Soil Emission of Nitrous Oxide and its Mitigation


Book Description

Nitrous oxide gas is a long-lived relatively active greenhouse gas (GHG) with an atmospheric lifetime of approximately 120 years, and heat trapping effects about 310 times more powerful than carbon dioxide per molecule basis. It contributes about 6% of observed global warming. Nitrous oxide is not only a potent GHG, but it also plays a significant role in the depletion of stratospheric ozone. This book describes the anthropogenic sources of N2O with major emphasis on agricultural activities. It summarizes an overview of global cycling of N and the role of nitrous oxide on global warming and ozone depletion, and then focus on major source, soil borne nitrous oxide emissions. The spatial-temporal variation of soil nitrous oxide fluxes and underlying biogeochemical processes are described, as well as approaches to quantify fluxes of N2O from soils. Mitigation strategies to reduce the emissions, especially from agricultural soils, and fertilizer nitrogen sources are described in detail in the latter part of the book.










Nitrogen Transformations Associated with N2O Emissions in Agricultural Soils


Book Description

Nitrogen (N) is one of the most important plant nutrient, and its availability and transformations are vital for net primary production. Soil N transformations include mineralization, nitrification and denitrification processes. Nitrogen mineralization transforms organic N into inorganic N, providing available N for crops. Both nitrification and denitrification are microbe-driven processes associated with nitrous oxide (N2O) emissions. N2O emissions from agricultural soils decrease N fertilization efficiency and potentially induce global warming. The mitigation of soil N2O emissions in agricultural practice is essential for sustainable development of agriculture considering the environmental effect of N2O. Various strategies have been proposed for the mitigation of N2O emissions. Nitrification inhibitors have been demonstrated to be useful in decreasing soil N2O emissions, including the application of nitrification inhibitors, such as dicyandiamide (DCD) and 3,4-dimethylpyrazole phosphate (DMPP). Recently, biological nitrification inhibitors have also attracted researchers' attention, which may be more environment-friendly. In addition, biochar commonly used as soil ameliorant to improve soil quality and C sequestration could also mitigate soil N2O emissions. Once all effective strategies would be widely implemented, more environment-friendly agriculture could be expected.




Gaseous Loss of Nitrogen from Plant-Soil Systems


Book Description

A growing interest has been shown recently in the dymanics of nitrogen in agricultural and natural ecosystems. This has been caused by increasing demands for food and fibre by a rapidly expanding world population, and by a growing concern that increased land clearing, cultivation and use of both fertilizer and biologically fixed nitrogen can have detrimental effects on the environment. These include effects on water quality, eutrophication of surface waters and changes in atmospheric composition all caused by increased cycling of nitrogenous compounds. The input and availability of nitrogen frequently affects the productivity of farming systems more than any other single management factor, but often the nitrogen is used inefficiently. Much of the fertilizer nitrogen applied to the soil is not utilised by the crop: it is lost either in solution form, by leaching of nitrate, or in gaseous forms as ammonia, nitrous oxide, nitric oxide or dinitrogen. The leached nitrate can contaminate rivers and ground waters, while the emitted ammonia can contaminate surface waters or combine with atmospheric sulfur dioxide to form aerosols which affect visibility, health and climate. There is also concern that increased evolution of nitrous oxide will deplete the protective ozone layer of the stratosphere. The possibility of a link between the intensity of agricultural use of nitrogen, nitrous oxide emissions and amounts of stratospheric ozone has focussed attention on these interactions.




Nitrogen Efficiency in Agricultural Soils


Book Description

A Seminar on nitrogen efficiency in agricultural soils and the efficiency use of fertilizer nitrogen, held in Edinburgh, 16-18 September 1987, as part of the EC Programme for the Coordination of Agricultural Research.




Nitrogen Cycle


Book Description

Anthropogenic activity has clearly altered the N cycle contributing (among other factors) to climate change. This book aims to provide new biotechnological approach representing innovative strategies to solve specific problems related to the imbalance originating in the N cycle. Aspects such as new conceptions in agriculture, wastewater treatment, and greenhouse gas emissions are discussed in this book with a multidisciplinary vision. A team of international authors with wide experience have contributed up-to-date reviews, highlighting scientific principles and their environmental importance and integrating different biotechnological processes in environmental technology.




Mitigating Gaseous Nitrogen and Carbon Losses From Northeastern Agricultural Soils Via Alternative Soil Management Practices


Book Description

Traditional agricultural practices often result in gaseous losses of nitrous oxide (N2O), ammonia (NH3), and carbon dioxide (CO2), representing a net loss of nutrients from agricultural soils, which negatively impacts crop yield and requires farmers to increase nutrient inputs. By adopting best management practices (BMPs; i.e., no-tillage, cover crops, sub-surface manure application, and proper manure application timing), there is great potential to reduce these losses. Because N2O and CO2 are also greenhouse gases (GHGs), climate change mitigation via BMP adoption and emissions reductions would be an important co-benefit. However, adopting a no-tillage and cover cropping system has had setbacks within the Northeast, primarily due to concerns regarding manure nitrogen (N) losses in no-tillage systems as well as uncertainty surrounding the benefits of cover crops. This thesis used two field-trials located in Alburgh, Vermont to assess differences in (i) GHG emissions from agricultural soils, (ii) nitrate and ammonium retention, (iii) corn yield and protein content, and (iv) N uptake and retention via cover crop scavenging under a combination of different BMPs. Chapter 1 evaluates the effects of different reduced-tillage practices and manure application methods (i.e., vertical-tillage, no-tillage, manure injection, and broadcast manure application) on reducing N2O and CO2 emissions, retaining inorganic N, and improving crop yields. Greenhouse gas measurements were collected every other week for the growing season of 2015-2017 via static chamber method using a photoacoustic gas analyzer. Results from this study showed that tillage regimes and manure application method did not interact to affect any of the three research objectives, although differences between individual BMPs were observed. Notably, vertical tillage enhanced CO2 emissions relative to no-tillage, demonstrating the role of soil disturbance and aeration on aerobic microbial C transformations. Manure injection was found to significantly enhance both N2O and CO2 emission relative to broadcast application, likely due to the formation of anerobic micro-zones created from liquid manure injection. However, plots that received manure injection retained greater concentrations of soil nitrate, a vital nutrient for quality crop production, thereby highlighting a major tradeoff between gaseous N losses and N retention with manure injection. Chapter 2 evaluates the effects of tillage practices and timing of manure application to increase N retention with the use of cover crops in order to mitigate GHG emissions, enhance soil nitrate and ammonium retention, and improve cropping system N uptake. Treatments at this field trial consisted of a combination of the presence or absence of cover crops, no-tillage or conventional-tillage, and spring or fall manure application. Greenhouse gas emissions were measured every other week via static chamber method using a gas chromatograph for the growing season of 2018. Results from this study showed that the presence of cover crops enhanced both N2O and CO2 emissions relative to fallow land, irrespective of tillage regime and manure application season, likely as a result of greater N and carbon substrates entering the soil upon cover crop decomposition. Due to enhanced N2O emissions with cover crops, cover crops did not retain significantly greater inorganic N in the system upon termination.




Effect of mineral N fertilizers – N form, amount and way of application – on nitrous oxide emissions from croplands


Book Description

The present work evaluated the effect of mineral nitrogen (N) fertilizer application during crop production on the potential risk of gaseous N loss in the form of nitrous oxide (N2O). Nitrous oxide (N2O) is an environmentally important atmospheric trace gas and contributes to the anthropogenic greenhouse effect. In addition, it is a precursor to photochemical nitric oxide (NO) production in the stratosphere which leads to stratospheric ozone depletion. Agriculture is considered to be the main source of anthropogenic N2O, with agricultural soils representing the single largest source due to nitrogen fertilizer applications during crop production. The purpose of this study was to examine the effects of mineral N fertilizers (N form, amount, mode of application) on N2O emissions from fertilized croplands in north-west Germany. Therefore several field trials, one greenhouse pot experiment and two incubation experiments were conducted. Nitrous oxide fluxes were measured by means of the closed chamber method. The length of the experimental period varied between experiments from several weeks (42 days) up to one-year measurement campaigns. The amount of N2O emitted during the crop growth period depended on the N form applied as well as on the mode of application, and a linear relationship between cumulative N2O emissions and total N fertilizer amount applied was found.