Conjugate Heat Transfer and Sooting Propensity of Ethanol for Laminar Coflow Diffusion Flames at Elevated Pressures


Book Description

The effect of sooting propensity of various compositions of methane and ethanol fuel in laminar diffusion flames at elevated pressures was analyzed numerically. Simulations of laminar diffusion flames comprised of pressure conditions up to 20 atm and composition of ethanol and methane fuel ranging from pure methane to pure ethanol. For all fuel compositions evaluated, the total carbon mass flow rate was maintained at a constant value of 0.458 mg/s. Soot formation and soot yield were corroborated against measured data and demonstrated well agreement with trends for pressure and fuel composition. For elevated pressure, fuel compositions with higher ethanol content yield higher peak soot concentrations, however at lower pressures synergistic effects result to soot concentration decreasing with ethanol content for ethanol dominant fuel mixtures. Finally, the effect of conjugate heat transfer and modification in burner wall geometry were evaluated which exhibited improved trends and overall results.




The Sooting Propensities of Ethanol, Ethylene, Propylene, and Butylene at Elevated Pressures


Book Description

Laminar co-flow diffusion flames of ethanol-doped methane flames with 10% of carbon from ethanol up to 6 bar and nitrogen-diluted alkene flames of ethylene and propylene up to 8 bar and 1-butylene up to 2.5 bar were investigated. Line-of-sight spectral emission measurements were inverted with an Abel-type algorithm to obtain radially resolved soot volume fraction and temperature measurements. Ethanol-doped methane flames displayed consistently higher soot yields than neat methane flames, but only a slightly higher pressure dependence. Comparing the nitrogen-diluted alkene flames, 1-butylene produced the most soot, followed by propylene and ethylene. Propylene and 1-butylene displayed similar sooting propensity pressure dependencies, but ethylene was found to have a significantly stronger pressure dependence. This was attributed to the greater concentration of aromatics in the pyrolysis products of propylene and 1-butylene as aromatics have been found to have a weaker sooting propensity pressure dependence.
















Heat Transfer in Flames


Book Description




Gaseous Species Measurements of Alternative Jet Fuels in Sooting Laminar Coflow Diffusion Flames


Book Description

The gaseous species concentration of Jet A-1, GTL, CTL and a blend of 80 vol.% GTL and 20 vol.% hexanol jet fuels in laminar coflow diffusion flames have been measured and studied. These species are carbon monoxide, carbon dioxide, oxygen, methane, ethane, ethylene, propylene, and acetylene. Benzene and propyne concentrations were also detected in CTL flames. 1-Butene has been quantified for the blend of GTL and hexanol flame.The detailed experimental setup has been described and results from different flames are compared. The CO is produced in a same amount in all the flames. The CTL flame had the largest and GTL/hexanol flame had lowest CO2 concentrations. The results indicate that GTL and GTL hexanol blend flames produce similar concentrations for all the measured hydrocarbon species and have the highest concentration among all the jet fuels. The experimental results from Jet A-1 fuel are also compared with numerical studies by Saffaripour et al .




An Investigation of Ethylene Laminar Diffusion Flames at Sub-atmospheric Pressures to Simulate Microgravity


Book Description

Ethylene/Air diffusion flames were studied at sub and super-atmospheric pressures to simulate a microgravity environment at fuel flow rates of 0.482 mg/s and 1.16 mg/s. Flame properties including flame dimensions, soot formation, temperature, and attachment mechanisms were investigated. Overall, luminous flame height decreased with decreasing pressure to the point of visible luminosity disappearance, resulting in blue flames. Flame width increased with decreasing pressure until the flame was almost spherical. Soot formation decreased with decreasing pressure to negligible concentrations in a near vacuum. At 0.482 mg/s, the percentage of carbon converted into soot was between 0.01% and 0.12%, whereas at 1.16 mg/s, this percentage was between 0.5% and 11% at sub-atmospheric pressures. Maximum flame temperatures increased with decreasing pressure. Regardless of fuel flow rate, the diffusion flames remained attached to the exterior of the burner. This attachment point moved further down the burner exterior as pressure decreased until a near vacuum.