Determination of Selected Heavy Metals in River Mukurumudzi to Establish Potential Contamination from Land Based Activities and Sources


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Master's Thesis from the year 2018 in the subject Environmental Sciences, grade: 76, , language: English, abstract: Rivers are the major sources of water being used in cities and its environs. This water may either be treated or untreated. River banks could be very busy, varied activities ranging from farming to industrial activities and other domestic household activities are conducted. The present study aimed at investigating the potential sources of selected heavy metal contaminants in River Mukurumudzi, Kwale County. Water and sediments were sampled in four points along the river impacted by mining, human settlements and agricultural activities for three different seasons. The samples were analyzed for Iron, Lead, Cadmium, Copper and Arsenic using an AAS. Sediment quality was also analysed by the calculation of CF and I-geo values. Interpretation of results was conducted using Minitab statistical software and Excel spreadsheets. The range of metals in water during the dry season was Fe (0.19-0.32) mg/l, Pb, Cu, Cd and As were below the detection limits. The range of metals in water during the short rain was Fe (0.12-1.25) mg/l and BDL for all other analysed metals. The range of metals in water during the long rain season was Fe (0.07-1.82) mg/l, Cu (0.08-0.11) mg/l and BDL for all the other analysed metals. The range of metals in sediments during dry season was Fe (0.13-1.44) ppm, Pb (0.08-0.54) ppm, and BDL for all other analysed metals. The range of metals in sediments during short rain season was Fe (0.23-1.73) ppm, Pb (0.12-0.27) ppm, and BDL for all other analysed metals. The range of metals in sediments during the long rain season was Fe (0.25-2.75) ppm, Pb (0.09-0.34) ppm, Cu (0.10-0.14) ppm, and BDL for all other analysed metals. The CF values for sediments were all




Metals in the Hydrocycle


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Geochemical and Hydrological Reactivity of Heavy Metals in Soils


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The hydrological and geochemical interactions between clay minerals and organic matter in soils directly influence the reaction, behavior, and mobility of heavy metals in soils. Geochemical and Hydrological Reactivity of Heavy Metals in Soils is one of few books that comprehensively illustrates this cause-and-effect relationship. It highlights anal




Metal Pollution in the Aquatic Environment


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Aquatic chemistry is becoming both a rewarding and substantial area of inquiry and is drawing many prominent scientists to its fold. Its literature has changed from a compilation of compositional tables to studies of the chemical reactions occurring within the aquatic environments. But more than this is the recognition that human society in part is determining the nature of aquatic systems. Since rivers deliver to the world ocean most of its dissolved and particulate components, the interactions of these two sets of waters determine the vitality of our coastal waters. This significant vol ume provides not only an introduction to the dynamics of aquatic chem istries but also identifies those materials that jeopardize the resources of both the marine and fluvial domains. Its very title provides its emphasis but clearly not its breadth in considering natural processes. The book will be of great value to those environmental scientists who are dedicated to keeping the resources of the hydrosphere renewable. As the size of the world population becomes larger in the near future and as the uses of materials and energy show parallel increases, the rivers and oceans must be considered as a resource to accept some of the wastes of society. The ability of these waters and the sediments below them to accommodate wastes must be assessed continually. The key questions relate to the capacities of aqueous systems to carry one or more pollutants.







Heavy Metals


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"Heavy Metals: Problems and Solutions" is divided into three sections dealing with basic geochemical processes, remediation and case studies. The basic geochemical processes are discussed with respect to mobility in the environment and impact as well as methods to derive guidelines for heavy metals. Remediation focuses on currently available methods to treat contaminated sediments and soils. In addition, it considers the concept of geochemical engineering for remediation of large areas contaminated by metals. A number of case studies of polluted sediments and soils and their environmental impact highlight the principles discussed in the first two sections.