Gas-Solid Reactions


Book Description

Gas-Solid Reactions describes gas-solid reaction systems, focusing on the four phenomena—external mass transfer, pore diffusion, adsorption/desorption, and chemical reaction. This book consists of eight chapters. After the introduction provided in Chapter 1, the basic components of gas-solid reactions are reviewed in Chapter 2. Chapter 3 describes the reactions of individual nonporous solid particles, while Chapter 4 elaborates the reaction of single porous particles. Solid-solid reactions proceeding through gaseous intermediates are considered in Chapter 5. Chapter 6 deals with the experimental approaches to the study of gas-solid reaction systems. How information on single-particle behavior may be used for the design of multiparticle, large-scale assemblies, and packed- and fluidized-bed reaction systems is deliberated in Chapter 7. The last chapter covers the specific gas-solid reaction systems, including some statistical indices indicating the economic importance of the systems and processes it's based on. This publication is recommended for practicing engineers engaged in process research, development, and design in the many fields where gas-solid reactions are important.




The Reduction of Iron Ores


Book Description

For the English edition the book was revised by the authors, taking into account a number of suggestions of the readers of the German edition. Some of the most important publications in the field of iron ore reduction, which appeared since 1967, have been used to bring the manuscript as far as possible up to date. The kind assistance of Dr. K. BOHNENKAMP of the Max-Planck-Institut fUr Eisenforschung, Dusseldorf, was much appreciated in this respect. Ohapters 2.9 and 2.10, dealing with the reduction of molten oxide slags by solid carbon and with the contribution of the water-gas reaction to iron ore reduction, have been added for the English edition. Ohapter 2.9 has been completely revised with the kind assistance of Dr. H. J. GRABKE, Stuttgart. Dipl.-Ing. J. LODDE contributed to this edition by revising the bibliography. Owing to the rapid development of the blast furnace it was necessary to revise Ohapter 5 considerably. In this field many valuable suggestions have been made by Dipl.-Ing. G. LANGE and Dipl.-Ing. P. HEINRICH. Furthermore, Ohapters3 and 4 have been thoroughly revised by Dr.-Ing. E. FORSTER and Dr.-Ing. U. SCHIERLOH. Last, but not least, we have to thank our translators for their excellent work.







Iron in Soils and Clay Minerals


Book Description

Probably more than any other element, iron markedly influences the chemical and physical properties of soils and sediments in the earth. Considering its transition metal status, with potential variation in electronic configuration, ionic radius, and magnetic moment, combined with its abundance and relatively large mass, little wonder that one sees its unique influence on every hand. Pre sentations at the NATO Advanced Study Institute (NATO AS!) on Iron in Soils and Clay Minerals reviewed and discussed the occurrence, behavior, and properties of Fe-bearing minerals found in soils and in the clay mineral groups kaolinite, smectite, and mica. Also discussed at the NATO AS! were the basic chemical properties of Fe, methods for separating and identifying Fe in minerals, and the role of Fe minerals in weathering and other soil-forming processes. The present publication is the reviewed and edited proceedings of that Advanced Study Institute. The sequence of chapters follows the general pattern beginning with introductory chapters which overview the general occurrence of Fe in the earth and its chemistry, both generally and in mineral environments, followed by identification and characterization methods for Fe and Fe phases in minerals. The properties and behavior of Fe oxides, Fe-bearing clay minerals, and other Fe minerals in soils are then described, and the text ends with a summary of the role of Fe in soil-forming processes. A Table of Contents and subject index are provided to assist the reader in finding specific topics within the text.




The Iron Oxides


Book Description

This book brings together in one, compact volume all aspects of the available information about the iron oxides. It presents a coherent, up to date account of the properties, reactions and mechanisms of formation of these compounds. In addition, there are chapters dealing with iron oxides in rocks and soils, as biominerals and as corrosion products together with methods of synthesis and the numerous application of these compounds. Their role in the environment is also discussed. The authors are experts in the field of iron oxides and have worked on all the topics covered. Much recent data from the authors' own laboratories is included and opportunities for further research are indicated. Special features are the electron micrographs and colour plates together with the many different spectra used to illustrate properties and aspects of behaviour. Numerous tables and graphs enable trends and relationships to be seen at a glance. The book concludes with an extensive bibliography. This book should prove invaluable to industry and to all researchers who, whatever their background and level of experience, are interested in this rapidly expanding field. It is an essential volume for any scientific library and is now in its second, completely revised and extended edition!




SPONGE IRON PRODUCTION BY DIRECT REDUCTION OF IRON OXIDE


Book Description

This book provides a fascinating study of the very important emerging field of direct reduction in which iron ore is ‘directly reduced’ in the solid-state, using either natural gas or non-coking coal, to produce a highly metallised material, referred to as sponge iron (or direct reduced iron). This intermediate product is subsequently melted in electric arc furnaces or induction furnaces (sometimes even in basic oxygen furnaces) to produce liquid steel. Such a process combination enables steel to be produced without using coking coal, which is an expensive input in the normal blast furnace—basic oxygen furnace route of steelmaking adopted in integrated steel plants. The book offers comprehensive coverage and critical assessment of various coal-based and gas-based direct reduction processes. Besides dealing with the application of the theoretical principles involved in the thermodynamics and kinetics of direct reduction, the book also contains some worked-out examples on sponge iron production. The concluding part of this seminal book summarises the present and future scenario of direct reduction, including the use of gas generated from coal in direct reduction processes. The book is primarily intended for the undergraduate and postgraduate students of metallurgical engineering. It is also a must-read for researchers, technologists and process metallurgists engaged in the rapidly developing field of direct reduction of iron oxides, which is of critical importance for India and other developing nations that are beginning to play a major role in global steelmaking.




Iron Nutrition and Interactions in Plants


Book Description

Many agricultural crops worldwide, especially in semi-arid climates, suffer from iron deficiencies. Among plants sensitive to iron deficiency are apples, avocado, bananas, barley, beans, citrus, cotton, grapes, peanuts, pecans, potatoes, sorghum, soybeans, and numerous ornamental plants. Deficiencies are usually recognized by chlorotic, in new leaves and are typically found among sensitive crops grown in calcareous or yellowed, interveinal areas soils which cover over 30% of the earth's land surface. Iron deficiency may lead, in extreme cases, to complete crop failure. In intensive agriculture on calcareous soils, iron often becomes a major limiting nutrient for optimal crop production, thus, correction of iron deficiency is required. Various chemicals and practices are available. They are, however, costly and do not always result in a complete remedy of the deficiency. Crucial questions relative to the cost-benefit equation such as the recovery rate of plants and the long-term fertilizing effect have not yet been resolved. The complexity of iron nutrition problems requires an understanding of the chemistry of iron oxides in soils, of the chemistry of both natural and synthetic chelates, of rhizosphere microbiology and biochemistry, and of the physiological involvement of the plant in iron uptake and transport.




Iron Ores and Iron Oxide Materials


Book Description

This book provides the multidisciplinary reading audience with a comprehensive state-of-the-art overview of research and innovations in the relationship between iron ores and iron ore materials. The book covers industrial sectors dealing with exploration and processing of iron ores as well as with advanced applications for iron ore materials and therefore entails a wide range of research fields including geology, exploration, beneficiation, agglomeration, reduction, smelting, and so on, thus encouraging life cycle thinking across the entire production chain. Iron remains the basis of modern civilization, and our sustainable future deeply depends upon our ability to satisfy the growing demand for iron and steel while decoupling hazardous emissions from economic growth. Therefore, environmental sustainability aspects are also broadly addressed. In response to socioeconomic and climatic challenges, the iron ore sector faces, this book delivers a vision for the new opportunities linked to deployment of the best available, innovative and breakthrough technologies as well as to advanced material applications.




The Iron Oxides


Book Description

This book brings together in one, compact volume all aspects of the available information about the iron oxides. It presents a coherent, up to date account of the properties, reactions and mechanisms of formation of these compounds. In addition, there are chapters dealing with iron oxides in soils, as biominerals and as corrosion products together with methods of synthesis and the numerous application of these compounds. The authors are experts in the field of iron oxides and have worked on all the topics covered. Much recent data from the authors' own laboratories is included and opportunities for further research are indicated. Special features are the electron micrographs and colour plates together with the many different spectra used to illustrate properties and aspects of behaviour. Numerous tables and graphs enable trends and relationships to be seen at a glance. The book concludes with an extensive bibliography. This book should prove invaluable to industry and to all researchers who, whatever their background and level of experience, are interested in this rapidly expanding field. It is an essential volume!




Rotating Electrode Methods and Oxygen Reduction Electrocatalysts


Book Description

Rotating Electrode Methods and Oxygen Reduction Electrocatalysts provides the latest information and methodologies of rotating disk electrode and rotating ring-disk electrode (RDE/RRDE) and oxygen reduction reaction (ORR). It is an ideal reference for undergraduate and graduate students, scientists, and engineers who work in the areas of energy, electrochemistry science and technology, fuel cells, and other electrochemical systems. - Presents a comprehensive description, from fundamentals to applications, of catalyzed oxygen reduction reaction and its mechanisms - Portrays a complete description of the RDE (Rotating Disc Electrode)/RRDE (Rotating Ring-Disc Electrode) techniques and their use in evaluating ORR (Oxygen Reduction Reaction) catalysts - Provides working examples along with figures, tables, photos and a comprehensive list of references to help understanding of the principles involved