Methods of Thermodynamics


Book Description

Outstanding text focuses on physical technique of thermodynamics, typical problems, and significance and use of thermodynamic potential. Mathematical apparatus, first law of thermodynamics, second law and entropy, more. 1965 edition.




Biochemical Thermodynamics


Book Description

Navigate the complexities of biochemical thermodynamics with Mathematica(r) Chemical reactions are studied under the constraints of constant temperature and constant pressure; biochemical reactions are studied under the additional constraints of pH and, perhaps, pMg or free concentrations of other metal ions. As more intensive variables are specified, more thermodynamic properties of a system are defined, and the equations that represent thermodynamic properties as a function of independent variables become more complicated. This sequel to Robert Alberty's popular Thermodynamics of Biochemical Reactions describes how researchers will find Mathematica(r) a simple and elegant tool, which makes it possible to perform complex calculations that would previously have been impractical. Biochemical Thermodynamics: Applications of Mathematica(r) provides a comprehensive and rigorous treatment of biochemical thermodynamics using Mathematica(r) to practically resolve thermodynamic issues. Topics covered include: * Thermodynamics of the dissociation of weak acids * Apparent equilibrium constants * Biochemical reactions at specified temperatures and various pHs * Uses of matrices in biochemical thermodynamics * Oxidoreductase, transferase, hydrolase, and lyase reactions * Reactions at 298.15K * Thermodynamics of the binding of ligands by proteins * Calorimetry of biochemical reactions Because Mathematica(r) allows the intermingling of text and calculations, this book has been written in Mathematica(r) and includes a CD-ROM containing the entire book along with macros that help scientists and engineers solve their particular problems.




Computational Thermodynamics


Book Description

Phase diagrams are used in materials research and engineering to understand the interrelationship between composition, microstructure and process conditions. In complex systems, computational methods such as CALPHAD are employed to model thermodynamic properties for each phase and simulate multicomponent phase behavior. Written by recognized experts in the field, this is the first introductory guide to the CALPHAD method, providing a theoretical and practical approach. Building on core thermodynamic principles, this book applies crystallography, first principles methods and experimental data to computational phase behavior modeling using the CALPHAD method. With a chapter dedicated to creating thermodynamic databases, the reader will be confident in assessing, optimizing and validating complex thermodynamic systems alongside database construction and manipulation. Several case studies put the methods into a practical context, making this suitable for use on advanced materials design and engineering courses and an invaluable reference to those using thermodynamic data in their research or simulations.




Thermodynamic Approaches in Engineering Systems


Book Description

Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. - Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion - Written by a first-class expert in the field of advanced methods in thermodynamics - Provides a synthesis of recent thermodynamic developments in practical systems - Presents very elaborate literature discussions from the past fifty years




Advanced Thermodynamics for Engineers


Book Description

Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.




Energy Systems


Book Description

Considered as particularly difficult by generations of students and engineers, thermodynamics applied to energy systems can now be taught with an original instruction method. Energy Systems applies a completely different approach to the calculation, application and theory of multiple energy conversion technologies. It aims to create the reader’s foundation for understanding and applying the design principles to all kinds of energy cycles, including renewable energy. Proven to be simpler and more reflective than existing methods, it deals with energy system modeling, instead of the thermodynamic foundations, as the primary objective. Although its style is drastically different from other textbooks, no concession is done to coverage: with encouraging pace, the complete range from basic thermodynamics to the most advanced energy systems is addressed. The accompanying ThermoptimTM portal (http://direns.mines-paristech.fr/Sites/Thopt/en/co/_Arborescence_web.html) presents the software and manuals (in English and French) to solve over 200 examples, and programming and design tools for exercises of all levels of complexity. The reader is explained how to build appropriate models to bridge the technological reality with the theoretical basis of energy engineering. Offering quick overviews through e-learning modules moreover, the portal is user-friendly and enables to quickly become fully operational. Students can freely download the ThermoptimTM modeling software demo version (in seven languages) and extended options are available to lecturers. A professional edition is also available and has been adopted by many companies and research institutes worldwide - www.thermoptim.org This volume is intended as for courses in applied thermodynamics, energy systems, energy conversion, thermal engineering to senior undergraduate and graduate-level students in mechanical, energy, chemical and petroleum engineering. Students should already have taken a first year course in thermodynamics. The refreshing approach and exceptionally rich coverage make it a great reference tool for researchers and professionals also. Contains International Units (SI).




Applied Thermodynamics


Book Description

Deals with the availability method and its application to power plant system design and energy conversion. The first part of the book describes the development and the formulation of the availability method. The second part presents its applications to energy conversion processes. Examples for each energy conversion system are introduced and there are practice problems throughout the text.




Computational Thermodynamics of Materials


Book Description

Integrates fundamental concepts with experimental data and practical applications, including worked examples and end-of-chapter problems.




Thermodynamics and Statistical Mechanics


Book Description

Innovative, wide-ranging treatment, suitable for advanced undergraduates and graduate students, covers negative temperatures and heat capacities, general and special relativistic effects, black hole thermodynamics, gravitational collapse, and more. Problems with worked solutions. 1978 edition.




Thermodynamics of Energy Conversion and Transport


Book Description

Scientists and engineers are nowadays faced with the problem of optimizing complex systems subject to constraints from, ecology, economics, and thermodynamics. It is chiefly to the last of these that this volume is addressed. Intended for physicists, chemists, and engineers, the book uses examples from solar, thermal, mechanical, chemical, and environmental engineering to focus on the use of thermodynamic criteria for optimizing energy conversion and transmission. The early chapters centre on solar energy conversion, the second section discusses the transfer and conversion of chemical energy, while the concluding chapters deal with geometric methods in thermodynamics.