Nonequilibrium Thermodynamics


Book Description

Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts - A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes - Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories - Has 198 fully solved examples and 287 practice problems - An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]




Extended Irreversible Thermodynamics


Book Description

Problems after each chapter




Non-equilibrium Statistical Thermodynamics


Book Description

This book stresses the role of uncorrelated exchange of properties between macroscopic systems and their surroundings as the only source of dynamic irreversibility. To that end, fundamentals of statistical thermodynamics extended to the non-equilibrium are worked out carefully. The principles are then applied to selected problems in classical fluid dynamics. Transport coefficients are first derived from basic laws. This is followed by a full discussion of transitions to dissipative structures in selected systems far removed from equilibrium (B‚nard and Taylor vortices, calculation of the critical Reynolds number for transition to turbulence in Poiseuille flow). The final part focuses on interaction of matter with light. Fundamentals are extended towards quantum-mechanical systems. Applied to coherent radiation and its interaction with matter, the proposed thermodynamic treatment introduces an original discussion into the quantum nature of micro-physics.The book questions and reconsiders a deeply rooted paradigm in macroscopic dynamics concerning the cause of irreversibility. The new proposal is illustrated by application to a couple of well documented non-equilibrium domains, namely fluid dynamics and laser physics.




Understanding Non-equilibrium Thermodynamics


Book Description

Discover the many facets of non-equilibrium thermodynamics. The first part of this book describes the current thermodynamic formalism recognized as the classical theory. The second part focuses on different approaches. Throughout the presentation, the emphasis is on problem-solving applications. To help build your understanding, some problems have been analyzed using several formalisms to underscore their differences and their similarities.




Non-equilibrium Thermodynamics For Engineering Applications


Book Description

This book presents the theory of non-equilibrium thermodynamics in a pedagogical and practical way that targets engineering applications. In it, tools to take advantage of the second as well as the first law of thermodynamics are provided.The book starts by explaining how the entropy production is the cornerstone of non-equilibrium thermodynamics — the basis to describe coupled transport phenomena, which are highly relevant for several renewable energy technologies. The book also uses entropy production as the foundation for a systematic methodology to analyze and improve energy efficiency, and shows how entropy production can be used to test the consistency of transport models. The link between transport theory and energy efficiency is also shown, and the relationship to exergy analysis is demonstrated. The theory is applied using examples from practical cases like evaporation, heat exchange, reactor optimization, distillation and more.Non-Equilibrium Thermodynamics for Engineering Applications may be used as a textbook for undergraduate and graduate university curricula containing thermodynamics or energy conversion issues at large, chemical and mechanical engineering, applied chemistry and applied physics.




Extended Thermodynamics


Book Description

Physicists firmly believe that the differential equations of nature should be hyperbolic so as to exclude action at a distance; yet the equations of irreversible thermodynamics - those of Navier-Stokes and Fourier - are parabolic. This incompatibility between the expectation of physicists and the classical laws of thermodynamics has prompted the formulation of extended thermodynamics. After describing the motifs and early evolution of this new branch of irreversible thermodynamics, the authors apply the theory to mon-atomic gases, mixtures of gases, relativistic gases, and "gases" of phonons and photons. The discussion brings into perspective the various phenomena called second sound, such as heat propagation, propagation of shear stress and concentration, and the second sound in liquid helium. The formal mathematical structure of extended thermodynamics is exposed and the theory is shown to be fully compatible with the kinetic theory of gases. The study closes with the testing of extended thermodynamics through the exploitation of its predictions for measurements of light scattering and sound propagation.




Introduction to Non-equilibrium Physical Chemistry


Book Description

Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. - The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium - Experimental studies have been reported which provide test of the theories and their limitations - Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed




Non-equilibrium Thermodynamics and Statistical Mechanics


Book Description

`Non-equilibrium Thermodynamics and Statistical Mechanics: Foundations and Applications' builds from basic principles to advanced techniques, and covers the major phenomena, methods, and results of time-dependent systems. It is a pedagogic introduction, a comprehensive reference manual, and an original research monograph. Uniquely, the book treats time-dependent systems by close analogy with their static counterparts, with most of the familiar results of equilibrium thermodynamics and statistical mechanics being generalized and applied to the non-equilibrium case. The book is notable for its unified treatment of thermodynamics, hydrodynamics, stochastic processes, and statistical mechanics, for its self-contained, coherent derivation of a variety of non-equilibrium theorems, and for its quantitative tests against experimental measurements and computer simulations. Systems that evolve in time are more common than static systems, and yet until recently they lacked any over-arching theory. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is unique in its unified presentation of the theory of non-equilibrium systems, which has now reached the stage of quantitative experimental and computational verification. The novel perspective and deep understanding that this book brings offers the opportunity for new direction and growth in the study of time-dependent phenomena. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is an invaluable reference manual for experts already working in the field. Research scientists from different disciplines will find the overview of time-dependent systems stimulating and thought-provoking. Lecturers in physics and chemistry will be excited by many fresh ideas and topics, insightful explanations, and new approaches. Graduate students will benefit from its lucid reasoning and its coherent approach, as well as from the chem12physof mathematical techniques, derivations, and computer algorithms.




Extended Non-Equilibrium Thermodynamics


Book Description

Extended Non-Equilibrium Thermodynamics provides powerful tools departing not from empirical or statistical considerations but from fundamental thermodynamic laws, proposing final solutions that are readily usable and recognizable for students, researchers and industry. The book deals with methods that allow combining easily the present theory with other fields of science, such as fluid and solid mechanics, heat and mass transfer processes, electricity and thermoelectricity, and so on. Not only are such combinations facilitated, but they are incorporated into the developments in such a way that they become part of the theory. This book aims at providing for a systematic presentation of Extended Non-Equilibrium Thermodynamics in nanosystems with a high degree of applicability. Furthermore, the book deals with how physical properties of systems behave as a function of their size. Moreover, it provides for a systematic approach to understand the behavior of thermal, electrical, thermoelectric, photovoltaic and nanofluid properties in nanosystems. Experimental results are used to validate the theory, the comparison is analysed, justified and discussed, and the theory is then again used to understand better experimental observations. The new developments in this book, being recognizable in relation with familiar concepts, should make it appealing for academics and researchers to teach and apply and graduate students to use. The text in this book is intended to bring attention to how the theory can be applied to real-life applications in nanoscaled environments. Case studies, and applications of theories, are explored including thereby nanoporous systems, solar panels, nanomedicine drug permeation and properties of nanoporous scaffolds. Explores new generalized thermodynamic models Provides introductory context of Extended Non-Equilibrium Thermodynamics within classical thermodynamics, theoretical fundamentals and several applications in nanosystems Provides for a systematic approach to understand the behavior of thermal, electric, thermoelectric and viscous properties as a function of several parameters in nanosystems Includes reflections to encourage the reader to think further and put the information into context Examines future developments of new constitutive equations and theories and places them in the framework of real-life applications in the energetic and medical sectors, such as photovoltaic and thermoelectric devices, nanoporous media, drug delivery and scaffolds




Non-Equilibrium Statistical Mechanics


Book Description

Groundbreaking monograph by Nobel Prize winner for researchers and graduate students covers Liouville equation, anharmonic solids, Brownian motion, weakly coupled gases, scattering theory and short-range forces, general kinetic equations, more. 1962 edition.