Hydrogen in Steel


Book Description

Hydrogen in Steel: Effect of Hydrogen on Iron and Steel During Production, Fabrication, and Use focuses on the effect of hydrogen on iron and steel during production, fabrication, and use. Topics covered range from the solubility of hydrogen in iron and ferrous alloys to the diffusion and permeation of hydrogen through iron and steel. Electrochemical problems related to the ability of iron to absorb hydrogen from aqueous solutions are also considered. Comprised of 19 chapters, this book begins with a detailed treatment of the nature and properties of metal-hydrogen systems, paying particular attention to the behavior of hydrogen in the bulk of the metal phase and the mechanism of reactions between metals and hydrogen or hydrogen-producing compounds. The reader is then introduced to the solubility of hydrogen in iron and ferrous alloys as well as the nature of the final product of the hydrogen-iron interaction. Subsequent chapters deal with dimensional changes and stresses produced in steel by cathodically evolved hydrogen; the effects of hydrogen on the physical, mechanical, and chemical properties of iron and steel; influence of welding on hydrogen; and sulfide corrosion cracking of steel. The effects of pickling on steel are also examined, along with the blistering and embrittlement caused by hydrogen on the base metal during electroplating. This book will be of value to students and practitioners in the field of physical chemistry.




The Problem of Hydrogen in Steel


Book Description

This memorandum introduces the problem of delayed, brittle failures associated with hydrogen in steel, particularly high-strength steel. It is intended to help the steel user determine if he has such a problem. The effects of hydrogen on the mechanical properties of steel are dealt with, and the behavior of material susceptible to delayed, brittle failure is described. Also, the effects of such factors as strength level, magnitude of applied stress, hydrogen content, steel composition, test temperature, and strain rate on hydrogen embrittlement and the susceptibility to hydrogen-induced, delayed, brittle failure are discussed. Possible sources of hydrogen in steel and the types of tests useful in determining the susceptibility to delayed failure are outlined. (Author).







The Effects of High Pressure, High Temperature Hydrogen on Steel


Book Description

This report deals with the deleterious effects of hydrogen gas on steel at elevated temperatures and/or pressures. Hydrogen attack on steels is manifest as decarburization, intergranular fissuring, or blistering. These conditions result in lowered tensile strength, ductility, and impact strength. The reaction of hydrogen with iron carbide to form methane is probably the most important chemical reaction involved in the attack on steel by hydrogen. Attack of steel at elevated temperatures and pressures is limited or prevented by the following measures: (1) use of steel alloyed with strong carbide-forming elements, (2) use of liners of resistant alloy steels, and (3) substitution of resistant nonferrous alloys.




Hydrogen Movement in Steel


Book Description

This report discusses the ways in which H2 enters steels, how it moves through steel, and methods whereby it may be removed from steel. The solubility of H2 is important in understanding other aspects of the behavior of H2 in steel and such aspects of solubility as preferred lattice sites, lattice expansion, measurements of solubility, and estimates of equilibrium H2 pressure in steel are discussed. The permeation of H2 through steel consisting of interactions at both the entry and exit surfaces of the metal as well as diffusion through the bulk metal is discussed. The various possibilities of H2 entry by corrosion processes, electrochemical processes, and other means are considered as well as factors which influence the rate of H2 removal from iron and steel. (Author).




Hydrogen in Engineering Metallic Materials


Book Description

This book analyzes the effect of hydrogen on the atomic-level interactions in metals, detailing the corresponding changes in the physical properties of crystal lattice defects, diffusion, and phase transformations in metallic materials as a result of hydrogen loading. It presents a novel derivation of the structure of stacking faults, the mobility of dislocations, and short-range atomic order in hydrogen-infused metallic alloys based on the change in the concentration of free electrons. It reviews the current hypotheses behind hydrogen embrittlement of iron-, nickel, and titanium-based alloys, focusing on the phenomenon of hydrogen-enhanced localized plasticity and taking into account inherent atomic states in the alloys and other effects due to hydrogen loading. Finally, the book analyzes the use of hydrogen as an interim alloying element in the technological processing of titanium alloys, discussing the necessary preconditions for hydrogen-enhanced plasticity of metals. This book is an excellent resource for graduate students, academic researchers, and practicing engineers involved in the development of advanced hydrogen-resistant metallic materials.




Hydrogen Production Technologies


Book Description

Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.




Hydrogen Technologies


Book Description

Hydrogen technologies are key for achieving a carbon-neutral economy; these offer solutions for the further expansion of renewable energy supplies, climate-neutral industry processes and sustainable mobility. For Germany and Europe alike, they present an opportunity to maintain industrial value creation, expand export opportunities and secure technological sovereignty. In this book, the Fraunhofer-Gesellschaft presents the knowledge and experience it has acquired along the entire value chain of the hydrogen economy. This encompasses materials and system development, production, system upscaling, energy sector applications, emission-intensive industry processes and mobility, as well as the practical, overarching issues of safety, standardization and service life.




Solutions to Hydrogen Attack in Steels


Book Description

This book is designed to help metallurgical, chemical, mechanical and reliability engineers responsible for the safe operation and maintenance of equipment made of steel.




Hydrogen Energy


Book Description

HYDROGEN ENERGY Comprehensive resource exploring integrated hydrogen technology with guidance for developing practical operating systems Hydrogen Energy presents all-inclusive knowledge on hydrogen production and storage to enable readers to design guidelines for its production, storage, and applications, addressing the recent renewed interest in hydrogen energy to manage the global energy crisis and discussing the electrochemical potential of hydrogen in transportation and fuel cells. Written by a highly qualified author, Hydrogen Energy explores sample topics such as: Essentials of hydrogen energy, such as its occurrence, physico-chemical properties, production, transmission, delivery, storage, and utilization Technology of hydrogen utilization in the land transport sector, such as automobiles, as well as other modes of transport, like marine and air Combustion characteristics and environmental pollution features, internal combustion engines, and fuel cells Guidelines to design prototype systems, covering their safety, hydrogen induced damages and life cycle analysis Providing in-depth coverage of the subject, Hydrogen Energy is an ideal resource for researchers and professionals working towards developing time-bound goal-oriented hydrogen-based programs in the chemical, automobile, power, and process engineering sectors.