Physico-Chemical Phenomena in Thin Films and at Solid Surfaces


Book Description

The book is devoted to the consideration of the different processes taking place in thin films and at surfaces. Since the most important physico-chemical phenomena in such media are accompanied by the rearrangement of an intra- and intermolecular coordinates and consequently a surrounding molecular ensemble, the theory of radiationless multi-vibrational transitions is used for its description. The second part of the book considers the numerous surface phenomena. And in the third part is described the preparation methods and characteristics of different types of thin films. Both experimental and theoretical descriptions are represented. Media rearrangement coupled with the reagent transformation largely determines the absolute value and temperature dependence of the rate constants and other characteristics of the considered processes. These effects are described at the atomic or molecular level based on the multi-phonon theory, starting from the first pioneering studies through to contemporary studies.A number of questions are included at the end of many chapters to further reinforce the material presented.· Unified approach to the description of numerous physico-chemical phenomena in different materials· Based on the pioneering research work of the authors· Explantion of a variety of experimental observations· Material is presented at two levels of complexity for specialists and non-specialists · Identifies existing and potential applications of the processes and phenomena · Includes questions at the end of some chapters to further reinforce the material discussed




The Molecular Theory of Adsorption in Porous Solids


Book Description

In the adsorption phenomenon the substances from the external environment the gas or liquid are absorbed by a solid surface (adsorbent). Adsorption is used to separate gaseous and liquid mixtures, for drying and purification of gases and liquids. This reference broadly explores the calculation of the equilibrium and dynamic characteristics of adsorption in porous bodies at the molecular level. Two new theories of statistical physics are presented, both developed by the author for the consistent description of the equilibrium distribution of molecules and dynamics of flows in complex porous materials to be able to solve a wide range of practical tasks in the development of new technologies.




Modern Technologies for Creating the Thin-film Systems and Coatings


Book Description

Development of the thin film and coating technologies (TFCT) made possible the technological revolution in electronics and through it the revolution in IT and communications in the end of the twentieth century. Now, TFCT penetrated in many sectors of human life and industry: biology and medicine; nuclear, fusion, and hydrogen energy; protection against corrosion and hydrogen embrittlement; jet engine; space materials science; and many others. Currently, TFCT along with nanotechnologies is the most promising for the development of almost all industries. The 20 chapters of this book present the achievements of thin-film technology in many areas mentioned above but more than any other in medicine and biology and energy saving and energy efficiency.




Cu(In1-xGax)Se2 Based Thin Film Solar Cells


Book Description

Cu(In1-xGax)Se2 Based Thin Film Solar Cells provides valuable contents about the fabrication and characterization of chalcopyrite Cu(In1-xGax)Se2 based thin film solar cells and modules. The growth of chalcopyrite Cu(In1-xGax)(S1-ySey)2 absorbers, buffers, window layers, antireflection coatings, and finally metallic grids, which are the sole components of solar cells, is clearly illustrated. The absorber, which contains multiple elements, segregates secondary phases if the growth conditions are not well optimized i.e., the main drawback in the fabrication of solar cells. More importantly the solutions for the growth of thin films are given in detail. The properties of all the individual layers and single crystals including solar cells analyzed by different characterization techniques such as SEM, AFM, XPS, AES, TEM, XRD, optical, photoluminescence, and Raman spectroscopy are explicitly demonstrated. The electrical analyses such as conductivities, Hall mobilities, deep level transient spectroscopy measurements etc., provide a broad picture to understand thin films or single crystals and their solar cells. The book clearly explains the working principle of energy conversion from solar to electrical with basic sciences for the chalcopyrite based thin film solar cells. Also, it demonstrates important criteria on how to enhance efficiency of the solar cells and modules. The effect of environmental factors such as temperature, humidity, aging etc., on the devices is mentioned by citing several examples. - Illustrates a number of growth techniques to prepare thin film layers for solar cells - Discusses characterization techniques such as XRD, TEM, XPS, AFM, SEM, PL, CL, Optical measurements, and Electrical measurements - Includes I-V, C-V measurements illustrations - Provides analysis of solar cell efficiency - Presents current trends in thin film solar cells research and marketing




Computer Vision In Robotics And Industrial Applications


Book Description

The book presents a collection of practical applications of image processing and analysis. Different vision systems are more often used among others in the automotive industry, pharmacy, military and police equipment, automated production and measurement systems. In each of these fields of technology, digital image processing and analysis module is a critical part of the process of building this type of system. The majority of books in the market deal with theoretical issues. However, this unique publication specially highlights industrial applications, especially industrial measurement applications. Along with its wide spectrum of image processing and analysis applications, this book is an interesting reference for both students and professionals.




Polymer Surfaces and Interfaces


Book Description

In what is an extremely practical and applicable new work, experts provide concise explanations, with examples and illustrations, of the key techniques in this important field. In each case, after basic principles have been reviewed, applications of the experimental techniques are discussed and illustrated with specific examples. Scientists and engineers in research and development will benefit from an application-oriented book that helps them to find solutions to both fundamental and applied problems. They will know that the surfaces and interfaces of polymers play an important role in most of the application areas of polymers, from moulds, foils, and composites, to biomaterials and applications in micro- and nanotechnology.




2D and Quasi-2D Composite and Nanocomposite Materials


Book Description

2D and Quasi-2D Composite and Nanocomposite Materials: Theory, Properties and Photonic Applications covers the theory, characterization and computational modeling of 2D composite materials and shows how they are used for the creation of materials for 3D structures The book covers three major themes: - Properties of 2D and quasi-2D composites are discussed in the context of homogenization theory. Homogenization results are discussed for spatiotemporal material composites assembled from materials which are distributed on a micro-scale in space and in time. - New types of transport phenomena and localization in random media are addressed, with particular attention to the non-reciprocity of transport coefficients. - Plasmonics and magneto-optics are also of particular interest. Magneto-transport and sub-wavelength resolution in electromagnetic and acoustic imaging are further considered. This book is an important resource for materials scientists and engineers working on nanomaterials, photonic composites, and materials theory, modeling and simulations. - Outlines major modelling techniques of 2D nanocomposites for photonic applications - Explores how the properties of 2D nanocomposites make them suitable for use for building 3D structures - Assesses the challenges of using 2D nanocomposites for designing new devices on a mass scale




Small Systems and Fundamentals of Thermodynamics


Book Description

Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.




Bimodal Oxidation


Book Description

This book is devoted to the problems of oxidation chemical reactions and addresses bimodal reaction sequences. Chemical reactions of oxidation, occurring under certain conditions and in multicomponent systems are complex processes. The process of the oxidation essentially changes in the presence and contact of the solid substances with reactants. The role of solid substances and the appearance of this phenomenon in oxidation reaction are discussed. The reader will understand the "driving forces" of this phenomenon and apply it in practice. Written for chemists, physicists, biologists and engineers working in the domain of oxidation reactions. Key Selling Features: Covers the historical background, modern state of the art, and perspectives in investigations of the coupling between heterogeneous and homogeneous reactions Discusses the feasible pathways of the coupling of heterogeneous and homogeneous reactions in oxidation in man-made and natural chemical systems Addresses the abundance, peculiarities and mechanisms of the bimodal reaction sequences in oxidation with dioxygen in recent decades Discusses the existence of the bimodal reaction sequences in chemical systems investigations in atmospheric chemistry and heterogeneous photocatalysis Presented in a simple concise style, accessible for both specialists and non-specialists




Films on Solid Surfaces


Book Description

Films on Solid Surfaces presents the physics and chemistry of physical adsorption. This book contains 10 chapters that are ordered according to the flow of a course given in a graduate study in University of Washington during 1973. The introductory chapter presents the motivation for the completion of the book. As the motivating factors are established, the book follows with the topic on atomic nature of physical adsorption and the states of single adsorbed atoms. A review of experimental techniques for the study of solid surfaces and films is given, as well as a discussion of substrate preparation and equilibrium thermodynamics. The various states of films and their phase transitions encompass four chapters. Lastly, the book also reviews thin film superfluidity. This book specifically caters to scientists in the fields of physics and biology working on physical adsorption and surface science.