Handbook of Electrolyte Solutions Parts A and B


Book Description

The development of science and technology demands precise data concerning the fundamental thermodynamic and transport properties of ionic solutions. Many fields, such as corrosion, pollution, food technology, biochemical phenomena, rates of reactions, etc., which involve such solutions, have been moving towards a more scientific treatment. Accordingly, the relevant fundamental parameters need to be known over a wider scale. Whereas some recent fields of science have information concentrated in a few specialist journals covering only a short span of time, the basic thermodynamic and transport properties of aqueous solutions are scattered among hundreds of different journals over a period of many decades. To aid the specialist in the search for one of these properties, the author has compiled comprehensive data from the literature on 1. Density. 2. Viscosity. 3. Conductance. 4. Transport numbers. 5. Diffusion coefficients. 6. Activity coefficients (and osmotic coefficients) of aqueous solutions of binary inorganic electrolytes, listed in alphabetical order according to the chemical formula. A list of electrolytes by alphabetical order of name in English is given in appendix I. All properties of a single solute are grouped together, thus forming a chapter, divided in sections according to temperature, e.g. Section 0 has data of the above six properties measured at 0°C, below 0°C or up to 2.4°C. Section 5, 10, 15, 20, 25, 30, 35, 40, 45 have data measured at the indicated t temperature or within the range t - 2.5°Cor=tor=t+2.4°C; Section 50 has data measured at 50°C or at temperatures higher than 47.5°C. brbrbrpbrThe present work is of immense value to those interested in readily assessing all the data of a single solute at a certain temperature, and appropriate indices easily supply the information of a certain property in every electrolyte.brbr




Albright's Chemical Engineering Handbook


Book Description

From fundamentals to plant operations, Albright's Chemical Engineering Handbook offers a thorough, yet succinct guide to day-to-day methods and calculations used in chemical engineering applications. Leaders from an exceptional diversity of specialties provide a clear review of basic information, case examples, and references to additional information. They discuss essential principles, calculations, and key issues such as reaction engineering, process control and design, waste disposal, and electrochemical and biochemical engineering. The final chapters cover aspects of patents, intellectual property, communications, and ethics that are most relevant to engineers.










The Physical Basis of Thermodynamics


Book Description

Given that thermodynamics books are not a rarity on the market, why would an additional one be useful? The answer is simple: at any level, thermodynamics is usually taught as a somewhat abstruse discipline where many students get lost in a maze of difficult concepts. However, thermodynamics is not as intricate a subject as most people feel. This book fills a niche between elementary textbooks and mathematically oriented treatises, and provides readers with a distinct approach to the subject. As indicated by the title, this book explains thermodynamic phenomena and concepts in physical terms before proceeding to focus on the requisite mathematical aspects. It focuses on the effects of pressure, temperature and chemical composition on thermodynamic properties and places emphasis on rapidly evolving fields such as amorphous materials, metastable phases, numerical simulations of microsystems and high-pressure thermodynamics. Topics like redox reactions are dealt with in less depth, due to the fact that there is already much literature available. Without requiring a background in quantum mechanics, this book also illustrates the main practical applications of statistical thermodynamics and gives a microscopic interpretation of temperature, pressure and entropy. This book is perfect for undergraduate and graduate students who already have a basic knowledge of thermodynamics and who wish to truly understand the subject and put it in a broader physical perspective. The book is aimed not at theoretical physicists, but rather at practitioners with a variety of backgrounds from physics to biochemistry for whom thermodynamics is a tool which would be better used if better understood.




Hydrolysis of Metal Ions


Book Description

Filling the need for a comprehensive treatment that covers the theory, methods and the different types of metal ion complexes with water (hydrolysis), this handbook and ready reference is authored by a nuclear chemist from academia and an industrial geochemist. The book includes both cation and anion complexes, and approaches the topic of metal ion hydrolysis by first covering the background, before proceeding with an overview of the dissociation of water and then all different metal-water hydrolysis complexes and compounds. A must-have for scientists in academia and industry working on this interdisciplinary topic.




Physical Chemistry


Book Description

New edition of the overwhelmingly favorite text for the physical chemistry course.







Biochemistry of Scandium and Yttrium, Part 1: Physical and Chemical Fundamentals


Book Description

Biochemistry of Scandium and Yttrium gathers together existing knowledge about scandium and yttrium from a wide variety of disciplines. Part 1 will present a comparative study of the physical and chemical properties of scandium and yttrium, looking at both their similarities and their differences. (Part 2 will address the biochemical aspects of these two elements, and the various medical and environmental applications.) While these elements are relatively rare in nature, these books will show that they have unusual physical and chemical properties, and a disproportionate number of important applications. Improved analytical techniques have revealed that scandium and yttrium are present throughout living matter, even though only a relatively limited number of species have been analyzed so far. This fact of course has far-ranging implications for biological and environmental concerns. Part 1 also contains a discussion of the interactions of scandium and yttrium with molecules of biological interest, such as organic acids, carbohydrates, proteins, nucleotides, and other biologically active molecules. The major impacts of scandium and yttrium in science, technology, and medicine will be of interest to a wide variety of researchers, including geochemists, inorganic and organic chemists, clinical biochemists, and those specializing in environmental protection. Biochemistry of Scandium and Yttrium, Part 1 and Part 2 will be especially welcome because the last book published on the biochemistry of scandium appeared over 20 years ago, and the only book mentioning the biochemistry of yttrium came out in 1990.




Treatise on Geochemistry


Book Description

This extensively updated new edition of the widely acclaimed Treatise on Geochemistry has increased its coverage beyond the wide range of geochemical subject areas in the first edition, with five new volumes which include: the history of the atmosphere, geochemistry of mineral deposits, archaeology and anthropology, organic geochemistry and analytical geochemistry. In addition, the original Volume 1 on "Meteorites, Comets, and Planets" was expanded into two separate volumes dealing with meteorites and planets, respectively. These additions increased the number of volumes in the Treatise from 9 to 15 with the index/appendices volume remaining as the last volume (Volume 16). Each of the original volumes was scrutinized by the appropriate volume editors, with respect to necessary revisions as well as additions and deletions. As a result, 27% were republished without major changes, 66% were revised and 126 new chapters were added. In a many-faceted field such as Geochemistry, explaining and understanding how one sub-field relates to another is key. Instructors will find the complete overviews with extensive cross-referencing useful additions to their course packs and students will benefit from the contextual organization of the subject matter Six new volumes added and 66% updated from 1st edition. The Editors of this work have taken every measure to include the many suggestions received from readers and ensure comprehensiveness of coverage and added value in this 2nd edition The esteemed Board of Volume Editors and Editors-in-Chief worked cohesively to ensure a uniform and consistent approach to the content, which is an amazing accomplishment for a 15-volume work (16 volumes including index volume)!