Novel Liquid Crystalline Polymers as Nonlinear Optical Materials


Book Description

Research results are presented for side-chain liquid crystalline polymers as NLO materials. Design criteria are discussed for temporally stabilized SHG (Second Harmonic Generation) in these polymers. The importance of liquid crystallinity on SHG is described. Main-chain liquid crystalline polymers for both second- and third-order NLO are presented. A photo-Fries reaction on polyarylcinnamates leads to a potential second-order chromophore while in the third-order area, siloxane and methylene spacers between defined pi-conjugated segments confers solubility and lowered melting temperatures to these polymers.




Novel Liquid Crystals - Polymers and Monomers - As Nonlinear Optical Materials


Book Description

Progress is reviewed on research into the design, synthesis and characterization of, primarily, side chain liquid crystalline polymers for nonlinear optics. Materials described are polyesters and vinyl polymers and copolymers having push-pull pi-electronic nlo structures as pendant groups. Chiral derivatives have also been prepared. The nlo species employed have been nitroaromatics and pyridine N-oxides. Results of collaborative efforts in further characterization (electrooptic, dielectric, Langmuir-Blodgett films) are described. Keywords: Nonlinear optical materials; Liquid crystals; Polymers. (mjm).




Nonlinear Optical Properties of Liquid Crystals and Polymer Dispersed Liquid Crystals


Book Description

This monograph is devoted to a detailed treatment of the nonlinear optical properties of liquid crystals. The basic concepts of director optical reorientation and thermal nonlinearities are presented showing the fundamental theoretical approaches and describing the main experimental observations. The presentation is self-consistent and tutorial although the subject matter is of current research interest.The last part of the book deals with more recent results on new composite materials: Polymer Dispersed Liquid Crystals (PDLC). A general presentation of the optical properties is given and the observations of several nonlinear optical effects are reported.







Optics and Nonlinear Optics of Liquid Crystals


Book Description

This is a monograph/text devoted to a detailed treatment of the optical, electro-optical and nonlinear optical properties of all the mesophases of liquid crystals and related processes, phenomena and application principles. Quantitative data on material and optical parameters spanning the ultraviolet, visible, infrared as well as the microwave regimes are presented along with detailed theoretical treatments of basic liquid crystal physics, material properties and nonlinear optics.Starting with a discussion on the basic building blocks of liquid crystalline molecules, the authors proceed to present in a pedagogical manner current theories, experiments, and applications of these unique and important optical properties of liquid crystals. Numerous tables of hard-to-find liquid crystalline parameters, a self-contained chapter on general nonlinear optics, and comprehensive literature review are also included.




Novel Optical Materials and Applications


Book Description

The discussion of semiconductors focuses on nanostructures and quantized structures, which possess very high density optoelectronics data- and signal-processing capabilities. They also enable the creation of ever more efficient and broad spectral range lasers and optoelectronics devices. The many applications of liquid crystals have lately been expanded by the discovery of both new material systems and new phenomena. The new systems/phenomena discussed here include dye-doped liquid crystals and waveguide structures. Polymeric materials are viewed in the light of their electro-optical and nonlinear optical properties, which have been exploited in the latest achievements in ultrafast devices for optical modulations and efficient wavelength conversion processes and structures.




Nonlinear Optical Materials


Book Description

The first step in a new era where optics supersedes electronics was established by fiber optic communication. Optical data processing is now following with optical elements which can address and retrieve information directly using fiber optics. The new technology is progressing rapidly due to a major input of materials scientists guided by early pioneers such as Francis Garito and Joseph Zyss, who are among the contributors to this volume, which is divided into eight parts: molecular engineering and nonlinear optics, Langmuir-Blodgett films, nonlinear polymers, harmonic generation, nonlinear optical materials, photoreactive materials, nonlinear liquid crystals, and optical testing. No subject index. Annotation c. by Book News, Inc., Portland, Or.




Nonlinear Optical Materials: Principles and Applications


Book Description

Nonlinear optical materials play a pivotal role in the future evolution of nonlinear optics in general and its impact in technology and industrial applications in particular. The progress in nonlinear optics has been tremendous since the first demonstration of an all-optical nonlinear effect in the early sixties, but until recently the main visible emphasis was on the physical aspects of the nonlinear radiation matter interaction. In the last decade, however, this effort has also brought its fruits in applied aspects of nonlinear optics. This can be essentially traced to the improvement of the performances of the nonlinear optical materials. Our understanding of the nonlinear polarization mechanisms and their relation to the structural characteristics of the materials has been considerably improved. In addition, the new development of techniques for the fabrication and growth of artificial materials has dramatically contributed to this evolution. The goal is to find and develop materials presenting large nonlinearities and satisfying at the same time all the technological requirements for applications such as wide transparency range, fast response, high damage threshold but also processability, adaptability and interfacing with other materials. Improvements, besides rendering possible the implementation of nonlinear effects in devices, open the way to the study of new nonlinear optical effects and the introduction of new concepts. This book describes new concepts which are emerging in the field of nonlinear optical materials, concentrating the attention on materials which seem more promising for applications in the technology of information transmission and processing.