Lignocellulosic Biomass to Liquid Biofuels


Book Description

Lignocellulosic Biomass to Liquid Biofuels explores the existing technologies and most recent developments for the production of second generation liquid biofuels, providing an introduction to lignocellulosic biomass and the processes for its conversion into biofuels. The book demonstrates biorefinery concepts compared with petro refinery, as well as the challenges of second generation biofuels processing. In addition to current pre-treatment techniques and their technical, environmental and economic implications, chapters included also further examine the particularities of conversion processes for bioethanol, biobutanol and biodiesel through chemical, biochemical and combined approaches. Finally, the book looks into concepts and tools for techno-economic and environmental analysis, which include supply chain assessment, by-products, zero-waste techniques and process evaluation and optimization. Lignocellulosic Biomass to Liquid Biofuels is particularly useful for researchers in the field of liquid biofuels seeking alternative chemical and biochemical pathways or those interested advanced methods to calculate maximum yield for each process and methods to simulate the implications and costs of scaling up. Furthermore, with the introduction provided by this volume, researchers and graduate students entering the field will be able to quickly get up to speed and identify knowledge gaps in existing and upcoming technology the book's comprehensive overview. - Examines the state-of-the-art technology for liquid biofuels production from lignocellulosic biomass - Provides a comprehensive overview of the existing chemical and biochemical processes for second generation biofuel conversion - Presents tools for the techno-economic and environmental analysis of technologies, as well as for the scale-up simulation of conversion processes




Enzymatic Conversion of Biomass for Fuels Production


Book Description

Discusses the use of enzymatic and microbial biocatalysis for transformation of biomass to liquid or gaseous fuels. Explores metabolic pathway engineering. Discusses characterization of new hydrolytic enzymes. Presents new microorganisms and fermentation techniques. Focuses on lignocellulosic biomass conversion technology.




Lignocellulose Conversion


Book Description

Bioethanol has been recognized as a potential alternative to petroleum-derived transportation fuels. Even if cellulosic biomass is less expensive than corn and sugarcane, the higher costs for its conversion make the near-term price of cellulosic ethanol higher than that of corn ethanol and even more than that of sugarcane ethanol. Conventional process for bioethanol production from lignocellulose includes a chemical/physical pre-treatment of lignocellulose for lignin removal, mostly based on auto hydrolysis and acid hydrolysis, followed by saccharification of the free accessible cellulose portions of the biomass. The highest yields of fermentable sugars from cellulose portion are achieved by means of enzymatic hydrolysis, currently carried out using a mix of cellulases from the fungus Trichoderma reesei. Reduction of (hemi)cellulases production costs is strongly required to increase competitiveness of second generation bioethanol production. The final step is the fermentation of sugars obtained from saccharification, typically performed by the yeast Saccharomyces cerevisiae. The current process is optimized for 6-carbon sugars fermentation, since most of yeasts cannot ferment 5-carbon sugars. Thus, research is aimed at exploring new engineered yeasts abilities to co-ferment 5- and 6-carbon sugars. Among the main routes to advance cellulosic ethanol, consolidate bio-processing, namely direct conversion of biomass into ethanol by a genetically modified microbes, holds tremendous potential to reduce ethanol production costs. Finally, the use of all the components of lignocellulose to produce a large spectra of biobased products is another challenge for further improving competitiveness of second generation bioethanol production, developing a biorefinery.




The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals


Book Description

The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals describes the importance of catalysis for the sustainable production of biofuels and biochemicals, focused primarily on the state-of-the-art catalysts and catalytic processes expected to play a decisive role in the "green" production of fuels and chemicals from biomass. In addition, the book includes general elements regarding the entire chain of biomass production, conversion, environment, economy, and life-cycle assessment. Very few books are available on catalysis in production schemes using biomass or its primary conversion products, such as bio-oil and lignin. This book fills that gap with detailed discussions of: - Catalytic pyrolysis of lignocellulosic biomass - Hybrid biogasoline by co-processing in FCC units - Fischer-Tropsch synthesis to biofuels (biomass-to-liquid process) - Steam reforming of bio-oils to hydrogen With energy prices rapidly rising, environmental concerns growing, and regulatory apparatus evolving, this book is a resource with tutorial, research, and technological value for chemists, chemical engineers, policymakers, and students. - Includes catalytic reaction mechanism schemes and gives a clear understanding of catalytic processes - Includes flow diagrams of bench-, pilot- and industrial-scale catalytic processing units and demonstrates the various process technologies involved, enabling easy selection of the best process - Incorporates many tables, enabling easy comparison of data based on a critical review of the available literature




Biorefinery: From Biomass to Chemicals and Fuels


Book Description

This book provides an introduction to the basic science and technologies for the conversion of biomass (terrestrial and aquatic) into chemicals and fuels, as well as an overview of innovations in the field. The entire value chain for converting raw materials into platform molecules and their transformation into final products are presented in detail. Both cellulosic and oleaginous biomass are considered. The book contains contributions by both academic scientists and industrial technologists so that each topic combines state-of-the-art scientific knowledge with innovative technologies relevant to chemical industries. Selected topics include: Refinery of the future: feedstock, processes, products The terrestrial and aquatic biomass production and properties Chemical technologies and biotechnologies for the conversion of cellulose, hemicellulose, lignine, algae, residual biomass Thermal, catalytic and enzymatic conversion of biomass Production of chemicals, polymeric materials, fuels (biogas, biodiesel, bioethanol, biohydrogen) Policy aspects of biomass product chains LCA applied to the energetic, economic and environmental evaluation of the production of fuels from biomass: ethanol, biooil and biodiesel, biogas, biohydrogen




Lignocellulosic Biomass to Value-Added Products


Book Description

Lignocellulosic Biomass to Value-Added Products: Fundamental Strategies and Technological Advancements focuses on fundamental and advanced topics surrounding technologies for the conversion process of lignocellulosic biomass. Each and every concept related to the utilization of biomass in the process of conversion is elaborately explained, with importance given to minute details. Advanced level technologies involved in the conversion of biomass into biofuels, like bioethanol and biobutanol, are addressed, along with the process of pyrolysis. Readers of this book will become fully acquainted with the field of lignocellulosic conversion, from its basics to current research accomplishments. The uniqueness of the book lies in the fact that it covers each and every topic related to biomass and its conversion into value-added products. Technologies involved in the major areas of pretreatment, hydrolysis and fermentation are explained precisely. Additional emphasis is given to the analytical part, especially the established protocols for rapid and accurate quantification of total sugars obtained from lignocellulosic biomass. - Includes chapters arranged in a flow-through manner - Discusses mechanistic insights in different phenomena using colorful figures for quick understanding - Provides the most up-to-date information on all aspects of the conversion of individual components of lignocellulosic biomass




Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals


Book Description

Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals. Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances. Topics covered include: • The importance of biomass conversion to fuels • The role of pretreatment in biological and chemical conversion of biomass • Composition and structure of biomass, and recalcitrance to conversion • Fundamentals of biomass pretreatment at low, neutral and high pH • Ionic liquid and organosolv pretreatments to fractionate biomass • Comparative data for application of leading pretreatments and effect of enzyme formulations • Physical and chemical features of pretreated biomass • Economics of pretreatment for biological processing • Methods of analysis and enzymatic conversion of biomass streams • Experimental pretreatment systems from multiwell plates to pilot plant operations This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.




Recent Advances in Bioconversion of Lignocellulose to Biofuels and Value Added Chemicals within the Biorefinery Concept


Book Description

Recent Advances in Bioconversion of Lignocellulose to Biofuels and Value Added Chemicals within the Biorefinery Concept covers the latest developments on biorefineries, along with their potential use for the transformation of residues into a broad range of more valuable products. Within this context, the book discusses the enzymatic conversion process of lignocellulosic biomass to generate fuels and other products in a unified approach. It focuses on new approaches to increase enzymatic production by microorganisms, the action of microbial inhibitors, and strategies for their removal. Furthermore, it outlines the benefits of this integrated approach for generating value-added products and the benefits to social and economic aspects, circular bio economy, HUBs and perspectives. - Covers the mechanisms of enzymatic conversion of biomass into value-added products - Discusses bioproducts derived from lignocellulose and their applications - Includes discussions on design, development and the technologies needed for the sustainable manufacture of materials and chemicals - Offers a techno-economic evaluation of biorefineries for integrated sustainability assessments - Discusses the socioeconomic and cultural-economic perspectives of the lignocellulosic biorefinery - Presents a virtual biorefinery as an integrated approach to evaluate the lignocellulose production chain




Pretreatment of Lignocellulosic Biomass for Biofuel Production


Book Description

The book describes the pretreatment of lignocellulosic biomass for biomass-to-biofuel conversion processes, which is an important step in increasing ethanol production for biofuels. It also highlights the main challenges and suggests possible ways to make these technologies feasible for the biofuel industry. The biological conversion of cellulosic biomass into bioethanol is based on the chemical and biological breakdown of biomass into aqueous sugars, for example using hydrolytic enzymes. The fermentable sugars can then be further processed into ethanol or other advanced biofuels. Pretreatment is required to break down the lignin structure and disrupt the crystalline structure of cellulose so that the acids or enzymes can easily access and hydrolyze the cellulose. Pre-treatment can be the most expensive process in converting biomass to fuel, but there is great potential for improving the efficiency and lowering costs through further research and development. This book is aimed at academics and industrial practitioners who are interested in the higher production of ethanol for biofuels.




Process Intensification


Book Description

Process Intensification: Engineering for Efficiency, Sustainability and Flexibility is the first book to provide a practical working guide to understanding process intensification (PI) and developing successful PI solutions and applications in chemical process, civil, environmental, energy, pharmaceutical, biological, and biochemical systems. Process intensification is a chemical and process design approach that leads to substantially smaller, cleaner, safer, and more energy efficient process technology. It improves process flexibility, product quality, speed to market and inherent safety, with a reduced environmental footprint. This book represents a valuable resource for engineers working with leading-edge process technologies, and those involved research and development of chemical, process, environmental, pharmaceutical, and bioscience systems. - No other reference covers both the technology and application of PI, addressing fundamentals, industry applications, and including a development and implementation guide - Covers hot and high growth topics, including emission prevention, sustainable design, and pinch analysis - World-class authors: Colin Ramshaw pioneered PI at ICI and is widely credited as the father of the technology