High Resolution Molecular Spectroscopy of Atmospheric Sciences


Book Description

During this project period the temperature dependence of the collision-broadened line widths of few selected lines of SO2 and H2S were studied between 90 K and 600 K. Selected lines were 18(3,15)- 18(2,16), 4(2,2)-3(1,3), 13(1,13)- 12(0,12), and 26(4,22)- 26(3,23) transitions of SO2 at 204.246 GHz, 235.151 GHz, 251.199 GHz, and 280.807 GHz respectively, and 1(1,0)-1(0,1) and 2(2,0) - 2(1,1) transitions of H2S at 168.762 GHz and 216.710 GHz respectively. The broadening gases were N2, O2, H2, and He. Reported pressure broadening results of SO2 and H2S extends for the first time to such a wide range of temperature. The newly developed Fast Scan Submillimeter Spectroscopic Technique (FASSST) was applied to investigate HNO3. A brief description of the system and some preliminary results related to HNO3 are included in the text below.




High Resolution Electronic Spectroscopy of Small Molecules


Book Description

Over recent years electronic spectroscopy has developed significantly, with key applications in atmospheric chemistry, astrophysics and astrochemistry. High Resolution Electronic Spectroscopy of Small Molecules explores both theoretical and experimental approaches to understanding the electronic spectra of small molecules, and explains how this information translates to practice. Professors Geoffrey Duxbury and Alexander Alijah present the links between spectroscopy and photochemistry, and discuss theoretical treatments of the interaction between different electronic states. They provide a thorough discussion of experimental techniques, and explore practical applications. This book will be an indispensable reference for graduate students and researchers in physics and chemistry working on theoretical and practical aspects of electronic spectra, as well as atmospheric scientists, photochemists, kineticists and professional spectroscopists.




Global and Accurate Vibration Hamiltonians from High-Resolution Molecular Spectroscopy


Book Description

The latest in a series providing chemical physicists with a forum for critical, authoritative evaluations of advances in every area of the discipline, this stand-alone volume focuses on using high resolution molecular spectroscopy to arrive at global and accurate Vibration Hamiltonians.




Molecular Spectroscopy


Book Description

Molecular Spectroscopy: Modern Research explores the advances in several phases of research in molecular spectroscopy. This eight-chapter book commemorates the 25th anniversary of the annual Columbus Symposium on Molecular Structure and Spectroscopy, held in September, 1970. This book highlights the spectroscopic studies of molecular species in the gas phase and in matrices. Representative articles are also included that cover the applications of molecular studies in a wide variety of areas such as biophysics, astrophysical problems, and energy transfer processes. Other chapters describe the progress achieved in the technology of high resolution spectroscopy and the techniques and terminology of Lamb-dip spectroscopy. A comprehensive bibliography is included for most of the subjects discussed and this text concludes with tables of standard data listing secondary wavelength standards, fundamental constants, atomic masses, and conversion factors of interest to spectroscopists. Spectroscopists, chemists, and researchers will find this work invaluable.




High Resolution Molecular Spectroscopy of Atmospheric Species


Book Description

The pressure-broadening of the 2 (1,1) - 2 (1 2), 3 (1,3) - 2 (2,1), and 7 (3,4) - 6 (4,3) transitions of HDO were studied between 90K and 600K. The broadening gases were He, H2, 02, and N2. Results for the temperature dependence of the pressure broadening parameters and collisional cross sections are discussed. The HDO transitions selected for study belong to widely different lower state energies. Such a selection allows to observe any dependence that 300K broadening parameters and temperature coefficients-may have on the rotational quantum numbers. All these have considerable theoretical interest.




Handbook of High Resolution Infrared Laboratory Spectra of Atmospheric Interest (1981)


Book Description

The handbook presents spectra to be utilized for the detection and measurement of new constituents in the earth's atmosphere and to obtain data for common minor species with large gas amounts in the absorption cell (such as CH/sub 4/ and N/sub 2/O). These results can be applied in the identification of absorption features in atmospheric spectra determined over long atmospheric paths. The spectra were recorded with Fourier Transform Spectrometers which are more precise than grating spectrometers. Each molecule spectrum was plotted on two scales: a condensed scale covering the range from 75 to 300/cm in one frame, and an expanded view covering 20 or 10/cm per frame. Each plot contains the name of the molecule, chemical formula, the gas pressure, cell length, and estimated resolution of the spectrum.




14th Symposium on High-Resolution Molecular Spectroscopy


Book Description

Proceedings of SPIE present the original research papers presented at SPIE conferences and other high-quality conferences in the broad-ranging fields of optics and photonics. These books provide prompt access to the latest innovations in research and technology in their respective fields. Proceedings of SPIE are among the most cited references in patent literature.




High Resolution Molecular Spectroscopy of Atmospheric Species. (The Pressure Broadening of HDO by O2, N2, H2, and He Between 100 and 600 Deg K).


Book Description

Laboratory-based pressure-broadening data has long provided information that is both of practical importance for technological applications and of fundamental interest for understanding molecular interactions and dynamics. During this project period the temperature dependence of the collision-broadened line widths of H20 and HDO were studied between 100 deg K and 600 deg K. Selected transitions were between 250 GHz and 500 GHz and the broadening gases were 02, N2, H2, and He. Low temperature measurements were made in a collisionally cooled cell to circumvent the limitations imposed by the low vapor pressure of the sample gas at temperatures far below their freezing points. The experimentally determined values were compared with earlier experimental and theoretical works.




71st International Symposium on Molecular Spectroscopy


Book Description

The International Symposium on Molecular Spectroscopy is the premier annual meeting in this exciting and interdisciplinary field. The symposium uniquely combines plenary talks from world leaders in the field with parallel sessions comprising shorter talks, many presented by graduate students, and fosters a collegial and collaborative atmosphere with a multitude of formal and informal interactions. Registration and housing costs are kept low to enable entire research groups to attend, and in fact most senior people in the field gave their very first conference presentation at this symposium (to a very friendly audience). A wide range of topics is covered, from theory to experiment, from gas-phase to condensed-phase, from low resolution to ultra-high resolution, from the microwave to the ultraviolet, and from fundamental science to applications such as astronomy and atmospheric science. Each year's meeting also includes three "mini-symposia" on topics of special interest.




Molecular Spectroscopy: Modern Research V3


Book Description

Molecular Spectroscopy: Modern Research, Volume III is a collection of papers presented at the 40th Annual Molecular Spectroscopy Symposium, held at the Ohio State University. The contributors of this seven-chapter text cover the significant advances in molecular spectroscopic research and their application in chemistry. Chapters 1 and 2 discuss first the higher-order vibration-rotation interactions in molecules and then present formulas and an insight into the direction being taken in theoretical pursuits. Chapter 3 provides an extensive compilation of published intensity and collision broadening parameters derived from infrared spectra. This chapter also contains a detailed discussion using consistent notation of some of the methods commonly applied to extract such information from laboratory spectra. Chapter 4 examines a variety of laser systems and their application in investigations involving triatomic free radicals and ions, while chapter 5 considers the developments in the microwave spectroscopic studies on nonpolar molecules when their symmetry is reduced by isotopic substitution. Chapter 6 emphasizes the quasi-linear molecular problem to develop an appreciation of the symptoms of quasi-linearity and theoretical treatments thereof. This chapter also examines the increasing role of highly resolved spectra in the interpretation of various large-amplitude motions in molecules. Lastly, Chapter 7 describes the electric multipolar moments of hydrogen and its isotopes. Spectroscopists, chemists, and researchers will find this work invaluable.