Photochemistry of Heterocycles


Book Description

Photochemistry of Heterocycles is a comprehensive review of the topic, including photooxidation, photoreduction and photoaddition reactions as well as industrial aspects of heterocyclic photochemistry. Many materials used for the manufacturing of OLEDs and other electrooptical switches contain heterocycles, and the use of small molecules or polymers containing heterocyclic substances are being studied as new photovoltaic materials. This reference is ideal for synthetic organic chemists, specifically researchers working in organic photochemistry, as well as medicinal chemists and material scientists. Heterocyclic compounds are widely used in the modern world, and most of the drugs currently in use have heterocyclic nuclei among their constituents. These compounds are subject to a photochemical degradation processes which must be known and prevented. Presents an authoritative and comprehensive review of the photochemistry of heterocycles Covers the full spectrum of photochemical reactivity, including photoreduction and photoaddition reactions of heterocyclic compounds Includes industrial aspects of heterocyclic photochemistry and materials used to manufacture OLEDs and other electrooptical switches




Photochemistry of Heterocycles


Book Description

Photochemistry of Heterocycles is a comprehensive review of the topic, including photooxidation, photoreduction and photoaddition reactions as well as industrial aspects of heterocyclic photochemistry. Many materials used for the manufacturing of OLEDs and other electrooptical switches contain heterocycles, and the use of small molecules or polymers containing heterocyclic substances are being studied as new photovoltaic materials. This reference is ideal for synthetic organic chemists, specifically researchers working in organic photochemistry, as well as medicinal chemists and material scientists. Heterocyclic compounds are widely used in the modern world, and most of the drugs currently in use have heterocyclic nuclei among their constituents. These compounds are subject to a photochemical degradation processes which must be known and prevented. - Presents an authoritative and comprehensive review of the photochemistry of heterocycles - Covers the full spectrum of photochemical reactivity, including photoreduction and photoaddition reactions of heterocyclic compounds - Includes industrial aspects of heterocyclic photochemistry and materials used to manufacture OLEDs and other electrooptical switches




Heterocyclic N-Oxides


Book Description

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal.




Preparative Organic Photochemistry


Book Description

(Abridged and translated) Organic photochemistry may be divided into three parts: theory which is the province of the physical chemist; instrumentation which requires the skill of both physicist and engineer; and preparation which falls within the sphere of the organic chemist. At one time the same person could cover all three fields without too much difficulty, but this has now become virtually impossible because the disciplines involved have expanded in both breadth and depth; it is there fore timely to have a separate treatment of preparative organic photo chemistry. There appears to be no review of the main photochemical reactions which includes the advances made in recent years available to the organic chemist working in the preparative field. An exception is the excellent "Photochemical Reactions" by C. R. MASSON, V. BOEKELHEIDE and W. A. NoYES JR., published in 1956, which gives a brief review of the reactions which are important in preparative organic photochemistry. The present monograph on the other hand seeks to provide a detailed survey for the chemist; the author does not set out to discuss every photo chemical reaction in the field of organic chemistry but he does include in addition to those of current interest in the preparative field some which are likely to be of interest in the future and which result in single end-products of known composition. The photochemical synthesis of highly polymerized products falls outside the scope of the work.




Organometallic Chemistry of Five-Membered Heterocycles


Book Description

Organometallic Chemistry of Five-Membered Heterocycles explores the synthesis, coordination modes, reactivity of coordinated five-membered monoheterocycles, and organometallic complexes of their numerous derivatives, including chelating ligands, oligomers, and macrocycles. Beginning with the introduction of organometallic compounds, this book dives deep into the reactivity of coordinated five-membered monoheterocycles and the derivatives of fundamental ligands. This book is an ideal reference for researchers working in organometallic, heterocyclic, materials, or organic chemistry, and catalysis. The readers will gain a comprehensive understanding of modern synthetic methods, reactivity trends of heteroaromatic ligands, and the methods of modern materials construction.




CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2


Book Description

The second edition of this best-selling handbook is bigger, more comprehensive, and now completely current. In addition to thorough updates to the discussions featured in the first edition, this edition includes 66 new chapters that reflect recent developments, new applications, and emerging areas of interest. Within the handbook's 145 critically r







The Paternò-Büchi Reaction


Book Description

The book represents the most complete description of the scientific results obtained on a photochemical experiment described 110 years ago by the Italian scientist Emanuele Paternò. This detailed that the photochemical reaction between a carbonyl compound and an alkene gives a corresponding oxetane. This oxetane ring is present in several naturally occurring compounds and bioactive compounds, and can be obtained with high regio- and stereoselectivity.




Organic Redox Chemistry


Book Description

Organic Redox Chemistry Explore the most recent advancements and synthesis applications in redox chemistry Redox chemistry has emerged as a crucial research topic in synthetic method development. In Organic Redox Chemistry: Chemical, Photochemical and Electrochemical Syntheses, some key researchers in this field, including editors Dr. Frédéric W. Patureau and the late Dr. Jun-Ichi Yoshida, deliver an insightful exploration of this rapidly developing topic. This book highlights electron transfer processes in synthesis by using different techniques to initiate them, allowing for a multi-directional perspective in organic redox chemistry. Covering a wide array of the important and recent developments in the field, Organic Redox Chemistry will earn a place in the libraries of chemists seeking a one-stop resource that compares chemical, photochemical, and electrochemical methods in organic synthesis.




Organic Photochemistry


Book Description

Organic photochemistry is the science arising from the application of photochemicalmethods to organic chemistry and organic chemical methods to photochemistry. It is aninterdisciplinary frontier.Intense activity in organic photochemistry in the last decade has produced so vast anaccumulation of factual knowledge that chemists in general have viewed it with awe.Even those chemists engaged in the study of organic photochemistry will find the rate ofdevelopment in the field perplexing to a high degree. This series originated to fill theneed for a critical summary of this vigorously expanding field with the purpose ofdrawing together seemingly unrelated facts, summarizing progress, and clarifyingproblems.Volume 11 continues to fulfill the original, essential role of this unique series byproviding a convenient review of the structural aspects of organic photochemistry. Aswith earlier volumes, this new book offers the research findings of distinguishedauthorities. It stresses timely aspects of organic photochemistry-previously scatteredthroughout the large body of literature-for which necessary critical review has beenlacking.This volume of the series emphasizes the mechanistic details of the di-n:-methanerearrangement . .. the synthetic aspects of the oxadi-n:-methane reaction ... thephotochemistry of carbenium ions and related species .. . photoinduced hydrogen atomabstraction by carbonyl compounds ... and matrix photochemistry of nitrenes, carbenes,and excited triplet states. Complete with numerous illustrations and bibliographiccitations of the literature, this book explores these important processes to the advantageof organic chemists, as an aid to research and as a source for supplementary knowledgeon particular topics .