Molecular Photoswitches


Book Description

A comprehensive overview about the emerging field of photoswitches and their applications in materials science and biology Molecular Photoswitches guides the reader through the basic molecular structures of photochromic compounds and their applications in the area of photoresponsive materials as well as in the biological context. The initial chapters describe individual classes of molecular photoswitches, introducing their principles of photochromism, typical switching wavelengths, thermal stability of photoisomers and other key information, which is ordinarily spread in the literature. These classes comprise i.a. azobenzenes, diazocines, arylazoheterocycles, arylhydrazones, indigoids, photochromic imines, or acylhydrazones. The book also covers: Catalysis with molecular switches Applications in photochromic porous materials, liquid crystals, or nanoparticles Light-responsive molecular machines, logic devices, and molecular magnets Photomodulation of biological systems: photoswitchable biopolymers, lightmodulated antibiotics, cytotoxins, ion channel inhibitors, light-propelled artificial muscles, and computationally designed photochromic proteins This two-volume work is a valuable guide for researchers and non-experts working in the field of photochemistry, organic chemistry, catalysis, materials science, biology, and medicine.




Diarylethene Molecular Photoswitches


Book Description

A comprehensive review to the synthesis, properties, and applications of diarylethene-based molecular photoswitches Diarylethene Molecular Photoswitches: Concept and Functionalities provides the fundamental concepts of molecular photoswitches and includes information on how the bistable photoswitches of diarylethenes modulate the functions of materials and biological activities. Written by Masahiro Irie (the inventor of photochromic diarylethene compound), the book explores the reaction mechanism, photoswitching performance, photoswitchable crystals, and the myriad applications of diarylethenes based photoswitches. This book offers academics, chemists, and engineers an essential resource for understanding the molecular photoswitches and provides a guide to the development of new photoresponsive materials. The author explores the applications based on diarylethene and its dirivatives to Field-Effect Transistors, Metal-Organic Frameworks including nanoparticles, super-resolution fluorescence microscopies, drug release, and self-healing materials. This important book: * Offers a guide to diarylethene derivatives, the most widely studied compounds worldwide among the photochromic compounds * Includes the basic concepts of molecular photoswitches * Explores the myraid applications grounded in diarylethene and its derivatives * Presents an authortative text from the inventor of the photochromic diarylethene compound Written for materials scientists, organic, polymer, and physical chemists, and electronics engineers, Diarylethene Molecular Photoswitches offers an introduction to the topic and includes recent developments in the field.




Molecular Switches


Book Description

Every day we use switches to turn electric appliances on and off and no computer could function without them. Molecular switches work in the same way, changing from state one to another depending on environmental influences. However, as opposed to normal switches, molecular switches are extremely tiny and their application in nanotechnology, biomedicine and computer chip design opens up whole new horizons. In this manual, the editor and authors describe molecular switches made of catenanes and rotaxanes, dihydroazulenes, fulgides, liquid crystals and polypeptides. The spectrum of topics discussed ranges from chiroptical switches via multifunctional systems to molecular logic systems and biomolecular switches. A wealth of information for chemists and materials scientists in industry and academia interested in one of the most innovative branches of their discipline.




Photochemistry


Book Description

Drawing on the continued wealth of photochemical research, this volume combines reviews on the latest advances in the field with specific topical highlights. Starting with periodical reports of the recent literature on physical and inorganic aspects, light induced reactions in cryogenic matrices, properties of transition-metal compounds, time-resolved spectroscopy, the exploitation of solar energy and the molecules of colour. Coverage continues with highlighted topics, in the second part, from photoresponsive hydrogels, the tunable photoredox properties of organic dyes, light-driven asymmetric organocatalytic processes, dual gold–photoredox catalysis, the preparation and characterization of photosensitizers for triplet–triplet annihilation photon upconversion and the role of photochemistry on traditional synthetic processes. This volume will include for the first time a section entitled ‘SPR Lectures on Photochemistry’, providing examples for academic readers to introduce a photochemistry topic and precious help for students in photochemistry. Providing critical analysis of the topics, this book is essential reading for anyone wanting to keep up to date with the literature on photochemistry and its applications.




Photochemistry: Volume 51


Book Description




Photochromic Materials


Book Description

Summarizing all the latest trends and recent topics in one handy volume, this book covers everything needed for a solid understanding of photochromic materials. Following a general introduction to organic photochromic materials, the authors move on to discuss not only the underlying theory but also the properties of such materials. After a selection of pplications, they look at the latest achievements in traditional solution-phase applications, including photochromic-based molecular logic operations and memory, optically modulated supramolecular system and sensors, as well as light-tunable chemical reactions. The book then describes the hotspot areas of photo-switchable surfaces and nanomaterials, photochromic-based luminescence/electronic devices and bulk materials together with light-regulated biological and bio-chemical systems. The authors conclude with a focus on current industrial applications and the future outlook for these materials. Written with both senior researchers and entrants to the field in mind.




Out-of-Equilibrium (Supra)molecular Systems and Materials


Book Description

A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.




Photoisomerization


Book Description

Different applications and uses of light energy have emerged over the last few years in many different fields such as in medicine, material science, energy and biochemistry. New and exciting applications of light-controlled processes have become practical in the diagnosis and treatment of diseases, the preparation and use of functional materials, the storage of solar energy and the control of biological properties. Many of these applications are based on a very simple chemical step: a photoisomerization. The isomerization of a chemical double bond allows for the control with extreme spatial and temporal resolution of complex systems. Nature offers different examples of very complex functions that are initiated by this type of simple chemical. Upon photon absorption, the light energy can be used to induce a chemical (geometrical) change that influences the protein environment that triggers a specific signal or function. Inspired by these amazing and extremely efficient processes, many efforts have been devoted to the modification of natural systems and to the design of new applications, using simple and tunable photoisomerizations. Accordingly, the preparation of photoactive molecular devices based on photoisomerizations and the use of these species in different applications is now a very active scientific field, with profound implications in our everyday lives. In this book, the fundamental aspects of the photoisomerization of many different chemical structures containing C=C, N=N and C=N double bonds is covered. Different experimental and computational tools used to study these processes are discussed and some specific applications of different compounds are presented.







Design of Hybrid Molecules for Drug Development


Book Description

Design of Hybrid Molecules for Drug Development reviews the principles, advantages, and limitations involved with designing these groundbreaking compounds. Beginning with an introduction to hybrid molecule design and background as to their need, the book goes on to explore a range of important hybrids, with hybrids containing natural products, molecules containing NO- and H2S-donors, dual-acting compounds acting as receptor ligands and enzyme inhibitors, and the design of photoresponsive drugs all discussed. Drawing on practical case studies, the hybridization of molecules for development as treatments for a number of key diseases is then outlined, including the design of hybrids for Alzheimer's, cancer, and malaria. With its cutting-edge reviews of breaking developments in this exciting field, the book offers a novel approach for all those working in the design, development, and administration of drugs for a range of debilitating disorders. - Highlights an approach unimpaired by the limitations of the classical search for lead structures - one of the core problems in modern drug development processes, making the content of high relevance for both academic and non-academic drug development processes - Pulls together research and design techniques in a novel way to give researchers the best possible platform from which to review the approaches and techniques applied - Compares the advantages and disadvantages of these compounds - Includes the very latest developments, such as photoactivatable and photo-responsive drugs