Nitrogen-Rich Polycyclic-Based Energetic Materials


Book Description

This book describes the design, synthesis, performance and practical application of energetic materials. The book consists of thirteen chapters demonstrating the design routes of nitrogen-rich polycyclic-based energetic materials that are bicyclic, tricyclic and tetracyclic-based. It presents the synthesis of the energetic backbone, the construction of linkage and the introduction of energetic units, which could have a positive impact on the chemistry of not only on high-energy-density materials but also in other fields. The book also provides detailed analysis of the experimental methods discussed. Work in this area will benefit from the combine expertise from organic, inorganic and physical chemistry as well as other connected disciplines. As such this book has wide appeal and will help in increasing fundamental knowledge of nitrogen-rich heterocycles to eventually allow for this knowledge to be transferred into industrial applications.




Nitrogen-Rich Energetic Materials


Book Description

Nitrogen-Rich Energetic Materials Provides in-depth and comprehensive knowledge on both the chemistry and practical applications of nitrogen-rich energetic materials Energetic materials, a class of material with high amounts of stored chemical energy, include explosives, pyrotechnics, and propellants. Initially used for military applications, nitrogen-rich energetic materials have become important in the civil engineering and aerospace sectors, they are increasingly used in commercial mining and construction as well as in rocket propulsion. Making these nitrogen-rich energetic materials safer, more powerful, and more cost-effective requires a thorough understanding of their chemistry, physics, synthesis, properties, and applications. Nitrogen-Rich Energetic Materials presents a detailed summary of the development of nitrogen-rich energetic materials over the past decade and provides up-to-date knowledge on their applications in various areas of advanced engineering. Edited by a panel of international experts in the field, this book examines the chemistry of pentazoles, fused ring and laser ignitable nitrogen-rich compounds, polynitrogen and tetrazole-based energetic compounds, and more. The text also introduces applications of nitrogen-rich energetic materials in energetic polymers and metal-organic frameworks, as pyrotechnics materials for light and smoke, and in oxadiazoles from precursor molecules. This authoritative volume: Presents in-depth chapters written by leading experts in each sub-field covered Offers a systematic introduction to new and emerging applications of nitrogen-rich energetic materials such as in computational chemistry Discusses recent advances in nitrate ester chemistry with focus on propellant applications Discusses green and eco-friendly approaches to nitrogen-rich compounds Nitrogen-Rich Energetic Materials is an important resource for researchers, academics, and industry professionals across fields, including explosives specialists, pyrotechnicians, materials scientists, polymer chemists, laser specialists, physical chemists, environmental chemists, chemical engineers, and safety officers.




Advanced Energetic Materials


Book Description

Advanced energetic materialsâ€"explosive fill and propellantsâ€"are a critical technology for national security. While several new promising concepts and formulations have emerged in recent years, the Department of Defense is concerned about the nation's ability to maintain and improve the knowledge base in this area. To assist in addressing these concerns, two offices within DOD asked the NRC to investigate and assess the scope and health of the U.S. R&D efforts in energetic materials. This report provides that assessment. It presents several findings about the current R&D effort and recommendations aimed at improving U.S. capabilities in developing new energetic materials technology. This study reviewed U.S. research and development in advanced energetics being conducted by DoD, the DoE national laboratories, industries, and academia, from a list provided by the sponsors. It also: (a) reviewed papers and technology assessments of non-U.S. work in advanced energetics, assessed important parameters, such as validity, viability, and the likelihood that each of these materials can be produced in quantity; (b) identified barriers to scale-up and production, and suggested technical approaches for addressing potential problems; and (c) suggested specific opportunities, strategies, and priorities for government sponsorship of technologies and manufacturing process development.




High Energy Density Materials


Book Description




Chemistry and Physics of Energetic Materials


Book Description

This book represents a collection of lectures presented at the NATO Advanced study Institute(ASI) on "Chemistry & Physics of the Molecular Processes in Energetic Materials", held at Hotel Torre Normanna, Altavilla Milicia, Sicily, Italy, September 3 to 15, 1989. The institute was attended by seventy participants including twenty lecturers, drawn from thirteen countries. The purpose of the institute was to review the major ad vances made in recent years in the theoretical and experi mental aspects of explosives and propellants. In accordance with the format of the NATO ASI, it was arranged to have a relatively small number of speakers to present in depth, re view type lectures emphasizing the basic research aspects of the subject, over a two week period. Most of the speakers gave two lectures, each in excess of one hour with addition al time for discussions. The scope of the meeting was limit ed to molecular and spectroscopic studies since the hydro dynamic aspects of detonation and various performance crite ria of energetic materials are often covered adequately in other international meetings. An attempt was made to have a coherent presentation of various theoretical, computational and spectroscopic approaches to help a better understanding of energetic materials from a molecular point of view. The progress already made in these areas is such that structure property (e. g.




Laser Ignition of Energetic Materials


Book Description

The book gives an introduction to energetic materials and lasers, properties of such materials and the current methods for initiating energetic materials. The following chapters and sections highlight the properties of lasers, and safety aspects of their application. It covers the properties of in-service energetic materials, and also materials with prospects of being used as insensitive ammunitions in future weapon or missiles systems or as detonators in civilian (mining) applications. Because of the diversity of the topics some sections will naturally separate into different levels of expertise and knowledge.




More Synthetic Approaches to Nonaromatic Nitrogen Heterocycles, 2 Volume Set


Book Description

More Synthetic Approaches to Nonaromatic Nitrogen Heterocycles An authoritative collection of resources discussing the latest trends in the synthesis of nonaromatic nitrogen heterocycles Widely distributed in nature, nitrogen heterocycles are extremely common in synthetic substances found in pharmaceuticals, agrochemicals, and materials. The literature is evolving rapidly and explores newly emerging structures and medicines. More Synthetic Approaches to Nonaromatic Nitrogen Heterocycles offers R&D professionals the opportunity to easily access a collection of the latest relevant research in the area. In the second two-volume set of this practical reference distinguished researcher Dr. Ana Maria M. M. Faisca Phillips delivers a collection of resources focusing on the newest and most widely applicable trends emerging in synthetic strategies for nonaromatic nitrogen heterocycles. With coverage of topics including organocatalysis, cascade reactions, flow chemistry in synthesis, cycloaddition reactions, metathesis, cross-coupling reactions, and electrochemistry, the book provides quick access to critical new avenues of synthesis. More Synthetic Approaches to Nonaromatic Nitrogen Heterocycles: Volume 1 and 2 also offers readers: A thorough introduction to recent advances in the design and synthesis of cyclic peptidomimetics Comprehensive explorations of fused heterocycles and transition metal promoted synthesis of isoindoline derivatives Practical discussions of 1,4-diazepane ring-based systems and recent advances in the synthesis of azepane-based compounds In-depth examinations of strained aziridinium ions, asymmetric organocatalysis in alternative media, and the electrochemical synthesis of non-aromatic N-heterocycles Perfect for academic and industrial researchers in organic chemistry and synthesis, organometallic chemistry, pharmaceutical chemistry catalysis, and sustainable chemistry, More Synthetic Approaches to Nonaromatic Nitrogen Heterocycles: Volume 1 and 2 is an indispensable reference for anyone seeking an authoritative source of information on new and emerging trends in synthesis.




Organic Chemistry of Explosives


Book Description

Organic Chemistry of Explosives is the first text to bring together the essential methods and routes used for the synthesis of organic explosives in a single volume. Assuming no prior knowledge, the book discusses everything from the simplest mixed acid nitration of toluene, to the complex synthesis of highly energetic caged nitro compounds. Reviews laboratory and industrial methods, which can be used to introduce aliphatic C-nitro, aromatic C-nitro, N-nitro, and nitrate ester functionality into organic compounds Discusses the advantages and disadvantages of each synthetic method or route, with scope, limitations, substrate compatibility and other important considerations Features numerous examples in the form of text, reaction diagrams, and tables.