in the Strategic Highway Research Program's (SHRP's) Materials Reference Library (MRL), that the crack initiation model predicts very similar performance as the SHRP's distress resistance indicators. Overall, this body of work yields improved input values for asphalt prediction models and serves as the basis for ongoing studies in the areas of asphalt chemical mapping, modeling of nano-damage, and nano-modification using AFM. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/149372







Binder Characterization and Evaluation


Book Description




Modeling and Design of Flexible Pavements and Materials


Book Description

This textbook lays out the state of the art for modeling of asphalt concrete as the major structural component of flexible pavements. The text adopts a pedagogy in which a scientific approach, based on materials science and continuum mechanics, predicts the performance of any configuration of flexible roadways subjected to cyclic loadings. The authors incorporate state-of the-art computational mechanics to predict the evolution of material properties, stresses and strains, and roadway deterioration. Designed specifically for both students and practitioners, the book presents fundamentally complex concepts in a clear and concise way that aids the roadway design community to assimilate the tools for designing sustainable roadways using both traditional and innovative technologies.




New Materials in Civil Engineering


Book Description

New Materials in Civil Engineering provides engineers and scientists with the tools and methods needed to meet the challenge of designing and constructing more resilient and sustainable infrastructures. This book is a valuable guide to the properties, selection criteria, products, applications, lifecycle and recyclability of advanced materials. It presents an A-to-Z approach to all types of materials, highlighting their key performance properties, principal characteristics and applications. Traditional materials covered include concrete, soil, steel, timber, fly ash, geosynthetic, fiber-reinforced concrete, smart materials, carbon fiber and reinforced polymers. In addition, the book covers nanotechnology and biotechnology in the development of new materials. Covers a variety of materials, including fly ash, geosynthetic, fiber-reinforced concrete, smart materials, carbon fiber reinforced polymer and waste materials Provides a “one-stop resource of information for the latest materials and practical applications Includes a variety of different use case studies







Self-Healing Polymers


Book Description

Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.




Advanced Asphalt Materials and Paving Technologies


Book Description

This book is a printed edition of the Special Issue "Advanced Asphalt Materials and Paving Technologies" that was published in Applied Sciences




Paving Materials and Pavement Analysis


Book Description

Pavement Design And Paving Material Selection are important for efficient, cost effective, durable, and safe transportation infrastructure Paving Materials and Pavement Analysis contains 73 papers examining bound and unbound material characterization, modeling, and performance of highway and airfield pavements. The papers in this publication were presented during the GeoShanghal 2010 International Conference held in Shanghai, China, June 3-5, 2010.