Radionuclides in the Environment


Book Description

Nuclear energy is the one energy source that could meet the world's growing energy needs and provide a smooth transition from fossil fuels to renewable energy in the coming decades and centuries. It is becoming abundantly clear that an increase in nuclear energy capacity will, and probably must, take place. However, nuclear energy and the use of radionuclides for civilian and military purposes lead to extremely long-lived waste that is costly and highly problematic to deal with. Therefore, it is critically important ot understand the environmental implications of radionuclides for ecosystems and human health if nuclear energy is to be used to avoid the impending global energy crisis. The present volume of the EIC Books series addresses this critical need by providing fundamental information on environmentally significant radionuclides. The content of this book was developed in collaboration with many of the authors of the chapters. Given the enormity of the subject the Editor and the Authors had to be judicious in selecting the chapters that would appropriately encompass and describe the primary topics, particularly those that are of importance to the health of ecosystems and humans. The resulting chapters were chosen to provide this information in a book of useful and appropriate length. Each chapter provides fundamental information on the chemistry of the radionuclides, their occurrence and movement in the enivornment, separation and analyses, and the technologies needed for their remediation and mitigation. The chapters are structured with a common, systematic format in order to facilitate comparions between elements and groups of elements. About EIC Books The Encyclopedia of Inorganic Chemistry (EIC) has proved to be one of the defining standards in inorganic chemistry, and most chemistry libraries around the world have access either to the first of second print editon, or to the online version. Many readers, however, prefer to have more concise thematic volumes, targeted to their specific area of interest. This feedback from EIC readers has encouraged the Editors to plan a series of EIC Books, focusing on topics of current interest. They will appear on a regular basis, and will feature leading scholars in their fields. Like the Encyclopedia, EIC Books aims to provide both the starting research student and the confirmed research worker with a critical distillation of the leading concepts in inorganic and bioinorganic chemistry, and provide a structured entry into the fields covered. This volume is also available as part of Encyclopedia of Inorganic Chemistry, 5 Volume Set. This set combines all volumes published as EIC Books from 2007 to 2010, representing areas of key developments in the field of inorganic chemistry published in the Encyclopedia of Inorganic Chemistry. Find out more.




Natural Organics in Groundwaters and Their Potential Effect on Contaminant Transport in Granitic Rock


Book Description

Presents a study of naturally occurring organics in groundwaters of the Whiteshell Research Area in Manitoba and of the Atikokan Research Area in Ontario to assess their potential role in radionuclide transport within granite fractures of the Canadian Shield. Attention is focused on the effect of organics on actinide mobility in groundwater, because actinides have isotopes with long half-lives that may pose a potential risk to man. Analytical techniques used include ultrafiltration and size fractionation, gas chromatography, mass spectroscopy, ultraviolet and visible absorbance spectroscopy, resin extraction, and carbon-14 age dating. Results presented include the observed dissolved organic carbon (DOC) concentrations, the characteristics of the DOC with respect to complexation capacity, and discussion of the origin of DOC in deep groundwaters.




Radionuclides, Inorganic Constituents, Organic Compounds, and Bacteria in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1991


Book Description

The US Geological Survey and the Idaho Department of Water Resources, in response to a request from the US Department of Energy, sampled 18 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for manmade pollutants and naturally occurring constituents. The samples were collected from six irrigation wells, seven domestic wells, two springs, one stock well, one dairy well, and one observation well. Quality assurance samples also were collected and analyzed. The water samples were analyzed for selected radionuclides, inorganic constituents, organic compounds, and bacteria. None of the samples analyzed for radionuclides, inorganic constituents, or organic compounds exceeded the established maximum contaminant levels for drinking water. Most of the radionuclide and inorganic constituent concentrations exceeded their respective reporting levels. All the samples analyzed for dissolved organic carbon had concentrations that exceeded their reporting level. Concentrations of 1,1,1 -trichloroethane exceeded the reporting level in two water samples. Two samples and a quality assurance replicate contained reportable concentrations of 2, 4-D. One sample contained fecal coliform bacteria counts that exceeded established maximum contaminant levels for drinking water.




Microbial Transformations of Natural Organic Compounds and Radionuclides in Subsurface Environments


Book Description

A major national concern in the subsurface disposal of energy wastes is the contamination of ground and surface waters by waste leachates containing radionuclides, toxic metals, and organic compounds. Microorganisms play an important role in the transformation of organic compounds, radionuclides, and toxic metals present in the waste and affect their mobility in subsurface environments. Microbial processes involved in dissolution, mobilization, and immobilization of toxic metals under aerobic and anaerobic conditions are briefly reviewed. Metal complexing agents and several organic acids produced by microbial action affect mobilization of radionuclides and toxic metals in subsurface environments. Information on the persistence of and biodegradation rates of synthetic as well as microbiologically produced complexing agents is scarce but important in determining the mobility of metal organic complexes in subsoils. Several gaps in knowledge in the area of microbial transformation of naturally occurring organics, radionuclides, and toxic metals have been identified, and further basic research has been suggested. 31 refs., 1 fig., 3 tabs.




Environmental Geochemistry


Book Description

The Treatise on Geochemistry is the first work providing a comprehensive, integrated summary of the present state of geochemistry. It deals with all the major subjects in the field, ranging from the chemistry of the solar system to environmental geochemistry. The Treatise on Geochemistry has drawn on the expertise of outstanding scientists throughout the world, creating the reference work in geochemistry for the next decade. Each volume consists of fifteen to twenty-five chapters written by recognized authorities in their fields, and chosen by the Volume Editors in consultation with the Executive Editors. Particular emphasis has been placed on integrating the subject matter of the individual chapters and volumes. Elsevier also offers the Treatise on Geochemistry in electronic format via the online platform ScienceDirect, the most comprehensive database of academic research on the Internet today, enhanced by a suite of sophisticated linking, searching and retrieval tools.




Evaluation of Guidelines for Exposures to Technologically Enhanced Naturally Occurring Radioactive Materials


Book Description

Naturally occurring radionuclides are found throughout the earth's crust, and they form part of the natural background of radiation to which all humans are exposed. Many human activities-such as mining and milling of ores, extraction of petroleum products, use of groundwater for domestic purposes, and living in houses-alter the natural background of radiation either by moving naturally occurring radionuclides from inaccessible locations to locations where humans are present or by concentrating the radionuclides in the exposure environment. Such alterations of the natural environment can increase, sometimes substantially, radiation exposures of the public. Exposures of the public to naturally occurring radioactive materials (NORM) that result from human activities that alter the natural environment can be subjected to regulatory control, at least to some degree. The regulation of public exposures to such technologically enhanced naturally occurring radioactive materials (TENORM) by the US Environmental Protection Agency (EPA) and other regulatory and advisory organizations is the subject of this study by the National Research Council's Committee on the Evaluation of EPA Guidelines for Exposures to Naturally Occurring Radioactive Materials.