Influence of Heat Treatment on Irradiation-Induced Dimensional Changes in Some Uranium-Zirconium Alloys


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Specimens made of alloys containing 1, 2, and 3 weight percentage of zirconium in uranium were irradiated under conditions where the specimens were free from physical restraint. The specimens studied were from cast, wrought, and wrought and heat-treated materials. The heat treatments investigated included quenching from the gamma phase, quenching and tempering, isothermal transformations, and alpha phase annealing. All specimens were found to increase in length as a result of irradiation except a rolled and alpha-annealed group, which was observed to shorten. The rate of change of length with uranium atom burnup was found to depend strongly upon the prior metallurgical history of the specimens and upon their compositions.







Effects of High Burnup at Elevated Temperatures on Uranium-0.52 and 1.62 W/o Zirconium Alloys


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An investigation of the effects of irradiation on uranium containing 0.52 and 1.62 w/o zirconium was made. Specimens of wrought material, variously heat treated, were studied as well as castings of the alloys. It was found that, although the wrought and heat-treated alloys were reportedly stable under thermal cycling, they elongated rapidly under irradiation. The best material studied was the 1.62% alloy in the as-cast condition. It was found to increase in length initially at a rate of about 5% per a/o burnup, after which the rate steadily diminished. Up to burnups of at least 5.3 a/o it retained a smooth surface. Two specimens of the cast 1.62% alloy, one irradiated to 2.1 a/o burnup at a calculated central temperature of 690 deg C and the other irradiated to 5.3 at.% burnup at a calculated central temperature of 620 deg C, swelled and increased in volume with the formation of a large central void surrounded by highly porous metal. The critical swelling temperature of urauium--1.62 w/o zirconium alloy was found to lie between 300 and 620 deg C, with some indications that it may be near 500 deg C.




Proceedings


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Annual Report


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Irradiation Behavior of Restrained and Vented Uranium-2 W/o Zirconium Alloy


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Twelve 0.22-in.-diameter fuel specimens containing a longitudinal central vent and clad with 0.010 in. of Type 304 stainless steel were irradiated to evaluate the effect of restraint and a central vent on fuel element stability. The cladding of 10 of the specimens contained porous end plugs to vent any released fission gas and thus to minimize the buildup of gas pressure within the stainless steel cladding. The specimens consisted of a 20% enriched uranium--2 wt% zirconium alloy core surrounded by a natural uranium--2 wt% zirconium alloy sleeve. Eight of the specimens were irradiated to burnups of the enriched core of 6.9 to 12.8% of all atoms (1.2 to 2.2 at.% of the duplex assembly) at maximum fuel temperatures ranging from 280 to 760 deg C. Most of the clad specimens exhibited negligible volume increases as a result of irradiation. Two specimens containing central vents but unclad were irradiated together with the clad specimens in an attempt to differentiate between the effects due to a central vent and the effects due to cladding. The central vent in itself did not appear to reduce the swelling characteristics of the alloy. Mechanical restraint appeared to have extended the useful operating temperatures of the metallic fuel alloy by at least 200 deg C and also greatly extended the burnup levels to which the fuel could be irradiated.







Fuel Elements Conference


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