Naturally Occurring Organohalogen Compounds - A Comprehensive Update


Book Description

Despite the long association of organohalogen compounds with human activities, nature is the producer of nearly 5,000 halogen-containing chemicals. Once dismissed as accidents of nature or isolation artifacts, organohalogen compounds represent an important and ever growing class of natural products, in many cases exhibiting exceptional biological activity. Since the last comprehensive review in 1996 (Vol. 68, this series), there have been discovered an additional 2,500 organochlorine, organobromine, and other organohalogen compounds. These natural organohalogens are biosynthesized by bacteria, fungi, lichen, plants, marine organisms of all types, insects, and higher animals including humans. These compounds are also formed abiogenically, as in volcanoes, forest fires, and other geothermal events.In some instances, natural organohalogens are precisely the same chemicals that man synthesizes for industrial use, and some of the quantities of these natural chemicals far exceed the quantities emitted by man.




Naturally Occurring Organohalogen Compounds


Book Description

The present volume is the third in a trilogy that documents naturally occurring organohalogen compounds, bringing the total number — from fewer than 25 in 1968 — to approximately 8,000 compounds to date. Nearly all of these natural products contain chlorine or bromine, with a few containing iodine and, fewer still, fluorine. Produced by ubiquitous marine (algae, sponges, corals, bryozoa, nudibranchs, fungi, bacteria) and terrestrial organisms (plants, fungi, bacteria, insects, higher animals) and universal abiotic processes (volcanos, forest fires, geothermal events), organohalogens pervade the global ecosystem. Newly identified extraterrestrial sources are also documented. In addition to chemical structures, biological activity, biohalogenation, biodegradation, natural function, and future outlook are presented.




Organohalide-Respiring Bacteria


Book Description

This book summarizes the current state of knowledge concerning bacteria that use halogenated organic compounds as respiratory electron acceptors. The discovery of organohalide-respiring bacteria has expanded the range of electron acceptors used for energy conservation, and serves as a prime example of how scientific discoveries are enabling innovative engineering solutions that have transformed remediation practice. Individual chapters provide in-depth background information on the discovery, isolation, phylogeny, biochemistry, genomic features, and ecology of individual organohalide-respiring genera, including Dehalococcoides, Dehalogenimonas, Dehalobacter, Desulfitobacterium and Sulfurospirillum, as well as organohalide-respiring members of the Deltaproteobacteria. The book introduces readers to the fascinating biology of organohalide-respiring bacteria, offering a valuable resource for students, engineers and practitioners alike.




Natural Production of Organohalogen Compounds


Book Description

This book summarizes the state-of-the-art knowledge on naturally occurring organohalogens, of which more than 3700 are documented. The chapters cover all aspects of this field, including the structural diversity and sources of organohalogens, the mechanisms for their formation and biodegradation, the clinical use of dichloroacetate, and the synthesis of the powerful anticancer chlorine-containing cryptophycin. Both biogenic and abiogenic sources of organohalogens are treated, the latter of which include volcanic emissions and abiogenic formation in soil. Halogenation in humans, fungi, and in the ocean are covered in separate chapters. Sources and biosynthesis of the relatively rare natural organofluorines are also discussed in this volume. By better understanding of the role nature plays in the area of organohalogens, we can more intelligently regulate the production, use, and disposal of man-made organohalogen compounds.




Algal Chemical Ecology


Book Description

Yet another Springer world-beater, this is the first ever book devoted to the chemical ecology of algae. It covers both marine and freshwater habitats and all types of algae, from seaweeds to phytoplankton. While the book emphasizes the ecological rather than chemical aspects of the field, it does include a unique introductory chapter that serves as a primer on algal natural products chemistry.




Environmental Inorganic Chemistry for Engineers


Book Description

Environmental Inorganic Chemistry for Engineers explains the principles of inorganic contaminant behavior, also applying these principles to explore available remediation technologies, and providing the design, operation, and advantages or disadvantages of the various remediation technologies. Written for environmental engineers and researchers, this reference provides the tools and methods that are imperative to protect and improve the environment. The book's three-part treatment starts with a clear and rigorous exposition of metals, including topics such as preparations, structures and bonding, reactions and properties, and complex formation and sequestering. This coverage is followed by a self-contained section concerning complex formation, sequestering, and organometallics, including hydrides and carbonyls. Part Two, Non-Metals, provides an overview of chemical periodicity and the fundamentals of their structure and properties. - Clearly explains the principles of inorganic contaminant behavior in order to explore available remediation technologies - Provides the design, operation, and advantages or disadvantages of the various remediation technologies - Presents a clear exposition of metals, including topics such as preparations, structures, and bonding, reaction and properties, and complex formation and sequestering




Progress in the Chemistry of Organic Natural Products


Book Description

The volumes of this classic series, now referred to simply as "Zechmeister" after its founder, L. Zechmeister, have appeared under the Springer imprint ever since the series was founded in 1938. The volumes contain contributions on various topics related to the origin, distribution, chemistry, synthesis, biochemistry, function or use of various classes of naturally occurring substances ranging from small molecules to biopolymers. Each contribution is written by a recognized authority in his field and provides a comprehensive and up-to-date review of the topic in question. Addressed to biologists, technologists and chemists alike, the series can be used by the expert as a source of information and literature citations and by the non-expert as a means of orientation in a rapidly developing discipline.




Ocean-Atmosphere Interactions of Gases and Particles


Book Description

The oceans and atmosphere interact through various processes, including the transfer of momentum, heat, gases and particles. In this book leading international experts come together to provide a state-of-the-art account of these exchanges and their role in the Earth-system, with particular focus on gases and particles. Chapters in the book cover: i) the ocean-atmosphere exchange of short-lived trace gases; ii) mechanisms and models of interfacial exchange (including transfer velocity parameterisations); iii) ocean-atmosphere exchange of the greenhouse gases carbon dioxide, methane and nitrous oxide; iv) ocean atmosphere exchange of particles and v) current and future data collection and synthesis efforts. The scope of the book extends to the biogeochemical responses to emitted / deposited material and interactions and feedbacks in the wider Earth-system context. This work constitutes a highly detailed synthesis and reference; of interest to higher-level university students (Masters, PhD) and researchers in ocean-atmosphere interactions and related fields (Earth-system science, marine / atmospheric biogeochemistry / climate). Production of this book was supported and funded by the EU COST Action 735 and coordinated by the International SOLAS (Surface Ocean- Lower Atmosphere Study) project office.




Naturally-Produced Organohalogens


Book Description

Should the production and use of chlorine and all chlorinated organic compounds be halted, in view of their adverse effects on the environment and human health? Those in favour argue that certain chlorinated compounds (PCBs, DDT, CFCs, etc.) have large negative environmental effects. The use of chlorine in disinfectants leads to the production of chloroform, while bulk products (PVC) contribute to the production of chlorinated dibenzo-p-dioxins and dibenzofurans when they are burned. Those against argue that chlorine and many chlorinated compounds are essential in the control of human health (the prevention of disease transmitted through drinking water that has not been disinfected), and that chlorinated compounds are indispensable intermediates in many production processes, representing a vast economic value. But such discussions often ignore the fact that Nature contributes significantly to the production of chlorinated organic compounds. More than 1000 such compounds are known, and their contribution to the biogeochemical cycling of chlorine is underestimated. Chlorine is organically bound in large quantities to humic materials, and natural production mechanisms are known for low molecular weight compounds (methyl chloride, chloroform, chlorinated dibenzo-p-dioxins and dibenzofurans). The role of these compounds in the environment is largely unknown. Naturally-Produced Organohalogens gives a complete overview of the present state of knowledge on the subject, giving a much needed balance to the argument sketched out above.




Chlorine and the Environment


Book Description

This is the first book to examine comprehensively the chlorine industry and its effects on the environment. It covers not only the history of chlorine production, but also looks at its products, their effects on the global environment, and the international legislation which controls their use, release, and disposal. Individual chapters are dedicated to subjects such as releases of organochlorines into the environment, and the environmental impact of ozone depletion, providing simple explanations of these complex issues. These are backed up with case studies of landmark events in the history of the chlorine industry - for example the Seveso explosion or the Yusho and Yu-Cheng mass poisonings. With a clear, concise text and numerous compilations of critical data, this book will prove an invaluable source reference for environmental scientists, students, and policy makers with an interest in this subject.