MAX Phases


Book Description

In this comprehensive yet compact monograph, Michel W. Barsoum, one of the pioneers in the field and the leading figure in MAX phase research, summarizes and explains, from both an experimental and a theoretical viewpoint, all the features that are necessary to understand and apply these new materials. The book covers elastic, electrical, thermal, chemical and mechanical properties in different temperature regimes. By bringing together, in a unifi ed, self-contained manner, all the information on MAX phases hitherto only found scattered in the journal literature, this one-stop resource offers researchers and developers alike an insight into these fascinating materials.




Mechanical Properties of MAX Phases


Book Description

MAX Phase Materials are uniquely structured carbide and nitride materials which combine the rigidity, oxidation-resistance and high-temperature strength of ceramic materials with such metallic properties as good machinability, thermal-shock resistance, damage-tolerance and good transport properties. Potential applications include microelectronic layers, coatings for electrical contacts, thermal shock-resistant refractories, high-temperature heating elements, neutron-irradiation resistant nuclear applications, thermal barriers, protective aerospace coatings, and bio-compatible materials. The book reviews theoretical and experimental research up to early 2021 and references 185 original resources with their direct web links for in-depth reading. Keywords: MAX Phase Materials, Rigidity, High-Temperature Strength, Machinability, Microelectronic Layers, Electrical Contact Coatings, Thermal-Shock Resistance, Heating Elements, Neutron-Irradiation Resistant Materials, Thermal Barriers, Bio-compatible Materials.




MAX Phases and Ultra-high Temperature Ceramics for Extreme Environments


Book Description

"This book investigates a new class of ultra-durable ceramic materials, which exhibit characteristics of both ceramics and metals, and will explore recent advances in the manufacturing of ceramic materials that improve their durability and other physical properties, enhancing their overall usability and cost-effectiveness"--




2D Metal Carbides and Nitrides (MXenes)


Book Description

This book describes the rapidly expanding field of two-dimensional (2D) transition metal carbides and nitrides (MXenes). It covers fundamental knowledge on synthesis, structure, and properties of these new materials, and a description of their processing, scale-up and emerging applications. The ways in which the quickly expanding family of MXenes can outperform other novel nanomaterials in a variety of applications, spanning from energy storage and conversion to electronics; from water science to transportation; and in defense and medical applications, are discussed in detail.




Fundamentals of Ceramics


Book Description

Updated and improved, this revised edition of Michel Barsoum's classic text Fundamentals of Ceramics presents readers with an exceptionally clear and comprehensive introduction to ceramic science. Barsoum offers introductory coverage of ceramics, their structures, and properties, with a distinct emphasis on solid state physics and chemistry. Key equations are derived from first principles to ensure a thorough understanding of the concepts involved. The book divides naturally into two parts. Chapters 1 to 9 consider bonding in ceramics and their resultant physical structures, and the electrical, thermal, and other properties that are dependent on bonding type. The second part (Chapters 11 to 16) deals with those factors that are determined by microstructure, such as fracture and fatigue, and thermal, dielectric, magnetic, and optical properties. Linking the two sections is Chapter 10, which describes sintering, grain growth, and the development of microstructure. Fundamentals of Ceramics is ideally suited to senior undergraduate and graduate students of materials science and engineering and related subjects.




Mechanical Properties of Ceramics


Book Description

A Comprehensive and Self-Contained Treatment of the Theory and Practical Applications of Ceramic Materials When failure occurs in ceramic materials, it is often catastrophic, instantaneous, and total. Now in its Second Edition, this important book arms readers with a thorough and accurate understanding of the causes of these failures and how to design ceramics for failure avoidance. It systematically covers: Stress and strain Types of mechanical behavior Strength of defect-free solids Linear elastic fracture mechanics Measurements of elasticity, strength, and fracture toughness Subcritical crack propagation Toughening mechanisms in ceramics Effects of microstructure on toughness and strength Cyclic fatigue of ceramics Thermal stress and thermal shock in ceramics Fractography Dislocation and plastic deformation in ceramics Creep and superplasticity of ceramics Creep rupture at high temperatures and safe life design Hardness and wear And more While maintaining the first edition's reputation for being an indispensable professional resource, this new edition has been updated with sketches, explanations, figures, tables, summaries, and problem sets to make it more student-friendly as a textbook in undergraduate and graduate courses on the mechanical properties of ceramics.




Tailoring of Mechanical Properties of Si3N4 Ceramics


Book Description

Proceedings of the NATO Advanced Research Workshop on `Tailoring of High Temperature Properties of Si3N4 Ceramics', Schloß Ringberg/Munich, Germany, October 6--9, 1993




Electronic Structure Methods for Complex Materials


Book Description

Density functional theory (DFT) has blossomed in the past few decades into a powerful tool that is used by experimentalists and theoreticians alike. This book highlights the extensive contributions that the DFT-based OLCAO method has made to progress in this field, and it demonstrates its competitiveness for performing ab initio calculations on large and complex models of practical systems. A brief historical account and introduction to the elements of the theory set the stage for discussions on semiconductors, insulators, crystalline metals and alloys, complex crystals, non-crystalline solids and liquids, microstructure containing systems and those containing impurities, defects, and surfaces, biomolecular systems, and the technique of ab initio core level spectroscopy calculation.




Cathodic Arcs


Book Description

Cathodic arcs are among the longest studied yet least understood objects in science. Plasma-generating, tiny spots appear on the cathode; they are highly dynamic and hard to control. With an approach emphasizing the fractal character of cathode spots, strongly fluctuating plasma properties are described such as the presence of multiply charged ions that move with supersonic velocity. Richly illustrated, the book also deals with practical issues, such as arc source construction, macroparticle removal, and the synthesis of dense, well adherent coatings. The book spans a bridge from plasma physics to coatings technology based on energetic condensation, appealing to scientists, practitioners and graduate students alike.




Ultra-High Temperature Ceramics


Book Description

The first comprehensive book to focus on ultra-high temperature ceramic materials in more than 20 years Ultra-High Temperature Ceramics are a family of compounds that display an unusual combination of properties, including extremely high melting temperatures (>3000°C), high hardness, and good chemical stability and strength at high temperatures. Typical UHTC materials are the carbides, nitrides, and borides of transition metals, but the Group IV compounds (Ti, Zr, Hf) plus TaC are generally considered to be the main focus of research due to the superior melting temperatures and stable high-melting temperature oxide that forms in situ. Rather than focusing on the latest scientific results, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications broadly and critically combines the historical aspects and the state-of-the-art on the processing, densification, properties, and performance of boride and carbide ceramics. In reviewing the historic studies and recent progress in the field, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications provides: Original reviews of research conducted in the 1960s and 70s Content on electronic structure, synthesis, powder processing, densification, property measurement, and characterization of boride and carbide ceramics. Emphasis on materials for hypersonic aerospace applications such as wing leading edges and propulsion components for vehicles traveling faster than Mach 5 Information on materials used in the extreme environments associated with high speed cutting tools and nuclear power generation Contributions are based on presentations by leading research groups at the conference "Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications II" held May 13-19, 2012 in Hernstein, Austria. Bringing together disparate researchers from academia, government, and industry in a singular forum, the meeting cultivated didactic discussions and efforts between bench researchers, designers and engineers in assaying results in a broader context and moving the technology forward toward near- and long-term use. This book is useful for furnace manufacturers, aerospace manufacturers that may be pursuing hypersonic technology, researchers studying any aspect of boride and carbide ceramics, and practitioners of high-temperature structural ceramics.