Effect of Hydrogen on Irradiation Creep and Growth for ZIRLO Alloy and Zr-1.0Nb


Book Description

The impact of hydrogen on the irradiation growth and creep of stress-relief annealed (SRA) ZIRLO® alloy and recrystallized annealed (RXA) Zr-1.0Nb cladding tubes is evaluated in this paper. The samples were charged with hydrogen in the range of approximately 160-720 ppm using the gaseous method. Biaxial in-reactor creep tests were performed after Cycle 1, Cycle 2, Cycle 3, and Cycle 4, on both as-received and precharged hydrogen cladding tubes. Outside diameter and axial length measurements were performed on the samples. The results showed that hydrogen had no effect on the axial irradiation creep but a relatively large effect on the axial irradiation growth. Increasing hydrogen decreased the axial irradiation growth in RXA Zr-1.0 Nb, which was opposite from the behavior of SRA ZIRLO cladding. This unique hydrogen effect on the irradiation axial growth of RXA Zr-1.0Nb could be due to the different intergranular stress resulting from the fabrication process or the absence of alloying elements, including tin. The total axial strain of both Zr-1.0Nb and SRA ZIRLO cladding increased with increasing fast fluence, and Zr-1.0Nb increased at a faster rate relative to SRA ZIRLO cladding. In the diameter direction, hydrogen had a minimal effect on the total diameter strain and the diameter irradiation creep strain for both SRA ZIRLO samples and the RXA Zr-1.0Nb sample. This finding from in-reactor test is contrary to the out-reactor tests results from the literature that have shown that hydrogen significantly decreases thermal creep. The total diameter strain and diameter irradiation creep behavior for the SRA ZIRLO samples and RXA Zr-1.0Nb were similar.







Effect of Alloying Elements, Cold Work, and Hydrogen on the Irradiation-Induced Growth Behavior of Zirconium Alloy Variants


Book Description

In-reactor dimensional changes in zirconium-based alloys result from a complex interplay of many factors, such as (1) alloy type and composition, including the addition of elements such as niobium, iron, and tin; (2) fabrication process, including cold work, texture, and residual stresses; (3) irradiation temperature; and (4) hydrogen levels. In many cases, the observed dimensional changes in light water reactor fuel-assembly components--especially at high exposures--cannot be fully explained based on current growth and creep models. Therefore, a systematic approach was taken in this multiyear (2005-2011) Nuclear Fuel Industry Research Program investigation. The objective was to measure stress-free irradiation-induced growth (IIG) of specially fabricated alloys through irradiation under controlled conditions in the BOR-60 fast-flux test reactor up to a high fluence of approximately 2 x 1026 m-2 (E > 1 MeV)--equivalent to maximum of approximately 37 dpa exposure--followed by postirradiation examinations (PIEs). Irradiation temperature was within a narrow temperature range (320 ± 10°C). The PIEs included dimensional-change and microhardness measurements, metallography and hydride etching, and scanning transmission electron microscopy (STEM) or transmission electron microscopy (TEM).



















Irradiation Creep and Growth in Zirconium During Proton Bombardment


Book Description

The irradiation creep and growth behavior of zirconium alloys has been studied during irradiation with 3.5-MeV protons. Irradiations were carried out at temperatures in the range 423 to 623 K and strain measurements were recorded up to displacement levels of 0.03 displacements per atom (dpa). In annealed materials, a significant portion of the measured strain could be attributed to the presence of dislocation loops. The measured growth strain was found to be dependent on texture, grain dimensions, network dislocation structure (cold work), and temperature. Experiments to separate the irradiation creep and growth components of the total strain revealed that irradiation growth was by far the most significant component in cold-worked zirconium-niobium alloys but that the two components were approximately equal in annealed crystal bar zirconium specimens. An investigation of transient effects revealed that no strain transient was observed when the irradiation flux was removed. The strain rate was found to be proportional to the applied stress (at low stresses) and to the damage rate.




Peculiarities of Structural and Behavioral Changes of Some Zirconium Alloys at Damage Doses of Up to 50 Dpa


Book Description

The irradiation-induced damage of zirconium alloys subjected to neutron irradiation up to dose levels of ~50 dpa was investigated. Specimens of unalloyed zirconium, Zr-1%Nb, Zr-2.5%Nb and Zr-1%Nb-1.3%Sn-0.4%Fe were irradiated in the BOR-60 reactor over the temperature range 320-420°C. The dose dependence of the irradiation growth strain increased sharply in zirconium and Zr-Nb irradiated at ~350°C at doses above ~10 dpa. In the case of Zr-1%Nb-1.3%Sn-0.4%Fe, it increased at doses of ~37 dpa. Upon increasing the irradiation temperature to 420°C, a sharp accelerated irradiation growth of the Zr-1%Nb alloy began shifting up to about 30 dpa. For the Zr- 1%Nb-1.3%Sn-0.4%Fe, no change of the irradiation growth rate was observed up to a dose of 55 dpa. The onset of increased irradiation growth in alloys correlates with the occurrence of c-component dislocation loops which coincides with a loss of coherence of finely-dispersed precipitates. Post-irradiation annealing experiments demonstrated that a delay in loop formation leads to displacement of the "break-away" beginning in the dose dependence of the irradiation growth in the direction of high doses. The a+c-type dislocation loops were also formed in Zr-1%Nb alloy at high doses, but their influence on the change of macroscopic properties was not observed.