Electron Transfer Reactions in Organic Chemistry


Book Description

The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.







Electron Transfer Reactions in Organic Chemistry


Book Description

The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.







Hydrogen Transfer Reactions


Book Description

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.










Electron Transfer in Chemistry, Principles, Theories, Methods, and Techniques


Book Description

Electron transfer is the most important process to take place in natural and artificial chemical systems, playing a fundamental role, for example, in photosynthesis as well as in photography. Electron transfer reactions - oxidations and reductions - are involved in, among others, a variety of energy conversion processes, analytical methods, synthetic strategies, and information processing systems. This five-volume work is the only comprehensive yet up-to-date reference on electron transfer processes. Following a foreword by Nobel prize-winner R. A. Marcus, renowned experts from all over the world provide an interdisciplinary overview of every aspect of electron transfer including theoretical-physicochemical backgrounds, latest analytical techniques to identify, monitor and measure the rate of electron transfer, utilizing electron transfer reactions in organic synthesis and catalysis, electron transfer in the gas phase or in special heterogeneous systems such as zeolites or sensitized electrodes. Other central issues are the study of biological systems and the biomimetic electron transfer processes in artificial supramolecular systems. Finally, a complete volume is dedicated to the application of electron transfer in molecular-level electronics, imaging processes and energy conversion. Each chapter is complemented by numerous tables, formulae and illustrations providing an indispensable wealth of information. All references are cross-indexed throughout the work for easy access to this highly complex topic. Whether for quickly looking-up a keyword or as a thorough introduction to a special aspect, this is an essential handbook for everyone working in the field, from experts to postgraduates, from synthetic chemists, physicochemists or biochemists to research groups in material sciences.




Radical Reactions in Organic Synthesis


Book Description

Introduction and some general concepts. -- General principles: chain reactions based on stannane chemistry. -- Further chain reactions of stannanes. -- Organo-silicon, -germanium, and -mercury hydrides. -- The Barton decarboxylation and related reactions. -- Atom and group transfer reactions. -- The persistent radical effect: non-chain processes. -- Redox processes. -- Some concluding remarks.




Electron Transfer Reactions


Book Description

Begins with a historical overview by Henry Taube. Overviews the advances pioneered by Taube, including mechanisms of electron transfer reactions, charge transfer complexes, and *p back bonding effects in metal-ligand interactions. Discusses applications of principles of electron transfer to diverse areas of chemistry and biology such as the selective and controlled oxidation of organic functional groups, polymerization catalysis, metal biological interactions with DNA, biological electron transfer reactions, and new imaging agents in diagnostic medicine.