Innovation in Zeolite Materials Science


Book Description

The proceedings of this zeolite scientific meeting reflect the growing drive to discover new materials. It is evident that zeolite materials science is in a post-ZSM-5 period - pushed by a massive expansion of new compositions and topologies, and the application of new scientific tools. Four new zeolite topologies were detailed at this meeting. Important new trends were the resurgence of interest in computational and theoretical approaches to explain synthesis, sorption and catalytic data, and the increasing use of NMR and high-resolution imaging.










Zeolites and Ordered Mesoporous Materials: Progress and Prospects


Book Description

Zeolites are the most frequently used industrial catalysts. Their applications range from oil refining, petrochemistry and the synthesis of special chemicals to environmental catalysis. Rapid progress in basic research and the development of new processes has resulted in the first Federation of European Zeolite Associations (FEZA) School on Zeolites. Zeolites and Ordered Mesoporous Materials: Progress and Prospects reflects the programme of the first School on Zeolites, held in Prague on August 20-21, 2005. Readers gain insight into the synthesis of the ever-expanding spectrum of zeolites, zeotypes and ordered mesoporous materials including the use of zeolites and mesoporous materials as catalysts in organic conversions. These range from the fascinating ship-in-bottle systems via cascade reactions to bulk applications in oil-refining and petrochemistry. Contributions from world experts enhance the book, with select chapters on trends in the molecular sieves field, zeolite structures, ion-exchange properties of zeolites, advanced applications (with unique technologies and opportunities) and a chapter on natural zeolites. * Contains contributions from world experts in the field * Includes an account of the frontier topic of high-throughput techniques * Reviews the application of quantum-chemical methods to zeolite science to show the necessity of combining experimental and theoretical approaches




Handbook of Zeolite Science and Technology


Book Description

The Handbook of Zeolite Science and Technology offers effective analyses ofsalient cases selected expressly for their relevance to current and prospective research. Presenting the principal theoretical and experimental underpinnings of zeolites, this international effort is at once complete and forward-looking, combining fundamental




Fly Ash Zeolites


Book Description

This book presents a thorough review of the state-of-knowledge and recent innovations in the synthesis of pure and improved grades of fly ash zeolites (FAZ). Addressing improvements to conventional methods, it also showcases a novel technique for the synthesis of high cation exchangers from fly ash and detailed characterization techniques for the products obtained. In addition, it examines in detail various areas of specific applications of fly ash zeolites. Over the years, several methods such as hydrothermal, fusion prior to hydrothermal, microwave assisted hydrothermal and molten salt techniques for producing FAZ have been developed. However, one-step and two-step reactions between the fly ash and alkali usually generate alkaline wastes that may cause environmental contamination. In addition, the separation of FAZ from the partially activated fly ash (the impurities) remains a major concern for researchers and industrialists alike. /divIn view of these challenges, this book presents a novel technique for three-step activation (TSA), which focuses on recycling the fly ash-NaOH-water reaction by-products until zeolitic residue is formed. The FAZ (the final residue after third step reactions) synthesized in this manner exhibits exceptionally high cation exchange capacity, specific surface area and pore area. This book offers a comprehensive compendium of reading material on fly ash and its recycled product, the zeolites. Students at both undergraduate and graduate levels, researchers, and practicing engineers will all find this book to be a valuable guide in their respective fields.




Zeolites as Catalysts, Sorbents and Detergent Builders


Book Description

This new book will be welcomed by companies involved in catalysis and catalyst manufacturing, sorbent and detergent production, chemical and petroleum refining, and by research scientists in academia. It contains 76 original contributions of recent work on fundamental and technological aspects of zeolite research and application. Particular attention is paid to novel developments in zeolite catalysis, sorption on zeolites and use of zeolites as detergent builders. Problems of zeolite synthesis, structure, modification, ion exchange, diffusion and novel applications are also dealt with. Topics which are the subject of much current interest are also treated, e.g. new catalytic applications of zeolites in the synthesis of fine chemicals, novel formulations of detergent builders and industrially developed zeolite-based separation processes. The application of zeolites is also discussed from both economic and ecological points of view. The contributions cover a wide range of materials and results which are organised, to a large extent, in tables and figures and are identified by appropriate keywords.The meeting at which these contributions were presented was the latest in a series of smaller, more specialized zeolite meetings which are held in between the large International Zeolite Conferences. Participating in the symposium were experts from both industry and academia who gave invited lectures, oral and poster presentations. The resulting book provides a large body of helpful information for present and future work and development in zeolite research and applications.




Molecular Sieves


Book Description

The porous structure of molecular sieves, combined with their chemical composition, makes them uniquely suitable for use as catalysts or catalytic supports. As such, the materials are used in a wide range of chemical reactions, and as components of formulated products. The shape selectivity of the materials further enhances their chemical usefulness, and exploitation of their unique absorption properties holds the key to improving their catalytic properties. To that end, great efforts are being made to find new of different molecular sieves, with altered or tailored structures or chemical composition. The synthesis and characterisation of molecular sieve materials is a considerable challenge, testing both the chemist's understanding and practical skills. In a thorough overhaul of the very successful first edition of this book, the author guides the reader in the basics of sieve structure, synthesis and characterisation, and points the way to the development of new or improved sieve materials. By covering both the principles and practical aspects of sieve synthesis and characterisation, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.




Zeolite Chemistry and Catalysis


Book Description

These proceedings reflect recent developments in the field of zeolite chemistry and catalysis with an emphasis on the role of a modifying component on the properties of the molecular sieve material. The plenary lectures and contributed papers concentrate on the problem of isomorphous substitution in a zeolitic framework; on the occlusion and the structure of metal, metal oxide, and metal sulphide clusters and complexes in the intracrystalline void volume of molecular sieves and zeolites as well as in the interlaminar space of layered compounds. Catalytic applications are discussed, not only in regard to traditional hydrocarbon transformation, but also in such areas as: reduction of SO2, decomposition of NO, reactions of sulphur containing compounds and conversion of CO, CO2 to hydrocarbons or of alcohols to oxygenated products. Because the book provides valuable data and information on new achievements in the zeolite material science and application, it will be of considerable interest to all research groups involved in zeolite science.




Zeolite Microporous Solids: Synthesis, Structure, and Reactivity


Book Description

Intensive research on zeolites, during the past thirty years, has resulted in a deep understanding of their chemistry and in a true zeolite science, including synthesis, structure, chemical and physical properties, and catalysis. These studies are the basis for the development and growth of several industrial processes applying zeolites for selective sorption, separation, and catalysis. In 1983, a NATO Advanced Study Institute was organized in Alcabideche (portugal) to establish the State-of-the-Art in Zeolite Science and Technology and to contribute to a better understanding of the structural properties of zeolites, the configurational constraints they may exert, and their effects in adsorption, diffusion, and catalysis. Since then, zeolite science has witnessed an almost exponential growth in published papers and patents, dealing with both fundamentals issues and original applications. The proposal of new procedures for zeolite synthesis, the development of novel and sophisticated physical techniques for zeolite characterization, the discovery of new zeolitic and related microporous materials, progresses in quantum chemistry and molecular modeling of zeolites, and the application of zeolites as catalysts for organic reactions have prompted increasing interest among the scientific community. An important and harmonious interaction between various domains of Physics, Chemistry, and Engineering resulted therefrom.