Crystallization of Polymers: Volume 2, Kinetics and Mechanisms


Book Description

In Crystallization of Polymers, 2nd Edition, Leo Mandelkern provides a self-contained, comprehensive, and up-to-date treatment of polymer crystallization. Volume 2 of this edition provides an authoritative account of the kinetics and mechanisms of polymer crystallization, building from the equilibrium concepts presented in volume 1. As crystalline polymers rarely, if ever, achieve their equilibrium state, this books serves as a bridge between equilibrium concepts and the state that is finally achieved. With a comprehensive treatment of the surrounding theories and experimental results from simple to complex polymer systems, this book will be an invaluable reference work for all chemists, physicists and materials scientists working in the area of polymer crystallization.







Crystallization of Polymers: Volume 1, Equilibrium Concepts


Book Description

First published in 2002, from an original 1964 edition, in the Crystallization of Polymers, 2nd edition Leo Mandelkern provides a self-contained treatment of polymer crystallization. All classes of macromolecules are included and the approach is through the basic disciplines of chemistry and physics. The book discusses the thermodynamics and physical properties that accompany the morphological and structural changes that occur when a collection of molecules of very high molecular weight are transformed from one state to another. Volume 1 is a presentation of the equilibrium concepts that serve as a basis for the subsequent volumes. In this volume the author shows that knowledge of the equilibrium requirements is vital to understanding all aspects of the polymer crystallization process, and the final state that eventually evolves. This book will be an invaluable reference work for all chemists, physicists and materials scientists who work in the area of polymer crystallization.




In-situ Structure Characterization of Elastomers during Deformation and Fracture


Book Description

This thesis offers novel insights into the time-dependent structural evolution of polymers under deformation. In-situ tensile experiments at high-brilliance synchrotron sources allowed to characterize the material with unrivaled resolution in time and space. The strain-induced crystallization in natural rubber was studied by wide-angle X-ray diffraction. Special emphasis was put on the establishment of new structure-property relationships to give a more in-depth understanding of the mechanical performance of rubber parts, e.g. in tear fatigue loading. To this end, the kinetics of strain-induced crystallization were investigated, subjecting the material to high strain rates. The local structure around a crack tip was observed by scanning wide-angle X-ray diffraction. Ultra-small angle X-ray scattering served to study filled elastomers under deformation, from specially prepared model filler systems to industrially relevant carbon black filled rubbers. Other methods include electron microscopy coupled with in-situ tensile testing and optical dilatometry to examine cavitation in rubbers. The underlying theory as well as a literature review are covered by an extensive introductory chapter, followed by a description of the experimental techniques. The results are presented in more detail than in the original journal publications.




Polymer Morphology


Book Description

With a focus on structure-property relationships, this book describes how polymer morphology affects properties and how scientists can modify them. The book covers structure development, theory, simulation, and processing; and discusses a broad range of techniques and methods. • Provides an up-to-date, comprehensive introduction to the principles and practices of polymer morphology • Illustrates major structure types, such as semicrystalline morphology, surface-induced polymer crystallization, phase separation, self-assembly, deformation, and surface topography • Covers a variety of polymers, such as homopolymers, block copolymers, polymer thin films, polymer blends, and polymer nanocomposites • Discusses a broad range of advanced and novel techniques and methods, like x-ray diffraction, thermal analysis, and electron microscopy and their applications in the morphology of polymer materials




Advances in Manufacturing and Characterization of Functional Polyesters


Book Description

In recent years, we have assisted the remarkable growth in the use of functional polyesters. This book gathers novel research works dealing with the manufacturing and characterization of polyesters that have been functionalized by synthesis, copolymerization, additives (at micro- and nanoscale), surface modification, among other methodologies, to tailor desired properties in terms of mechanical, chemical, thermal, and barrier properties, biodegradation, and biocompatibility. Thus, Advances in Manufacturing and Characterization of Functional Polyesters will serve to guide a diverse audience of polymer scientists and engineers and provides an update of the “state-of-the-art” knowledge on functional polyesters.




Thermal Properties of Bio-based Polymers


Book Description

The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students.




Polymers from Renewable Resources


Book Description

This book is a printed edition of the Special Issue "Polymers from Renewable Resources" that was published in Polymers




Advanced Polymer Nanocomposites


Book Description

Advanced Polymer Nanocomposites: Science Technology and Applications presents a detailed review of new and emerging research outcomes from fundamental concepts that are relevant to science, technology and advanced applications. Sections cover key drivers such as the rising demand for lightweight and high strength automotive parts, the need for sustainable packaging materials and conservation of flavor in the food, drinks and beverages industries, and defense initiatives such as ballistic protection, fire retardation and electromagnetic shielding. With contributions from international authors working at the cutting-edge of research, this book will be an essential reference resource for materials scientists, chemists, manufacturers and polymer engineers. Through recent advances in nanotechnology, researchers can now manipulate atoms to create materials and products that are changing the way we live our lives. These materials have enhanced properties, such as tensile strength, impact and scratch resistance, electrical and thermal conductivity, thermal stability and fire resistance. Combines processing, properties and advanced commercial applications Emphasizes synthesis and fabrication techniques Focuses on environmental and health aspects Covers future challenges, opportunities, recycling and sustainability Contains contributions from high-profile, cutting-edge international researchers




Constitutive Models for Rubber XII


Book Description

Constitutive Models for Rubber XII is a comprehensive compilation of the oral and poster contributions to the XII European Conference on Constitutive Models for Rubbers (Milan, Italy, 7-9 September 2022). As the first after the COVID Pandemic, the XII edition again brought together researchers from the industry and the academia working in the field of elastomer technology and science to discuss the most recent advancement in the following topics: • Constitutive models • Micro-structural investigations • Experimental methods and characterization • Numerical methods • Fatigue and fracture • Aging • Industrial applications • Smart elastomer materials: applications and modelling Including more than 80 contributions from authors from around the world, this book aims at professionals and academics interested in elastomer technology and science.