Ion Exchange in Analytical Chemistry


Book Description

Analytical Chemistry, Volume 38: Ion Exchange in Analytical Chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. This book focuses on the plate-equilibrium theory of chromatography, which is less difficult theoretically than the mass-transfer theory. Organized into 11 chapters, this volume begins with an overview of the earliest recorded application of ion exchange. This text then examines how high temperature affects ion-exchange resins. Other chapters consider the exchange of ions between a solid ion-exchanging material and a solution, which is a typically reversible reaction. This book describes as well the relatively simple separations and other applications of ion exchange to analytical chemistry. The final chapter deals with the interesting nature of the metal complexes formed within the exchanger and describe the use of ion-exchange distribution studies to determine the stability and nature of complexes existing in the solution. This book is a valuable resource for analytical chemists.




Ion Exchange in Analt Chemistry


Book Description

The aim of this rare volume is to provide up-to-the-minute coverage of the many applications of ion exchange in analytical chemistry. This work places major emphasis on modern high-resolution chromatography, and also includes the analysis of proteins and biological macromolecules. The easy-to-read text gives a general account of ion exchangers, their properties and how they are made, as well as a brief account of the physical chemistry of classical microporous ion-exchanging polymers. Organized by methods and techniques, this one-of-a-kind book describes each technique using illustrations by representative applications. This interesting review also compares ion-exchange methods with other methods of accomplishing the same analyses. It addresses many new areas in this field, including such exciting topics as pulsed amperometric detection of carbohydrates, amino acids, and peptides; chromatography of carbohydrates by anion exchange; and methods of polymer synthesis. Everyone who has an interest in analytical chemistry, chromatography, reactive polymers, and chromatographic science will want to add this reference to their collection of up-to-date resources.




Ion Exchange in Analytical Chemistry


Book Description

Ion Exchange in Analytical Chemistry ...




Ion Exchange Materials: Properties and Applications


Book Description

Ion Exchange Materials: Properties and Applications fills a "two-dimensional" gap in books currently available on the subject. Firstly, there is a lack of modern comprehensive publications on the chemistry of ion exchange materials and on the relationships between their properties and practical applications. Secondly, there are few books on ion exchange chemistry that are targeted to industrial R&D specialists and research students who (i) do not work with ion exchange on a daily basis, (ii) need to develop competence in this area, and (iii) find it difficult to start studying the subject from primary scientific publications. The book bridges these gaps by describing classical and modern theoretical concepts, as well as practical approaches for using ion exchange materials. Ion exchange materials combine properties of homogeneous and heterogeneous materials. Besides being an interesting subject for investigation, they are essential in a wide variety of industrial technologies: in the chemical and biochemical industries, pharmacy, medicine, microelectronics, the nuclear industry, food production, waste treatment, and many other areas. Ion exchange is a powerful tool in chemical analysis and scientific research. The main focus in this book is on ion exchange polymers: ion exchange resins, chelating resins, imprinted (templated), and other functional polymers. It provides an in-depth study of ion exchange materials, suitable for postgraduate students and R&D industrial specialists in chemistry, chemical and biochemical technology. - Comprehensively covers the subject - Provides links between theoretical concepts, material properties, practical applications, and technical solutions - Easy to understand - requires only ground knowledge of university-level chemistry and can be read without an in-depth knowledge of mathematics - Supported with an interactive website




Ion Chromatography


Book Description

Bewitched is an odd word with which to begin a chemical textbook. Yet that is a fair description of how I reacted on first leaming of ion exchange and imagining what might be done with it. That initial fascination has not left me these many years later, and it has provided much ofthe motivation for writing this book. The perceived need for a text on the fundamentals of ion chromatography provided the rest. Many readers will have a general idea of what ion chromatography is and what it does. Briefly, for those who do not, it is an umbrella term for a variety of chromatographie methods for the rapid and sensitive analysis of mixtures of ionic species. It has become highly developed in the last decade, and while it is now routinely used for the determination of organic as weH as inorganic ions, its initial impact was greatest in the area of inorganic analysis. In the past the determination of inorganic ions, particularly anions, meant laborious, time-con suming, and often not very sensitive "wet chemieal" methods. In the last ten years that has changed radically as ion chromatography has supplanted these older methods.




Ion Exchange


Book Description

Ion Exchange: Theory and Application focuses on the applications, complexities, and theoretical aspects of ion exchange. This book discusses the kinetics of fixed-bed ion exchange; fundamental properties of ion exchange resins; ion exchange equipment design; and ion exchange in water treatment. The multistage systems in ion exchange; desalting sea water; applications of ion exchange to the separation of inorganic cations; and ion exchange as a tool in analytical chemistry are also elaborated. This text likewise covers the metal concentration and recovery by ion exchange; catalytic application of ion exchangers; and use of ion exchange adsorbents in biochemical and physiological studies. Other topics include the separation of amino acids by ion exchange chromatography; sugar refining and by-product recovery; and ion exchange recovery of alkaloids. This publication is a good reference for chemists and students interested in ion exchange.




Encyclopedia of Geochemistry


Book Description

The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.




Inorganic Ion Exchangers in Chemical Analysis


Book Description

The book provides an in-depth discussion regarding inorganic ion exchangers for students, teachers, and researchers engaged in conducting research in chemical technology and related areas. Analytical chemists seeking simple and novel means of using easy-to-prepare chromatographic materials will find this book extremely informative. Inorganic Ion Exchangers in Chemical Analysis is unique in its discussion of column and planar chromatographic applications of amorphous synthetic inorganic ion exchangers. The book also covers the historical background of iorganic ion exchangers, their classification and present status, and the analytical aspects of these materials.




Ion Exchange


Book Description

Ion Exchange, 2nd Edition is a totally revised and updated version of the highly popular Monograph for Teachers, first published by The Royal Society of Chemistry in 1975. It covers the practical application of ion exchange and the synthesis of organic ion exchange resins, which have spanned nearly 60 years of development since the pioneering work of Adams and Holmes in 1935. This book covers the theory, development, and application in considerable detail and describes the history of development of ion exchange materials and the advances in their utilization in industrial processes. Key applications in such areas as water purification, hydrometallurgy, and chromatography are described and supported by chapters on the related scientific fundamentals governing equilibria and kinetics of ion exchange. Twenty-two experiments using inexpensive equipment are detailed, which not only complement a chapter dedicated to the characterization of organic exchangers, but also serve to illustrate several other pure and applied principles related to ion exchange phenomena. It is anticipated that the unique inclusion of experiments and the broad coverage of the whole text should appeal to a wide readership and offer particular relevance to practitioners in schools, colleges, and industry.




CRC Handbook of Ion Exchange Resins, Volume VI


Book Description

The six-volume CRC Handbook of Ion Exchange Resins reviews the application of ion exchange resins to inorganic analytical chemistry. Extracted from over 6,000 original publications, it presents the information in over 1,000 tables complemented by concise descriptions of analytical methods involving virtually all the elements of the periodic table. Also, the ion exchange characteristics of the elements, as well as other important information required by analysis using ion exchange resins, are presented in separate tables. The methods that allow the multi-element analysis of complex matrices are emphasized. This work includes a general discussion of the theoretical, instrumental, and other principles underlying the various applications of ion exchange resins in inorganic analytical chemistry with special attention focused on techniques based on ion chromatography.