Selective Oxidation by Heterogeneous Catalysis


Book Description

Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.




New Developments in Selective Oxidation by Heterogeneous Catalysis


Book Description

This volume contains invited papers and communications presented at the Third European Workshop Meeting on Selective Oxidation by Heterogeneous Catalysis. The purpose of the meeting was to present recent results and to discuss new aspects of partial oxidation by heterogeneous catalysis. The following topics were discussed: Novel processes for obtaining new fine chemicals by catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in preparation methods of oxidation catalysts; new phenomena in partial oxidation and new aspects of surface chemistry in oxide catalysts; new applications of physicochemical methods for characterization of oxide catalysts; oxidation with other agents than oxygen and catalytic oxidation of carbohydrates. This book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation and encourage innovation and creativity.




New Developments in Selective Oxidation II


Book Description

This volume contains invited papers and communications presented at the Second World Congress and Fourth European Workshop Meeting on New Developments in Selective Oxidation. The purpose of the meeting was to present new topics and recent advances as well as the discussion of new aspects of fundamental and applied aspects of partial selective oxidation in heterogeneous and homogeneous catalysis. The following topics were discussed: New processes for fine chemicals by catalytic oxidation; Recent developments in surface chemistry of oxide catalysts; Novel catalytic systems and preparation methods; Heterogenized homogeneous oxidation catalysts; Selective oxidation and oxidative dehydrogenation of alkanes; New industrial developments based on catalytic oxidation reactions; Bio-, photo-, and electro-catalytic oxidation; Oxidation by other agents than dioxygen; Bifunctional metal-on-metal oxide catalysts for selective oxidation.This book provides a valuable set of data on selective oxidation reactions which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field.







Vanadium Catalysis


Book Description

Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.




Advanced Materials in Catalysis


Book Description

Advanced Materials in Catalysis is a collection of materials that discusses various catalysts. The book presents the physical and chemical properties that indicate that a particular class of materials may be of catalytic interest. The text first covers bimetallic catalysts, and then proceeds to examining the catalytic properties of compounds such as graphite intercalation compounds; oxides with the scheelite structure; and synthetic layered silicates and aluminosilicate. The book also covers reduction catalysts, biological catalysts, and monolithic catalyst supports. The selection will be of g ...




Heterogeneous Catalysis and Fine Chemicals IV


Book Description

After three meetings in Poitiers, France, the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals was held under the auspices of the New Swiss Chemical Society in Basel, Switzerland. Fundamental as well as applied contributions on the use of heterogeneous catalysis for the preparation of fine chemicals were presented and discussed.The program consisted of 4 plenary lectures, 28 oral contributions and around 90 posters covering a broad range of reactions and catalytic aspects. 82 of these contributions are collected in the present proceedings, grouped into the following 8 topical areas:- Industrial and engineering problems (7 contributions)- Alkylation and acylation reactions (11 contributions)- Enantio- and diastereoselective hydrogenation reactions (9 contributions)- Chemoselective hydrogenation reactions (12 contributions)- Oxidation reactions (14 contributions)- Immobilized and encapsulated complex catalysts (12 contributions)- Zeolite and clay catalysts (12 contributions)- Miscellaneous topics (5 contributions)




Third World Congress on Oxidation Catalysis


Book Description

The overall theme of the 3rd World Congress is "Atom Efficient Catalytic Oxidations for Global Technologies". This theme was chosen to stimulate the participants to report their findings with an emphasis on conserving valuable material in their catalytic transformations, as well as conserving energy, in an environmentally responsible manner. Progress towards this stated goal is substantial as evidenced by the tremendous response of the community in their participation of quality publications complied in these Proceedings of the Congress.The subjects presented span a wide range of oxidation reactions and catalysts. These include the currently important area of lower alkane oxidation to the corresponding olefins, unsaturated aldehydes, acids and nitriles.The four featured lectures and seven plenary lectures constitute the general background and overview of the subject matter at hand. The 104 contributed papers and 13 poster manuscripts, summarized in this compendium, probe new avenues to achieve catalytically efficient oxidation reactions for the future needs of mankind in a global environment.




Metal Oxides in Heterogeneous Catalysis


Book Description

Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. - Presents case studies in each chapter that provide a focus on the industrial applications - Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource - Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications




Site-Selective Catalysis


Book Description

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science.The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience.Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.Review articles for the individual volumes are invited by the volume editors.Readership: research chemists at universities or in industry, graduate students