March 2010 Groundwater Sampling at the Project Shoal Site, Nevada (Data Validation Package).


Book Description

The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Project Shoal Area (Shoal) in March 2010. Wells HC-4, HC-5, HC-7, HC-8, MV-1, MV-2 and MV-3 were sampled March 10-12, 2010, as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351, continually updated). Wells HC-1, HC-2, HC-3, and HC-6 were sampled March 24, 2010, by Desert Research Institute personnel.




Data Validation Package May 2015, Groundwater Sampling at the Shoal, Nevada, Site


Book Description

The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Shoal, Nevada, Site (Shoal) in May 2015. Groundwater samples were collected from wells MV-1, MV-2, MV-3, MV-4, MV-5, H-3, HC-1, HC-2d, HC-3, HC-4, HC-5, HC-6, HC-7, HC-8, and HS-1. Sampling was conducted as specified in the Sampling and Analysis Plan for US. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and-analysis-plan-us-department-energy­ office-legacy-management-sites). Monitoring wells MV-1, MV-2, MV-3, MV-4, MV-5, HC-2d, HC-4, HC-5, HC-7, HC-8, and HS-1 were purged prior to sampling using dedicated submersible pumps. At least one well casing volume was removed, and field parameters (temperature, pH, and specific conductance) were allowed to stabilize before samples were collected. Samples were collected from wells H-3, HC-1, HC-3, and HC-6 using a depth-specific bailer because these wells are not completed with dedicated submersible pumps. Samples were submitted under Requisition Index Number (RIN) 15057042 to ALS Laboratory Group in Fort Collins, Colorado, for the determination of bromide, gross alpha, gross beta, tritium, uranium isotopes, and total uranium (by mass); and under RIN 15057043 to the University of Arizona for the determination of carbon-14 and iodine-129. A duplicate sample from location MV-2 was included with RIN 15057042. The laboratory results from the 2015 sampling event are consistent with those of previous years with the exception of sample results from well HC-4. This well continues to be the only well with tritium concentrations above the laboratory’s minimum detectable concentration which is attributed to the wells proximity to the nuclear detonation. The tritium concentration (731 picocuries per liter [pCi/L]) is consistent with past results and is below the U.S. Environmental Protection Agency's (EPA) maximum contaminant level (MCL) of 20,000 pCi/L. However, concentrations of gross alpha, uranium, and carbon-14 all increased in the sample from well HC-4 during this sampling event. Concentrations of gross alpha and uranium have been above the EPA MCLs in this well since 2012 and the highest concentrations of gross alpha (60.6 pCi/L) and uranium (110 micrograms per liter) were detected during this sampling event. Refer to the time-concentration plots included with this report. Also see the 2015 Groundwater Monitoring Report Project Shoal Area: Subsurface Corrective Action Unit 447 for additional information on the 2015 sampling results.




March 2011 Groundwater Sampling at the Project Shoal Site (Data Validation Package).


Book Description

The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Project Shoal Area (Shoal) in March 2011. Wells HC-1, HC-2, HC-4, HC-5, HC-6, HC-7, MV-1, MV-2 and MV-3 were sampled as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351, continually updated). Two extra tritium samples were collected from well HC-4, one sample (HC-4-400) was collected at about 1/3 of the purge volume (135 gallons), the second sample (HC-4-400) was collected at 2/3 of purge volume (270 gallons). These additional samples were collected prior to completing the well purging process to evaluate the effects well purging has on the analytical results. Samples were not collected from locations HC-3 and HC-8 at the direction of the S.M. Stoller Corporation site lead.




May 2010 Groundwater Sampling at the Central Nevada Test Area (Data Validation Package).


Book Description

The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Central Nevada Test Area (CNTA) on June 7-9, 2010, in accordance with the 2004 Correction Action Decision Document/Corrective Action Plan for Corrective Action Unit 443: Central Nevada Test Area (CNTA)-Subsurface. Sampling and analysis were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351), continually updated).




June 2012 Groundwater Sampling at the Central Nevada Test Area (Data Validation Package).


Book Description

The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Central Nevada Test Area (CNTA) on June 26-27, 2012, in accordance with the 2004 Correction Action Decision Document/Corrective Action Plan for Corrective Action Unit 443: Central Nevada Test Area (CNTA)-Subsurface and the addendum to the "Corrective Action Decision Document/Corrective Action Plan" completed in 2008. Sampling and analysis were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351), continually updated).




May 2011 Groundwater Sampling at the Central Nevada Test Area (Data Validation Package).


Book Description

The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Central Nevada Test Area (CNTA) on May 10-11, 2011, in accordance with the 2004 Correction Action Decision Document/Corrective Action Plan for Corrective Action Unit 443: Central Nevada Test Area (CNTA)-Subsurface and the addendum to the "Corrective Action Decision Document/Corrective Action Plan" completed in 2008. Sampling and analysis were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351), continually updated).




Data Validation Package - April and July 2015 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing Site


Book Description

This event included annual sampling of groundwater and surface water locations at the Gunnison, Colorado, Processing Site. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites. Samples were collected from 28 monitoring wells, three domestic wells, and six surface locations in April at the processing site as specified in the 2010 Ground Water Compliance Action Plan for the Gunnison, Colorado, Processing Site. Domestic wells 0476 and 0477 were sampled in July because the homes were unoccupied in April, and the wells were not in use. Duplicate samples were collected from locations 0113, 0248, and 0477. One equipment blank was collected during this sampling event. Water levels were measured at all monitoring wells that were sampled. No issues were identified during the data validation process that requires additional action or follow-up.




Validation Analysis of the Shoal Groundwater Flow and Transport Model


Book Description

Environmental restoration at the Shoal underground nuclear test is following a process prescribed by a Federal Facility Agreement and Consent Order (FFACO) between the U.S. Department of Energy, the U.S. Department of Defense, and the State of Nevada. Characterization of the site included two stages of well drilling and testing in 1996 and 1999, and development and revision of numerical models of groundwater flow and radionuclide transport. Agreement on a contaminant boundary for the site and a corrective action plan was reached in 2006. Later that same year, three wells were installed for the purposes of model validation and site monitoring. The FFACO prescribes a five-year proof-of-concept period for demonstrating that the site groundwater model is capable of producing meaningful results with an acceptable level of uncertainty. The corrective action plan specifies a rigorous seven step validation process. The accepted groundwater model is evaluated using that process in light of the newly acquired data. The conceptual model of ground water flow for the Project Shoal Area considers groundwater flow through the fractured granite aquifer comprising the Sand Springs Range. Water enters the system by the infiltration of precipitation directly on the surface of the mountain range. Groundwater leaves the granite aquifer by flowing into alluvial deposits in the adjacent basins of Fourmile Flat and Fairview Valley. A groundwater divide is interpreted as coinciding with the western portion of the Sand Springs Range, west of the underground nuclear test, preventing flow from the test into Fourmile Flat. A very low conductivity shear zone east of the nuclear test roughly parallels the divide. The presence of these lateral boundaries, coupled with a regional discharge area to the northeast, is interpreted in the model as causing groundwater from the site to flow in a northeastward direction into Fairview Valley. Steady-state flow conditions are assumed given the absence of groundwater withdrawal activities in the area. The conceptual and numerical models were developed based upon regional hydrogeologic investigations conducted in the 1960s, site characterization investigations (including ten wells and various geophysical and geologic studies) at Shoal itself prior to and immediately after the test, and two site characterization campaigns in the 1990s for environmental restoration purposes (including eight wells and a year-long tracer test). The new wells are denoted MV-1, MV-2, and MV-3, and are located to the northnortheast of the nuclear test. The groundwater model was generally lacking data in the north-northeastern area; only HC-1 and the abandoned PM-2 wells existed in this area. The wells provide data on fracture orientation and frequency, water levels, hydraulic conductivity, and water chemistry for comparison with the groundwater model. A total of 12 real-number validation targets were available for the validation analysis, including five values of hydraulic head, three hydraulic conductivity measurements, three hydraulic gradient values, and one angle value for the lateral gradient in radians. In addition, the fracture dip and orientation data provide comparisons to the distributions used in the model and radiochemistry is available for comparison to model output. Goodness-of-fit analysis indicates that some of the model realizations correspond well with the newly acquired conductivity, head, and gradient data, while others do not. Other tests indicated that additional model realizations may be needed to test if the model input distributions need refinement to improve model performance. This approach (generating additional realizations) was not followed because it was realized that there was a temporal component to the data disconnect: the new head measurements are on the high side of the model distributions, but the heads at the original calibration locations themselves have also increased over time. This indicates that the steady-state assumption of the groundwater model is in error. To test the robustness of the model despite the transient nature of the heads, the newly acquired MV hydraulic head values were trended back to their likely values in 1999, the date of the calibration measurements. Additional statistical tests are performed using both the backward-projected MV heads and the observed heads to identify acceptable model realizations. A jackknife approach identified two possible threshold values to consider. For the analysis using the backward-trended heads, either 458 or 818 realizations (out of 1,000) are found acceptable, depending on the threshold chosen. The analysis using the observed heads found either 284 or 709 realizations acceptable. The impact of the refined set of realizations on the contaminant boundary was explored using an assumed starting mass of a single radionuclide and the acceptable realizations from the backward-trended analysis.




Data Validation Package, April and June 2016 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing Site, October 2016


Book Description

This event included annual sampling of groundwater and surface water locations at the Gunnison, Colorado, Processing Site. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for US Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and analysis-plan-us-department-energy-office-legacy-management-sites). Samples were collected from 28 monitoring wells, three domestic wells, and six surface locations in April at the processing site as specified in the draft 2010 Ground Water Compliance Action Plan for the Gunnison, Colorado, Processing Site. Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. Domestic wells 0476 and 0477 were sampled in June because the homes were unoccupied in April, and the wells were not in use. Duplicate samples were collected from locations 0126, 0477, and 0780. One equipment blank was collected during this sampling event. Water levels were measured at all monitoring wells that were sampled. See Attachment 2, Trip Reports for additional details. The analytical data and associated qualifiers can be viewed in environmental database reports and are also available for viewing with dynamic mapping via the GEMS (Geospatial Environmental Mapping System) website at http://gems.lm.doe.gov/#. No issues were identified during the data validation process that requires additional action or follow-up. An assessment of anomalous data is included in Attachment 3. Interpretation and presentation of results, including an assessment ofthe natural flushing compliance strategy, will be reported in the upcoming 2016 Verification Monitoring Report. U.S.




Data Validation Package - July 2016 Groundwater Sampling at the Gunnison, Colorado, Disposal Site


Book Description

Groundwater sampling at the Gunnison, Colorado, Disposal Site is conducted every 5 years to monitor disposal cell performance. During this event, samples were collected from eight monitoring wells as specified in the 1997 Long-Term Surveillance Plan for the Gunnison, Colorado, Disposal Site. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for US Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and analysis-plan-us-department-energy-office-legacy-management-sites). Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. A duplicate sample was collected from location 0723. Water levels were measured at all monitoring wells that were sampled and seven additional wells. The analytical data and associated qualifiers can be viewed in environmental database reports and are also available for viewing with dynamic mapping via the GEMS (Geospatial Environmental Mapping System) website at http://gems.lm.doe.gov/#. No issues were identified during the data validation process that require additional action or follow-up.