Oxidation in Organic Chemistry 5-B


Book Description

Organic Chemistry, Volume 5-B: Oxidation in Organic Chemistry, Part B presents some of the most common and significant reactions in organic chemistry, which involves oxidation and reduction. This book provides detailed discussions of specific oxidants or topics concerning oxidation of organic compounds. Organized into four chapters, this volume begins with an overview of the specific oxidants, including thallium(III), cupric ion, and ruthenium tetroxide. This text then presents the scope and preparative use as well as the mechanistic aspects of the various oxidations. Other chapters consider the significance of phenolic oxidative coupling in nature's biosynthetic pathways. This book discusses as well the various mechanistic alternatives for the enzymic and non-enzymic reactions, which will lead to a fuller understanding of the enzymic mechanisms and the greater synthetic utility of this reaction. The final chapter deals with the oxidative coupling of phenols. This book is a valuable resource for organic chemists and research workers.




Oxidation in Organic Chemistry 5-D


Book Description

Organic Chemistry, A Series of Monographs, Volume 5-D: Oxidation in Organic Chemistry is a four-chapter text that discusses the specific oxidants in oxidation reactions of organic compounds. Chapter I covers oxidations with lead tetraacetate, an oxidant that has been used widely for the selective oxidation of a variety of functional groups. Chapter II examines an oxidant that has a long and extensive history, the permanganate, with emphasis on phase transfer assisted permanganate oxidations. Chapter III discusses the intramolecular oxidative coupling of aromatic substrates, highlighting the utility of developed methods, such as vanadium oxytrifluoride oxidations, in the syntheses of complex natural products. Chapter IV describes the process of coal oxidation with emphasis on the selective oxidative degradation procedures as tools for characterization of coal structure. This text will be of value to organic chemists, researchers, teachers, and students who are interested in oxidation of organic compounds.




Oxidation in Organic Synthesis


Book Description

Oxidation plays a crucial role in organic synthesis. This volume presents the array of oxidizing agents and their applications in oxidations. The book describes in great detail a number of reagents of importance. The text includes oxidation of specific types of organic compounds including hydrocarbons, alcohols, phenols, ethers, carbonyl compounds, carboxylic acids, amides, hydrazides, nitro compounds, nitroso compounds, hydroxylamines, azo compounds, azides, hydrazo compounds, amines, phosphorus, arsenic and sulphur compounds. It also covers enzymatic or microbial oxidations as well as oxidations under benign conditions.




Oxidizing and Reducing Agents


Book Description

Oxidizing and Reducing Agents S. D. Burke University of Wisconsin at Madison, USA R. L. Danheiser Massachusetts Institute of Technology, Cambridge, USA Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis. Handbook of Reagents for Organic Synthesis: Oxidizing and Reducing Agents, provides the synthetic chemist with a convenient compendium of information concentrating on the most important and frequently employed reagents for the oxidation and reduction of organic compounds, extracted and updated from EROS. The inclusion of a bibliography of reviews and monographs, a compilation of Organic Syntheses procedures with tested experimental details and references to oxidizing and reducing agents will ensure that this handbook is both comprehensive and convenient.




Oxidation and Antioxidants in Organic Chemistry and Biology


Book Description

Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information




March's Advanced Organic Chemistry


Book Description

The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations




Organic Chemistry of Enzyme-Catalyzed Reactions, Revised Edition


Book Description

The Organic Chemistry of Enzyme-Catalyzed Reactions is not a book on enzymes, but rather a book on the general mechanisms involved in chemical reactions involving enzymes. An enzyme is a protein molecule in a plant or animal that causes specific reactions without itself being permanently altered or destroyed. This is a revised edition of a very successful book, which appeals to both academic and industrial markets. - Illustrates the organic mechanism associated with each enzyme-catalyzed reaction - Makes the connection between organic reaction mechanisms and enzyme mechanisms - Compiles the latest information about molecular mechanisms of enzyme reactions - Accompanied by clearly drawn structures, schemes, and figures - Includes an extensive bibliography on enzyme mechanisms covering the last 30 years - Explains how enzymes can accelerate the rates of chemical reactions with high specificity - Provides approaches to the design of inhibitors of enzyme-catalyzed reactions - Categorizes the cofactors that are appropriate for catalyzing different classes of reactions - Shows how chemical enzyme models are used for mechanistic studies - Describes catalytic antibody design and mechanism - Includes problem sets and solutions for each chapter - Written in an informal and didactic style




Basic Principles of Organic Chemistry


Book Description

Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.




Electron Transfer Reactions in Organic Chemistry


Book Description

The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.