Geopolymer Chemistry and Applications


Book Description

What can be done about the major concerns of our Global Economy on energy, global warming, sustainable development, user-friendly processes, and green chemistry? Here is an important contribution to the mastering of these phenomena today. Written by Joseph Davidovits, the inventor and founder of geopolymer science, it is an introduction to the subject for the newcomers, students, engineers and professionals. You will find science, chemistry, formulas and very practical information (including patents' excerpts) covering: - The mineral polymer concept: silicones and geopolymers, - Macromolecular structure of natural silicates and aluminosilicates, - Scientific Tools, X-rays, FTIR, NMR, - The synthesis of mineral geopolymers, Poly(siloxonate) and polysilicate, soluble silicate, Chemistry of (Na, K)oligo-sialates: hydrous alumino-silicate gels and zeolites, Kaolinite / Hydrosodalite-based geopolymer, Metakaolin MK-750-based geopolymer, Calcium-based geopolymer, Rock-based geopolymer, Silica-based geopolymer, Fly ash-based geopolymer, Phosphate-based geopolymer, Organic-mineral geopolymer, - Properties: physical, chemical and long-term durability, - Applications: Quality controls, Development of user-friendly systems, Castable geopolymer, industrial and decorative applications, Geopolymer / fiber composites, Foamed geopolymer, Geopolymers in ceramic processing, Manufacture of geopolymer cement, Geopolymer concrete, Geopolymers in toxic and radioactive waste management. It is a textbook, a reference book instead of being a collection of scientific papers. Each chapter is followed by a bibliography of the relevant published literature including 75 patents, 120 tables, 360 figures, 550references, 700 authors cited, representing the most up to date contributions of the scientific community. The industrial applications of geopolymers with engineering procedures and design of processes are also covered in this book.




Green Materials Obtained by Geopolymerization for a Sustainable Future


Book Description

Geopolymerization techniques allow the conversion of industrial waste materials into environmentally friendly materials. The vast list of applications includes thermal insulation, fire-resistant materials, construction materials, refractory linings, cements and concretes, encapsulation of radioactive and toxic waste etc. The book presents the technological processes involved, as well as the characterization and applications of the resulting ecomaterials. Keywords: Geopolymerization, Industrial Waste Materials, Green Materials, Thermal Insulation, Fire-resistant Materials, Construction Materials, Refractory Linings, Cements and Concretes, Encapsulation of Radioactive Waste, Encapsulation of Toxic Waste, Thermal Power Plant Ash, Aluminosilicates Recycling, Porous Geopolymers, Environmentally Friendly Concrete.




ICSCEA 2021


Book Description

This book presents articles from the Second International Conference on Sustainable Civil Engineering and Architecture, held on 30 October 2021 in Ho Chi Minh City, Vietnam. The conference brings together international experts from both academia and industry to share their knowledge, expertise, to facilitate collaboration and improve cooperation in the field. The book highlights the latest advances in sustainable architecture and civil engineering, covering topics such as offshore structures, structural engineering, construction materials, and architecture.




Geopolymers


Book Description

A geopolymer is a solid aluminosilicate material usually formed by alkali hydroxide or alkali silicate activation of a solid precursor such as coal fly ash, calcined clay and/or metallurgical slag. Today the primary application of geopolymer technology is in the development of reduced-CO2 construction materials as an alternative to Portland-based cements. Geopolymers: structure, processing, properties and industrial applications reviews the latest research on and applications of these highly important materials.Part one discusses the synthesis and characterisation of geopolymers with chapters on topics such as fly ash chemistry and inorganic polymer cements, geopolymer precursor design, nanostructure/microstructure of metakaolin and fly ash geopolymers, and geopolymer synthesis kinetics. Part two reviews the manufacture and properties of geopolymers including accelerated ageing of geopolymers, chemical durability, engineering properties of geopolymer concrete, producing fire and heat-resistant geopolymers, utilisation of mining wastes and thermal properties of geopolymers. Part three covers applications of geopolymers with coverage of topics such as commercialisation of geopolymers for construction, as well as applications in waste management.With its distinguished editors and international team of contributors, Geopolymers: structure, processing, properties and industrial applications is a standard reference for scientists and engineers in industry and the academic sector, including practitioners in the cement and concrete industry as well as those involved in waste reduction and disposal. - Discusses the synthesis and characterisation of geopolymers with chapters covering fly ash chemistry and inorganic polymer cements - Assesses the application and commercialisation of geopolymers with particular focus on applications in waste management - Reviews the latest research on and applications of these highly important materials




Development of Geopolymer from Pond Ash-Thermal Power Plant Waste


Book Description

DEVELOPMENT OF GEOPOLYMER FROM POND ASH-THERMAL POWERPLANT WASTE Explains how geopolymer technologies using industrial waste obtained from thermal power plants become cementitious materials in construction sectors for civil engineers. Utilization of waste materials has become a global challenge since they endanger our environment. In this book, the authors demonstrate how to utilize fly ash/pond ash (waste materials from thermal power plants) to produce a novel material called 'Geopolymer' (GP). Red mud, slags, etc., are mixed with fly ash to produce GP with enhanced strength. As shown in a few European countries, GP can replace cement, and some permanent structures constructed with GP are now appearing in a few advanced countries. GP, and geopolymer concrete, is considered suitable for the construction of roads, buildings, etc., and will eventually, fully or partially, replace cement. The book highlights the mechanism of the formation of GP from pond ash. Properties of structures made with GP concrete are found to be comparable to those made with cement concrete. Systematic investigations are presented to understand the chemistry of GP formation with pond ash materials. Performances of these materials above ambient temperature, as well as with different environmental conditions, are also evaluated. Audience The book will be used by civil engineers in the construction and ceramic industries, as well as the industrial waste sector. Researchers in materials science, structural and civil engineering, environmental science, and ceramic engineering, will also benefit. Additionally, the book is suitable for graduate courses in civil engineering.




Recent Advances in Nano-Tailored Multi-Functional Cementitious Composites


Book Description

Over the past few years, concrete technology has advanced quite dramatically thanks to the use of a great variety of additives and admixtures, which have paved the way for the effective development of new-generation concrete mixtures. Among these additives and admixtures, nanomaterials used in construction materials such as paste, mortar, and concrete mixtures have become very popular recently. Much of the previous attention in regard to the utilization of nanomaterials in construction materials was specifically devoted to the characterization of their fresh-state, hydration, microstructure, pore structure, mechanical, transport, and durability properties. However, research into the tailoring of multi-functional properties of construction materials (especially cementitious) with the use of nanomaterials is still in its infancy. Recent Advances in Nano-Tailored Multi-Functional Cementitious Composites aims to capture recent major scientific advances and the current state of the art in multi-functional cementitious composites developed with nanomaterials. The book will provide researchers, engineers, and other stakeholders with an insight into future directions of multi-functional capabilities of cementitious composites. Chapters focus on the large-scale development, characterization, and application of multi-functional cementitious composites addressing the following topics: nano-modified concrete; strain-hardening cementitious composites; self-sensing concrete; self-healing and bacteria-based concrete; self-cleaning concrete; self-consolidating concrete; material/construction technology for 3D printing; thermal insulation capability; green concretes including geopolymer concrete; nanoscale characterization methods; low CO2 reactive magnesia cements; and future developments and challenges of nano-tailored cementitious composites. The book will be an essential reference resource for academic and industrial researchers, materials scientists, and civil engineers working on the development and application of nano-tailored multi-functional cementitious composites. - Provides very comprehensive and unique details about multi-functional properties of cementitious composites - Presents a detailed account of investigations conducted into the application of nanomaterials and nanoscale tailoring to achieve multi-functional properties for cementitious composites - Features state-of-the-art preparation, production, processing, and implementation techniques of nanoscale tailoring of multi-functional cementitious composites starting from laboratory to large scale




Developments in Porous, Biological and Geopolymer Ceramics, Volume 28, Issue 9


Book Description

Papers from The American Ceramic Society's 31st International Conference on Advanced Ceramics and Composites, held in Daytona Beach, Florida, January 21-26, 2007. Includes papers on porous ceramics ranging from nanoporous to macroporous systems, including foams, honeycombs, 3D scaffolds, interconnected fibers, sintered hollow spheres, and aerogels; ceramics in medical applications; and geopolymers, a new class of totally inorganic, aluminosilicate-based ceramics that are charge balanced by group I oxides (i.e., Na, K, and Cs)




Handbook of Sustainable Concrete and Industrial Waste Management


Book Description

The Handbook of Sustainable Concrete and Industrial Waste Management summarizes key research trends in recycling and reusing concrete and industrial waste to reduce their environmental impact. This volume also includes important contributions in collaboration with the CRI-TEST Innovation Lab, Naples – Acerra. Part one discusses eco-friendly innovative cement and concrete and reviews key substitute materials. Part two analyzes the use of industrial waste as aggregates and the mechanical properties of concrete containing waste materials. Part three discusses differences between innovative binders, focusing on alkali-activated and geopolymer concrete. Part four provides a thorough overview of the life cycle assessment (LCA) of concrete containing industrial wastes and the impacts related to the logistics of wastes, the production of the concrete, and the management of industrial wastes. By providing research examples, case studies, and practical strategies, this book is a state-of-the-art reference for researchers working in construction materials, civil or structural engineering, and engineers working in the industry. - Offers a systematic and comprehensive source of information on the latest developments in sustainable concrete; - Analyzes different types of sustainable concrete and innovative binders from chemical, physical, and mechanical points of view; - Includes real case studies showing application of the LCA methodology.




Advances in Geopolymer-Zeolite Composites


Book Description

Geopolymers and zeolites as eco-friendly materials can participate in cutting-edge research and applications due to their tailored properties, including superabsorbent capacity, heavy metals encapsulation, flame retardancy, mechanical performance, electrokinetic behaviour, corrosion resistance, and thermal properties. This book joins activities and knowledge of researchers from multiple fields to present a comprehensive overview of the advances in synthesis and characterization of geopolymers and zeolites, including base chemistry concepts, nanoscale characterization, and applications in top-level industry.