SPATIAL PREDICTION OF BIOAVAILABILITY AND RISK OF LEAD IN URBAN SOILS TO CHILDREN


Book Description

Lead poisoning in young children is a concern in many urban areas, even 30 years after the banning of Pb-based paint and leaded gasoline. Soil and dust have been found to be prominent lead exposure pathways for children because young children often inadvertently ingest contaminated soil and dust through exploratory hand-to-mouth activities. In 2010, 16.6% of 6,550 children tested in Toledo, OH had blood lead levels (BLLs) above the CDC lead poisoning reference level of 5 μg/dL. The objectives of this study were 1) to quantify the concentration and distribution of total and bioavailable lead in soils of Toledo, OH; 2) to relate total lead and bioavailable lead in soils to BLLs in children; and 3) to model the relationship between BLLs in children and spatial variables such as housing age and road density. Outreach education served as a means to educate students about the dangers of soil lead as well as the importance of sampling protocols in science. Students in Toledo area schools were instructed on proper USEPA soil sampling guidelines and were asked to collect soil samples from their yards. A subsample of 81 soils was analyzed for total lead and bioavailable lead. Site-specific total lead and bioavailability data were used in the USEPA Integrated Exposure Uptake and Biokinetic (IEUBK) model to predict BLLs for children under 7 years of age. A spatial index model was derived using fuzzy sets, analytical hierarchy process (AHP) and weighted linear combination (WLC) to relate 6 spatial predictor variables to the predicted BLLs. It was found that 8.6% of sampled sites had total lead concentrations above the USEPA action level of 400 mg/kg, but 28.4% of soils samples yielded predicted elevated BLLs, suggesting the action level is set too high. The majority of soil samples had lead bioavailability values above 60%, thus increasing the risk of lead poisoning. The spatial variables influencing risk of lead poisoning from most important to least important were age of housing, road density, percent impervious surfaces, home value, household income and soil type. The data predict that lead poisoning disproportionately affects children from low socioeconomic status families.




Lead: Its Effects on Environment and Health


Book Description

Volume 17, entitled Lead: Its Effects on Environment and Health of the series Metal Ions in Life Sciences centers on the interrelations between biosystems and lead. The book provides an up-to-date review of the bioinorganic chemistry of this metal and its ions; it covers the biogeochemistry of lead, its use (not only as gasoline additive) and anthropogenic release into the environment, its cycling and speciation in the atmosphere, in waters, soils, and sediments, and also in mammalian organs. The analytical tools to determine and to quantify this toxic element in blood, saliva, urine, hair, etc. are described. The properties of lead(II) complexes formed with amino acids, peptides, proteins (including metallothioneins), nucleobases, nucleotides, nucleic acids, and other ligands of biological relevance are summarized for the solid state and for aqueous solutions as well. All this is important for obtaining a coherent picture on the properties of lead, its effects on plants and toxic actions on mammalian organs. This and more is treated in an authoritative and timely manner in the 16 stimulating chapters of Volume 17, which are written by 36 internationally recognized experts from 13 nations. The impact of this recently again vibrant research area is manifested in nearly 2000 references, over 50 tables and more than 100 illustrations (half in color). Lead: Its Effects on Environment and Health is an essential resource for scientists working in the wide range from material sciences, inorganic biochemistry all the way through to medicine including the clinic ... not forgetting that it also provides excellent information for teaching.




Leaded Gasoline Phase-out


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Airborne Lead Reduction Act of 1984


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Lead Toxicity


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Revival: Lead in Soil (1993)


Book Description

Until the publication of this new book there had been a lack of well-founded guidelines for evaluating concentrations of lead in soil and its relationship to human health. Thus, much confusion has existed among regulatory agencies, industries, public health officials, and the medical community about the evaluation and remedying of lead-contaminated soils. Lead in Soil: Recommended Guidelines represents the combined efforts of a multi-disciplinary international task force from the Society for Environmental Geochemistry and Health (SEGH) whose members are experts in the fields of lead pollution and toxicology. It provides an international consensus concerning environmental lead and blood lead-especially in children. The task force evaluated the evidence and made recommendations for guidelines to appraise lead concentration. It also studied the influence of soil and other sources of lead on blood lead concentrations. A model was prepared that allows the user to select appropriate target levels of blood lead while allowing for a variety of environmental situations or regulatory criteria.




A Soil Fertility Test


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