High-Temperature Irradiation Growth in Zircaloy


Book Description

Irradiation growth behavior of Zircaloy-2 and -4 was studied on specimens irradiated in the Experimental Breeder Reactor II to fluences of 1.4 to 6.3 x 1025 neutrons (n).m-2 (E > 1 MeV) in the temperature range 644 to 723 K. Measurements in the three principal directions on annealed and cold-worked/stress-relieved Zircaloy-2 slab materials provided evidence that growth is a constant-volume process up to about 680 K. The growth strains were shown to be determined by the crystallographic texture, that is, proportional to (1-3(1-3fdc)), where), where fdc is the fraction of basal poles, is the fraction of basal poles, fc, in the direction d. The growth strains for annealed and cold-worked Zircaloy were large relative to previously reported data, were similar in magnitude, were strongly dependent on irradiation temperature, and varied linearly with fluence over the range investigated. Transmission electron microscopy on annealed Zircaloy-4 specimens revealed a few small voids and larger cavities, a grain boundary second phase, and dislocation loops, tangles, and arrays. The high growth strains in annealed Zircaloy appear to be governed by dislocation arrays formed during irradiation. This implies a change in growth mechanism from that pertaining at lower temperatures in annealed material. The data suggest a transition from saturating steady-state growth at lower temperatures to increasing and eventually high steady-state rates under the conditions of these tests.







High-Fluence Irradiation Growth of Zirconium Alloys at 644 to 725 K


Book Description

Irradiation growth behavior of zirconium, Zircaloy-2 and Zircaloy-4,Zr-2.5Nb, and Zr-3.5Sn-0.8Mo-0.8Nb (EXCEL) was studied on specimens irradiated in the Experimental Breeder Reactor II (EBR-II) to fluences of 1.2 to 16.9 x 1025 neutrons (n).m-2 (E > 1 MeV) in the temperature range 644 to 725 K. In Zircaloy, growth and growth rate were observed to increase continuously with fluence up to 16.9 x 1025 n.m-2 with no indication of saturation in either recrystallized or cold-worked materials. Positive growth strains of 1.5% and negative strains of approximately 2% to 2.5% were observed in both recrystallized and cold-worked Zircaloy. The formation of both a-type loops and c component dislocations is recrystallized Zircaloy under irradiation appears to be the basis in this material for growth strains similar in magnitude to those in cold-worked Zircaloy. Alloy additions to zirconium can increase growth by as much as an order of magnitude for a given texture at the higher irradiation temperatures and fluences. A sharp change to increasing growth rate with temperature occurs in Zircaloy at ~670 K, with a similar trend indicated for the other alloys. Although growth in all these alloys is a strong function of crystallographic texture, an exact (1-3f) type of dependence is not always apparent. In Zr-2.5Nb the dependence of growth on texture appears to be masked by the precipitation of betaniobium, with a transition to a well-defined texture dependence being a function of fluence and temperature. Significant differences in growth behavior were observed in nominally similar Zircaloys, apparently due to minor microstructural or chemical differences.




Non-Linear Irradiation Growth of Cold-Worked Zircaloy-2


Book Description

Accelerating irradiation growth has been reported for several zirconium alloys with a range of metallurgical states during high-temperature tests in fast-breeder reactors (673 to 723 K) for annealed Zircaloys in thermal test reactors at power reactor temperatures (523 to 623 K) and in power reactor core components fabricated from annealed or recrystallized Zircaloy. In the latter case, there was a transition from low to high irradiation growth rates at moderate fluences (about 3 x 1025 n/m2, E > 1 MeV, at 580 K) related to the nucleation and growth of basal plane c-component loops.







Accelerated Irradiation Growth of Zirconium Alloys


Book Description

Sponge zirconium and Zr-2.5 wt% Nb, Zircaloy, or Excel alloys all exhibit accelerated irradiation growth compared with high-purity crystal-bar zirconium for irradiation temperatures between 550 to 710 K and fluences between 0.1 to 10 x 1025 n • m-2 (E > 1 MeV). There is generally an incubation period or fluence before the onset of accelerated or "breakaway" growth, which is dependent on the particular material being irradiated, its metallurgical condition before irradiation, and the irradiation temperature.




Zirconium in the Nuclear Industry


Book Description

Annotation The 41 papers of this proceedings volume were first presented at the 13th symposium on Zirconium in the Nuclear Industry held in Annecy, France in June of 2001. Many of the papers are devoted to material related issues, corrosion and hydriding behavior, in-reactor studies, and the behavior and properties of Zr alloys used in storing spent fuel. Some papers report on studies of second phase particles, irradiation creep and growth, and material performance during loss of coolant and reactivity initiated accidents. Annotation copyrighted by Book News, Inc., Portland, OR.







Zirconium in the Nuclear Industry


Book Description




The Temperature and Neutron Dose Dependence of Irradiation Growth in Zircaloy 2


Book Description

Irradiation growth due to fast neutron bombardment has been measured in textured Zircaloy 2 as a function of neutron dose (?t) and irradiation temperature. The growth strain ? obeys a relationship ?? (?t)n over a temperature range -196 to 280 C and for doses up to 1021 n/cm2. For irradiation temperatures up to 80 C, n = 0.4; but at 280 C, n = 0.7. The temperature dependence of irradiation growth in Zircaloy 2 is small, and in the temperature and dose ranges considered the growth strains do not differ by more than a factor of four. The growth rate G?d ?/d (?t) is initially large at low doses but approaches 1 at high doses (~;1021 n/cm2).