Advances in Nuclear Fuel Chemistry


Book Description

Advances in Nuclear Fuel Chemistry presents a high-level description of nuclear fuel chemistry based on the most recent research and advances. Dr. Markus H.A. Piro and his team of global, expert contributors cover all aspects of both the conventional uranium-based nuclear fuel cycle and non-conventional fuel cycles, including mining, refining, fabrication, and long-term storage, as well as emerging nuclear technologies, such as accident tolerant fuels and molten salt materials. Aimed at graduate students, researchers, academics and practicing engineers and regulators, this book will provide the reader with a single reference from which to learn the fundamentals of classical thermodynamics and radiochemistry. - Consolidates the latest research on nuclear fuel chemistry into one comprehensive reference, covering all aspects of traditional and non-traditional nuclear fuel cycles - Includes contributions from world-renowned experts from many countries representing government, industry and academia - Covers a variety of fuel designs, including conventional uranium dioxide, mixed oxides, research reactor fuels, and molten salt fuels - Written by experts with hands-on experience in the development of such designs




The Nuclear Fuel Cycle


Book Description







Radiochemistry and Nuclear Chemistry


Book Description

Origin of Nuclear Science; Nuclei, Isotopes and Isotope Separation; Nuclear Mass and Stability; Unstable Nuclei and Radioactive Decay; Radionuclides in Nature; Absorption of Nuclear Radiation; Radiation Effects on Matter; Detection and Measurement Techniques; Uses of Radioactive Tracers; Cosmic Radiation and Elementary Particles; Nuclear Structure; Energetics of Nuclear Reactions; Particle Accelerators; Mechanics and Models of Nuclear Reactions; Production of Radionuclides; The Transuranium Elements; Thermonuclear Reactions: the Beginning and the Future; Radiation Biology and Radiation Protection; Principles of Nuclear Power; Nuclear Power Reactors; Nuclear Fuel Cycle; Behavior of Radionuclides in the Environment; Appendices; Solvent Extraction Separations; Answers to Exercises; Isotope Chart; Periodic Table of the Elements; Quantities and Units; Fundamental Constants; Energy Conversion Factors; Element and Nuclide Index; Subject Index.




State-of-the-art Report on the Progress of Nuclear Fuel Cycle Chemistry


Book Description

The implementation of advanced nuclear systems requires that new technologies associated with the back end of the fuel cycle are developed. The separation of minor actinides from other fuel components is one of the advanced concepts being studied to help close the nuclear fuel cycle and to improve the long-term effects on the performance of geological repositories. Separating spent fuel elements and subsequently converting them through transmutation into short-lived nuclides should considerably reduce the longterm risks associated with nuclear power generation. R&D programmes worldwide are attempting to address such challenges, and many processes for advanced reprocessing and partitioning minor actinides are being developed. This report provides a comprehensive overview of progress on separation chemistry processes, and in particular on the technologies associated with the separation and recovery of minor actinides for recycling so as to help move towards the implementation of advanced fuel cycles. The report examines both aqueous and pyro processes, as well as the status of current and proposed technologies described according to the hierarchy of separations targeting different fuel components. The process criteria that will affect technology downselection are also reviewed, as are non-proliferation requirements. The maturity of different reprocessing techniques are assessed using a scale based on the technology readiness level, and perspectives for future R&D are reviewed.







An Introduction to Nuclear Waste Immobilisation


Book Description

Drawing on the authors' extensive experience in the processing and disposal of waste, An Introduction to Nuclear Waste Immobilisation, Second Edition examines the gamut of nuclear waste issues from the natural level of radionuclides in the environment to geological disposal of waste-forms and their long-term behavior. It covers all-important aspects of processing and immobilization, including nuclear decay, regulations, new technologies and methods. Significant focus is given to the analysis of the various matrices used, especially cement and glass, with further discussion of other matrices such as bitumen. The final chapter concentrates on the performance assessment of immobilizing materials and safety of disposal, providing a full range of the resources needed to understand and correctly immobilize nuclear waste.




Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment


Book Description

Advanced separations technology is key to closing the nuclear fuel cycle and relieving future generations from the burden of radioactive waste produced by the nuclear power industry. Nuclear fuel reprocessing techniques not only allow for recycling of useful fuel components for further power generation, but by also separating out the actinides, lanthanides and other fission products produced by the nuclear reaction, the residual radioactive waste can be minimised. Indeed, the future of the industry relies on the advancement of separation and transmutation technology to ensure environmental protection, criticality-safety and non-proliferation (i.e., security) of radioactive materials by reducing their long-term radiological hazard.Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment provides a comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment. Part one covers the fundamental chemistry, engineering and safety of radioactive materials separations processes in the nuclear fuel cycle, including coverage of advanced aqueous separations engineering, as well as on-line monitoring for process control and safeguards technology. Part two critically reviews the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment. The section includes discussions of advanced PUREX processes, the UREX+ concept, fission product separations, and combined systems for simultaneous radionuclide extraction. Part three details emerging and innovative treatment techniques, initially reviewing pyrochemical processes and engineering, highly selective compounds for solvent extraction, and developments in partitioning and transmutation processes that aim to close the nuclear fuel cycle. The book concludes with other advanced techniques such as solid phase extraction, supercritical fluid and ionic liquid extraction, and biological treatment processes.With its distinguished international team of contributors, Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment is a standard reference for all nuclear waste management and nuclear safety professionals, radiochemists, academics and researchers in this field. - A comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment - Details emerging and innovative treatment techniques, reviewing pyrochemical processes and engineering, as well as highly selective compounds for solvent extraction - Discusses the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment




Sustainable and Safe Nuclear Fission Energy


Book Description

Unlike existing books of nuclear reactor physics, nuclear engineering and nuclear chemical engineering this book covers a complete description and evaluation of nuclear fission power generation. It covers the whole nuclear fuel cycle, from the extraction of natural uranium from ore mines, uranium conversion and enrichment up to the fabrication of fuel elements for the cores of various types of fission reactors. This is followed by the description of the different fuel cycle options and the final storage in nuclear waste repositories. In addition the release of radioactivity under normal and possible accidental conditions is given for all parts of the nuclear fuel cycle and especially for the different fission reactor types.




Solvent Extraction and Ion Exchange in the Nuclear Fuel Cycle


Book Description

This book covers most aspects of the processing of these fuels, bringing together the current thinking of international scientists and presenting a picture of the applications of solvent and ion exchange in the fuel cycle.