Non-Equilibrium Dynamics in Chemical Systems


Book Description

Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.




Encyclopedia of Physical Organic Chemistry, 6 Volume Set


Book Description

Winner of 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE This encyclopedia offers a comprehensive and easy reference to physical organic chemistry (POC) methodology and techniques. It puts POC, a classical and fundamental discipline of chemistry, into the context of modern and dynamic fields like biochemical processes, materials science, and molecular electronics. Covers basic terms and theories into organic reactions and mechanisms, molecular designs and syntheses, tools and experimental techniques, and applications and future directions Includes coverage of green chemistry and polymerization reactions Reviews different strategies for molecular design and synthesis of functional molecules Discusses computational methods, software packages, and more than 34 kinds of spectroscopies and techniques for studying structures and mechanisms Explores applications in areas from biology to materials science The Encyclopedia of Physical Organic Chemistry has won the 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE. The PROSE Awards recognize the best books, journals and digital content produced by professional and scholarly publishers. Submissions are reviewed by a panel of 18 judges that includes editors, academics, publishers and research librarians who evaluate each work for its contribution to professional and scholarly publishing. You can find out more at: proseawards.com Also available as an online edition for your library, for more details visit Wiley Online Library




Selforganization by Nonlinear Irreversible Processes


Book Description

These Proceedings contain invited lectures presented at the third Interna tional Conference on "Irreversible Processes and Dissipative Structures" in Kiihlungsborn (German Democratic Republic) in March, 1985. These con ferences, the first of which was held in Rostock in 1977 and the second in Berlin in 1982, are devoted to the study of irreversible processes far from thermal equilibrium and to the phenomena of selforganization. The meet ing in Kiihlungsborn brought together some 160 mathematicians, physicists, chemists and biologists from 10 countries, who are all interested in the inter disciplinary field of synergetics. The main topics of the conference were basic concepts of selforganization and evolution, such as entropy, instabilities, nucleation, dissipative struc tures, chaos and turbulence. The contributions cover methods from ther modynamics, the theory of dynamic systems, stochastic and statistic theory, the method of Green's functions, the fluctuation-dissipation theorem, etc. Several problems are studied in more detail, e.g., the kinetics of nucleation especially in finite systems, the dynamics of interfaces, reaction-diffusion sys tems, chemical and biochemical pattern formation and information process ing. Further, several contributions are devoted to the development of the concepts of chaos and turbulence. The editors hope that the contributions collected in this volume will pro vide some new information about the field of selforganization, which is in full development now.







Temporal Disorder in Human Oscillatory Systems


Book Description

Rhythms of the heart and of the nervous and endocrine system, breathing, locomotory movements, sleep, circadian rhythms and tissue cell cycles are major elements of the temporal order of man. The dynamics of these systems are characterized by changes in the properties of an oscillator, transitions from oscillatory states into chaotic or stationary states, and vice versa, coupling or uncoupling between two or more oscillators. Any deviation from the normal range to either more or less ordered states may be defined as temporal disorder. Pathological changes of temporal organization, such as tremor, epileptic seizures, Cheyne-Stokes breathing, cardiac arrhythmicities and circadian desynchronization, may be caused by small changes in the order (control) parameters. One major aspect of the symposium was the analysis of characteristic features of these temporal control systems, including nonlinear dynamics of interactions, positive, negative and mixed feedback systems, temporal delays, and their mathematical description and modelling. The ultimate goal is a better understanding of the principles of temporal organization in order to treat periodic diseases or other perturbations of "normal" dynamics in human oscillatory systems.




Computational Systems — Natural and Artificial


Book Description

This book contains the invited papers presented at an international sympo sium held at Schloss Elmau, Bavaria (FRG), May 4-9, 1987. Leading experts from neurobiology, medicine, physics, and the computer sciences joined to gether to present and discuss their most recent results. A particular example of the natural computational systems discussed is the visual system of man and animals. A bridge between neural networks and physical systems is provided by spin glass models of neural networks, which were also treated. Concrete realizations of new kinds of devices in microelectronics were among the further topics, as were general problems on the calculation of chaotic orbits. In this way these proceedings present a number of quite recent ap proaches to problems which are of great current interest in fields concerned with computational systems. Bringing together scientists from neurobiology, physics, and the computer sciences has been one of the main aims of the synergetics enterprise, and in particular of its international symposia, from the very beginning. For exam ple, its first meeting held in 1972 at Schloss Elmau included, among others, papers by R. Landauer and J. W. F. Woo on cooperative phenomena in data processing, by W. Reichardt on mechanisms of pattern recognition by the visual system of insects, by B. Julesz on stereoscopic depth perception, and by H. R. Wilson on cooperative phenomena in a homogeneous cortical tissue model. Whole meetings and the corresponding proceedings were devoted to these problems, e. g.







Selforganization in Complex Systems: The Past, Present, and Future of Synergetics


Book Description

This proceedings volume contains talks and poster presentations from the International Symposium "Self-Organization in Complex Systems: The Past, Present, and Future of Synergetics", which took place at Hanse-Wissenschaftskolleg, an Institute of Advanced Studies, in Delmenhorst, Germany, during the period November 13 - 16, 2012. The Symposium was organized in honour of Hermann Haken, who celebrated his 85th birthday in 2012. With his fundamental theory of Synergetics he had laid the mathematical-physical basis for describing and analyzing self-organization processes in a diversity of fields of research. The quest for common and universal principles of self-organization in complex systems was clearly covered by the wide range of interdisciplinary topics reported during the Symposium. These extended from complexity in classical systems and quantum systems over self-organisation in neuroscience even to the physics of finance. Moreover, by combining a historical view with a present status report the Symposium conveyed an impression of the allure and potency of this branch of research as well as its applicability in the future.




Complex Systems — Operational Approaches in Neurobiology, Physics, and Computers


Book Description

A great deal of the success of science has rested on its specific methods. One of which has been to start with the study of simple phenomena such as that of falling bodies, or to decompose systems into parts with well-defined properties simpler than those of the total system. In our time there is a growing awareness that in many cases of great practical or scientific interest, such as economics or the hu man brain, we have to deal with truly complex systems which cannot be decomposed into their parts without losing crucial properties of the total system. In addi tion, complex systems have many facets and can be looked at from many points of view. Whenever a complicated problem arises, some scientists or other people are ready to invent lots of beautiful words, or to quote Goethe "denn immer wo Begriffe feh len, dort stellt ein Wort zur rechten Zeit sich ein" ("whenever concepts are lack king, a word appears at the right time"). Quite often such a procedure gives not only the layman but also scientists working in fields different from that of the in ventor of these new words the impression that this problem has been solved, and I am occasionally shocked to see how influential this kind of "linguistics" has become.