Metals and Chemical Change


Book Description

This book looks at how molecules react, and how the feasibility and outcome of chemical reactions can be predicted. Beginning with an introduction to the concept of an activity series of metals, Metals and Chemical Change then introduces chemical thermodynamics (enthalpy, entropy and free energy) and applies the concept to both inorganic and organic elements. A Case Study on batteries and fuel cells is also included. The accompanying CD-ROM includes video sequences of the reactions of metals with water, acid and aqueous ions, and gives the reader an opportunity to make experimental observations and predictions about chemical behaviour. A comprehensive Data Book of chemical and physical constants is included, along with a set of interactive self-assessment questions. The Molecular World series provides an integrated introduction to all branches of chemistry for both students wishing to specialise and those wishing to gain a broad understanding of chemistry and its relevance to the everyday world and to other areas of science. The books, with their Case Studies and accompanying multi-media interactive CD-ROMs, will also provide valuable resource material for teachers and lecturers. (The CD-ROMs are designed for use on a PC running Windows 95, 98, ME or 2000.)




W Tungsten


Book Description

The present volume continues the description of the chemical reactions of eiemental tungsten started with "Tungsten" Suppl. Vol. A 7. It covers the reactions with the metallic elements from zinc to actinoids. The treatment includes phase diagrams, bulk reactions, and surface processes which again are of outstanding importance in most systems. The raader is referred to the introductory remarks on pp. X/XI. Frankfurt am Main Ernst Koch November 1987 Introductory Remarks Abbreviations In order not to overload the text, the following abbreviations are sometimes used without definitions in the present volume, in addition to the abbreviations usual in the Gmelin Handbook. a. c. alternating current AE Auger electron Auger electron spectroscopy(ic) or spectrum AES bcc body-centered cubic CPD contact potential difference counts per second cps d. c. direct current DTA differential thermoanalysis Fermi Ievel EF EI electron impact ELS electron energy loss spectroscopy or spectrum EMF, emf electromotive force fcc face-centered cubic FE field emission field electron (emission) microscope(ic) FEM FES field emission spectroscopy FIM field ion microscope(ic) F-N Fowler-Nordheim hcp hexagonal close-packed 6 L Langmuir=1·10- Torr·s LEED low energy electron diffraction monolayer ML PES photoelectron spectroscopy PSD photon-stimulated desorption RHEED reflection high energy electron diffraction room temperature RT SI secondary ion SIMS secondary ion mass spectrometry TDS thermal desorption spectroscopy(ic) or spectrum TE thermionic emission total energy distribution TED UHV ultra-high vacuum UPS ultra-violet photoelectron spectroscopy(ic) or spectrum XPS X-ray photoelectron spectroscopy(ic) or spectrum Gmelin Handbock WSuppl. Vol.




The Sceptical Chymist


Book Description

Reproduction of the original: The Sceptical Chymist by Robert Boyle




Chemistry 2e


Book Description

Chemistry 2e is designed to meet the scope and sequence requirements of the two-semester general chemistry course. The textbook provides an important opportunity for students to learn the core concepts of chemistry and understand how those concepts apply to their lives and the world around them. The book also includes a number of innovative features, including interactive exercises and real-world applications, designed to enhance student learning. The second edition has been revised to incorporate clearer, more current, and more dynamic explanations, while maintaining the same organization as the first edition. Substantial improvements have been made in the figures, illustrations, and example exercises that support the text narrative. Changes made in Chemistry 2e are described in the preface to help instructors transition to the second edition.




Corrosion Control


Book Description

Human beings undoubtedly became aware of corrosion just after they made their first metals. These people probably began to control corrosion very so on after that by trying to keep metal away from corrosive environments. "Bring your tools in out of the rain" and "Clean the blood off your sword right after battle" would have been early maxims. Now that the mechanisms of corrosion are better understood, more techniques have been developed to control it. My corrosion experience extends over 10 years in industry and research and over 20 years teaching corrosion courses to university engineering students and industrial consulting. During that time I have developed an approach to corrosion that has successfully trained over 1500 engineers. This book treats corrosion and high-temperature oxidation separately. Corrosion is divided into three groups: (1) chemical dissolution including uniform attack, (2) electrochemical corrosion from either metallurgicalor environmental cells, and (3) corrosive-mechanical interactions. It seems more logical to group corrosion according to mechanisms than to arbitrarily separate them into 8 or 20 different types of corrosion as if they were unrelated. University students and industry personnel alike generally are afraid of chemistry and consequently approach corrosion theory very hesitantly. In this text the electrochemical reactions responsible for corrosion are summed up in only five simple half-cell reactions. When these are combined on a polarization diagram, which is explained in detail, the electrochemical pro cesses become obvious.




Chemistry


Book Description

Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.




High Temperature Oxidation and Corrosion of Metals


Book Description

The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.




The Theory of Transformations in Metals and Alloys


Book Description

This work is a classic reference text for metallurgists, material scientists and crystallographers. The first edition was published in 1965. The first part of that edition was revised and re-published in 1975 and again in 1981. The present two-part set represents the eagerly awaited full revision by the author of his seminal work, now published as Parts I and II. Professor Christian was one of the founding fathers of materials science and highly respected worldwide. The new edition of his book deserves a place on the bookshelf of every materials science and engineering department. Suitable thermal and mechanical treatments will produce extensive rearrangements of the atoms in metals and alloys, and corresponding marked variations in physical and chemical properties. This book describes how such changes in the atomic configuration are effected, and discusses the associated kinetic and crystallographic features. It deals with areas such as lattice geometry, point defects, dislocations, stacking faults, grain and interphase boundaries, solid solutions, diffusion, etc. The first part covers the general theory while the second part is concerned with descriptions of specific types of transformations.




Chemical Reactions


Book Description

This title introduces the reader to the huge variety of chemical reactions that shape our world. Find out all about explosions, learn about how to start reactions and understand how chemical equations work.