Methods for Oxidation of Organic Compounds V2


Book Description

Methods for the Oxidation of Organic Compounds: Alcohols, Alcohol Derivatives, Alkyl Halides, Nitroalkanes, Alkyl Azides, Carbonyl Compounds, Hydroxyarenes and Aminoarenes describes the different methods used for the controlled oxidation of alcohols, alcohol derivatives, alkyl halides, nitroalkanes, alkyl azides, carbonyl compounds, hydroxyarenes, and aminoarenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of eight chapters and begins with a discussion on the oxidation of alcohols, with particular emphasis on the formation of carbonyl compounds and carboxylic acids. The following chapters focus on the oxidation of esters and alkyl halides; ethers, acetals, and metal derivatives of alcohols; amines, nitro compounds, and azides; carbonyl compounds; 1,2-diols and related compounds; and hydroxyarenes, aminoarenes, dihydroxyarenes, diaminoarenes, and aminohydroxyarenes. Methods such as catalytic oxidation, catalytic dehydrogenation, and electrochemical and biochemical oxidation are mentioned. This monograph should be of interest to organic chemists and research students.




Hydrocarbon Chemistry


Book Description

Hydrocarbons and their transformations play major roles in chemistry as raw materials and sources of energy. Diminishing petroleum supplies, regulatory problems, and environmental concerns constantly challenge chemists to rethink and redesign the industrial applications of hydrocarbons. Written by Nobel Prize-winner George Olah and hydrocarbon expert Árpád Molnár, the completely revised and expanded Second Edition of Hydrocarbon Chemistry provides an unparalleled contemporary assessment of the field, presenting basic concepts, current research, and future applications. Hydrocarbon Chemistry begins by discussing the general aspects of hydrocarbons, the separation of hydrocarbons from natural sources, and the synthesis from C1 precursors with recent developments for possible future applications. Each successive chapter deals with a specific type of hydrocarbon transformation. The Second Edition includes a new section on the chemical reduction of carbon dioxide–focusing on catalytic, ionic, electrocatalytic, photocatalytic, and ezymatic reductions–as well as a new chapter on new catalysts and activation methods, combinatorial chemistry, and environmental chemistry. Other topics covered include: Major processes of the petrochemical industry, such as cracking, reforming, isomerization, and alkylation Derivation reactions to form carbon-heteroatom bonds Hydrocarbon oxidations Metathesis Oligomerization and polymerization of hydrocarbons All chapters have been updated by adding sections on recent developments to review new advances and results. Essential reading for practicing scientists in industry, polymer and catalytic chemists, as well as researchers and graduate students, Hydrocarbon Chemistry, Second Edition remains the benchmark text in its field.




Methods for Oxidation of Organic Compounds V1


Book Description

Methods for the Oxidation of Organic Compounds: Alkanes, Alkenes, Alkynes, and Arenes is an account of the different methods used for the controlled oxidation of alkanes, alkenes, alkynes, and arenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of five chapters and begins with a discussion on alkanes, alkyl groups, and hydrocarbon residues. The formation of alkenes, alcohols, hydroperoxides, dialkyl peroxides, cyclic peroxides, ethers, and esters as well as aldehydes, ketones, and carboxylic acids is described, together with the aromatization of cyclic systems. The following chapters are devoted to alkenes, alkynes, and arenes and focus on the formation of compounds ranging from 1,2-diols and oxiranes (1,2-epoxides) to 1,2-dicarbonyl compounds, phenols and their derivatives, and quinones. The formation of dialkynes by oxidative coupling of 1-alkynes is described, along with the oxidative cleavage of arenes and oxidative coupling of phenols. This monograph should be of interest to organic chemists and research students.




Houben-Weyl


Book Description







Inorganic Reactions and Methods, The Formation of Bonds to Group VIB (O, S, Se, Te, Po) Elements (Part 1)


Book Description

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.







The Chemistry of Anilines


Book Description

Aniline is the parent molecule of a vast family of aromatic amines. Since its discovery in 1826 it has become one of the hundred most important building blocks in chemistry. Aniline is used as an intermediate in many different fields of applications, such as isocyanates, rubber processing chemicals, dyes and pigments, agricultural chemicals and pharmaceuticals. The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series, this volume treats all aspects of this functional group. It contains chapters on the theoretical and computational foundations; on analytical and spectroscopical aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses.