Polycyclic Aromatic Hydrocarbons and Astrophysics


Book Description

The near Infra-Red emission of the Interstellar Medium is a very puzzling subject. In the brightest regions, where spectroscopic observa tions are possible from the ground, several bands (3.3 - 3.4 - 6.2 - 7.7 - 8.6 - 11.3 ~m) have been observed since 1973. The absence of satisfying explanation was so obvious that they were called "Unidenti fied IR Emission Bands". The puzzle still increased when were known the first results of the general IR sky survey made by the satellite IRAS. On a large scale, the near IR emission of the Interstellar medium was expected to be very small but it was observed to be about one third of the total IR emission for our own galaxy ..• The situation has moved in 1984 when it was suggested that a class of stable organic molecules, the Polycyclic Aromatic Hydrocarbons (PAH's) could be at the origin of this near IR emission. Initially based on the required refractory character of particules that should be heated to high temperature without subliming, this hypothesis leads to a sugges tive spectroscopic similarity with the observed astronomical bands. This hypothesis is attractive and it has many implications, for ins tance, the PAHs would be the most abundant organic molecules in the universe. However, many points have to be clarified and the different consequences of this suggestion should be explored.




The Diffuse Interstellar Bands


Book Description

The mystery of the diffuse interstellar bands has been variously a curiosity, a co nundrum, and a nuisance for astronomers in the seven decades since the features were first noticed, but recently they have become a forefront issue in astrophysics. Ever since Paul Merrill, in a series of papers starting in 1934, pointed out the interstellar and unidentified nature of the bands, a Who's Who of twentieth century astronomers have tried their hands at solving the problem of identifying the carriers. Henry Norris Russell, Pol Swings, Otto Struve, Paul Ledoux, W. W. Morgan, Walter Adams, Jesse Greenstein, Lawrence Aller, and Gerhard Herzberg all briefly entered the stage, only to move on quickly to other problems where the chances for progress appeared more realistic. In more recent times a number of equally prominent scientists have pursued the bands, but generally only as a sideline to their real astronomical research. But in the past decade, and particularly in the past three years, the view of the search for the diffuse band absorbers as an interesting but perhaps quixotic quest has changed. Today there are several astronomers, as well as laboratory chemists, who are devoting substantial research time and resources to the problem and, as perhaps the most reliable indicator of the newly elevated status of research in this field, some research grants have now been awarded for the study of the bands.







Evolution of Polycyclic Aromatic Hydrocarbons in the Interstellar Space -


Book Description

The space between stars within galaxies is not empty; it is filled with gas and dust. Polycyclic aromatic hydrocarbons (PAHs) are one of the most complex organic species found in space. Over the past 20 years it has become increasingly clear that we live in a molecular universe: Molecules are directly interwoven into the fabric of the universe.Multiple formation mechanisms are discussed for interstellar PAHs, both in and ex situ. These pertain to molecular clouds and stellar ejecta, for which physical parameters vary largely. In the stellar ejecta of carbon-rich Asymptotic Giant Branch stars, terrestrial-combustion-like chemical reactions are more likely to take place, of which the products can be transported to the interstellar medium (ISM) by interstellar wind.One of the aims of this book is also to extensively discuss PAHs impact on the environment and the magnitude of the human health risks posed by such substances. It also contains important information on concentrations, burdens and fate of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere.This book is designed for students of Astrophysics, Environmental Science, Environmental chemistry, Astronomy enthusiast, Health and safety professional and other professionals who wants to increase or update their knowledge in the area of polycyclic aromatic hydrocarbons and the interstellar space.




The Interstellar Medium


Book Description

Describing interstellar matter in our galaxy in all of its various forms, this book also considers the physical and chemical processes that are occurring within this matter. The first seven chapters present the various components making up the interstellar matter and detail the ways that we are able to study them. The following seven chapters are devoted to the physical, chemical and dynamical processes that control the behaviour of interstellar matter. These include the instabilities and cloud collapse processes that lead to the formation of stars. The last chapter summarizes the transformations that can occur between the different phases of the interstellar medium. Emphasizing methods over results, The Interstellar Medium is written for graduate students, for young astronomers, and also for any researchers who have developed an interest in the interstellar medium.




Investigating the Formation Mechanism of Polycyclic Aromatic Hydrocarbons and Adapting Particle Swarm Optimization Techniques to Search Large Data Sets


Book Description

The unidentified infrared bands (UIBs) have been attributed to emission from polycyclic aromatic hydrocarbons (PAHs). The UIBs at 3.3 and 11.3 [mu]m, among others, are seen in many astrophysical environments, with the notable exception of carbon-rich AGB stars (C stars). PAHs are expected to form around C stars, yet only a few show the UIBs and all of these have hot companions. This makes C stars with hot companions an ideal environment to study the conditions associated with PAH formation and processing. We present new observations, taken using the Gemini North telescope, of several C stars with hot companions in order to understand the distribution of PAHs responsible for the emerging UIB emission. As the size of data and model sets continue to increase, more efficient ways are needed to sift through the available information. We also present a computational method which will efficiently search large parameter spaces to either map the space or find individual data/models of interest. This is done through a heavily modified Particle Swarm Optimization algorithm.




Astrochemistry


Book Description

The dynamic field of astrochemistry brings together ideas of physics, astrophysics, biology and chemistry to the study of molecules between stars, around stars and on planets. Astrochemistry: from Astronomy to Astrobiology provides a clear and concise introduction to this rapidly evolving multidisciplinary subject. Starting with the Molecular Universe, the text covers the formation of the elements, simple models of stars and their classification. It then moves on to draw on the theme of the Origins of Life to study interstellar chemistry, meteorite and comet chemistry as well as the chemistry of planets. Prebiotic chemistry and astrobiology are explored by examining the extremes of the biosphere on Earth, seeing how this may be applied to life in other solar systems. Astrochemsitry assumes a basic familiarity with principles of physical and organic chemistry but no prior knowledge of biology or astrophysics. This innovative text incorporates results from the latest research and ground and space missions, with key images enhanced by a colour plate section. includes latest research and results from ground and space missions colour plate section summary of concepts and calculations at the end of each chapter accompanying website www.wiley.co/go/shawastrochemistry This book will be an ideal text for an undergraduate course in Astrochemistry and an essential tool for postgraduates entering the field.




Theory and Applications of Computational Chemistry


Book Description

Computational chemistry is a means of applying theoretical ideas using computers and a set of techniques for investigating chemical problems within which common questions vary from molecular geometry to the physical properties of substances. Theory and Applications of Computational Chemistry: The First Forty Years is a collection of articles on the emergence of computational chemistry. It shows the enormous breadth of theoretical and computational chemistry today and establishes how theory and computation have become increasingly linked as methodologies and technologies have advanced. Written by the pioneers in the field, the book presents historical perspectives and insights into the subject, and addresses new and current methods, as well as problems and applications in theoretical and computational chemistry. Easy to read and packed with personal insights, technical and classical information, this book provides the perfect introduction for graduate students beginning research in this area. It also provides very readable and useful reviews for theoretical chemists. * Written by well-known leading experts * Combines history, personal accounts, and theory to explain much of the field of theoretical and compuational chemistry * Is the perfect introduction to the field




Astrophysics of Dust


Book Description




Aromatic Polycyclic Hydrocarbons—Advances in Research and Application: 2012 Edition


Book Description

Aromatic Polycyclic Hydrocarbons—Advances in Research and Application: 2012 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Aromatic Polycyclic Hydrocarbons. The editors have built Aromatic Polycyclic Hydrocarbons—Advances in Research and Application: 2012 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Aromatic Polycyclic Hydrocarbons in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Aromatic Polycyclic Hydrocarbons—Advances in Research and Application: 2012 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.