Practical Aspects of Electroorganic Synthesis


Book Description

Practical Aspects of Electroorganic Synthesis presents educational insights into the practical aspects of electrosynthesis methods, providing a variety of examples and techniques. The book covers concepts referred to as "green chemistry" and "sustainable technology." Sections cover direct electrolysis, anodic oxidation, cathodic reduction, mechanistic studies (cyclic voltammetry), and how to set-up electrochemical experiments. Indirect electrolysis is also covered, including an exploration of catalysts and additives to take on modern electrochemical methods. Finally, the book explores the burgeoning new field of paired electrolysis, in which the ultimate green-synthesis applications are possible, with no wasted electrons and very few by-products. This book offers researchers a modern and authoritative resource that brings complete and up-to-date practical concepts of electrosynthesis methods and guides the audience on how to carry out a large number of experimental techniques. - Discusses complete and up-to-date practical concepts of electrosynthesis methods - Provides sound insights into the experimental approaches of electrosynthesis, covering new and novel synthesis techniques - Breaks down the fundamentals aspects of electrolysis into three digestible and logical sections




Applications of the Voltammetry


Book Description

The present book Applications of Voltammetry is a collection of six chapters, organized in two sections. The first book section is dedicated to the application of mathematical methods, such as multivariate calibration coupled with voltammetric data and numeric simulation to solve quantitative electroanalytical problems. The second book section is devoted to the electron transfer kinetic studies and electroanalytical applications of the voltammetry, such as interfacial electron transfer of the haem group in human haemoglobin molecules, physisorbed on glass-/tin-doped indium oxide substrates, analysis of dyes and metal ions in trace concentrations and characterization of the antioxidant properties of wine and wine products, using a variety of voltammetric techniques and electrodes. The most recent trends and advances in voltammetry are professionally commented.







Electroanalytical Methods


Book Description

This laboratory book delivers hands-on advice to researchers in all fields of life and physical sciences already applying or intending to apply electro-analytical methods in their research. The authors represent in a strictly practice-oriented manner not only the necessary theoretical background but also substantial know-how on measurement techniques, interpretation of data, experimental setup and trouble shooting. The author and the editor are well-known specialists in their field.




Square-Wave Voltammetry


Book Description

In a real tour-de-force of scientific publishing, three distinguished experts here systematically deliver both the underlying theory and the practical guidance needed to effectively apply square-wave voltammetry techniques. Square-wave voltammetry is a technique used in analytical applications and fundamental studies of electrode mechanisms. In order to take full advantage of this technique, a solid understanding of signal generation, thermodynamics, and kinetics is essential. Not only does this book cover all the necessary background and basics, but it also offers an appendix on mathematical modeling plus a chapter on electrode mechanisms that briefly reviews the numerical formulae needed to simulate experiments using popular software tools.




Cyclic Voltammetry and the Frontiers of Electrochemistry


Book Description

This text adopts an unique classification of electrochemical processes and introduces the subject in a stepwise fashion, from simple solution electrochemistry to photo-electrochemistry. The reader can thus obtain a comprehensive view of the recent trends in electrochemistry without serious difficulty.




Electrode Kinetics: Principles and Methodology


Book Description

Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide a comprehensive review of the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26 whilst Volume 27 deals with reactions at particular types of electrodes.Chapter 1 serves as an introduction to both volumes and is a survey of the fundamental principles of electrode kinetics. Chapter 2 deals with mass transport - how material gets to and from an electrode. Chapter 3 provides a review of linear sweep and cyclic voltammetry which constitutes an extensively used experimental technique in the field. Chapter 4 discusses a.c. and pulse methods which are a rich source of electrochemical information. Finally, chapter 5 discusses the use of electrodes in which there is forced convection, the so-called ``hydrodynamic electrodes''.




Electroorganic Synthesis


Book Description

This book provides the first practical, hands-on approach to electroorganic synthesis. It includes many details of the experimental design of cells, electrodes, electrolytes, and so on, as well as methods and reaction conditions for a large range of chemical transformations. By demonstrating the practicalities and versatility of electroorganic synthesis, this book encourages synthetic chemists to learn electrochemical methods for use in their daily activities.




Novel Trends in Electroorganic Synthesis


Book Description

Among the topics of interest to organic chemists today are the versatility and uniqueness of electrolysis procedures in organic synthesis, as well as the latest advances in methodology, including basic concepts for the design of electrolysis conditions and apparatus. The International Symposium on Electroorganic Synthesis met in Kurashiki, Japan, in September 1997 for lectures on all aspects of current research in the field. This volume comprising the papers from the symposium consists of two parts. Part I, Electrooxidation, includes papers on alcohols and phenols, olefins and aromatics, halogenation, polymers, and electrodes, among others. Included in Part II, Electroreduction, are papers on carbonyl compounds, halogen-containing compounds, reaction with EG bases, and metal complexes. The novel trends presented here will be of special interest to researchers and graduate students in electroorganic chemistry and are a valuable resource for all organic chemists.




Electroanalytical Methods


Book Description

Researchers and professionals will find a hands-on guide to successful experiments and applications of modern electroanalytical techniques here. The new edition has been completely revised and extended by a chapter on quartz-crystal microbalances. The book is written for chemists, biochemists, environmental and materials scientists, and physicists. A basic knowledge of chemistry and physics is sufficient for understanding the described methods. Electroanalytical techniques are particularly useful for qualitative and quantitative analysis of chemical, biochemical, and physical systems. Experienced experts provide the necessary theoretical background of electrochemistry and thoroughly describe frequently used measuring techniques. Special attention is given to experimental details and data evaluation.