Environmentally Benign Catalysts


Book Description

Over the past twenty years, Catalysis by Heteropolyacids (HPAs) has received wide attention and led to new and promising developments both at academic and industrial level. In particular, heterogeneous catalysis is particularly attractive because it generally satisfies most of green chemistry’s requirements. By emphasizing the development of third generation catalysts, this volume presents trends and opportunities in academic and industrial research. The book appeals to postgraduates, researchers, and chemists working in the field of environmentally benign catalysts as well as catalytic processes.




Liquid Phase Oxidation via Heterogeneous Catalysis


Book Description

Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.




Plants and BioEnergy


Book Description

A country's vision for developing renewable and sustainable energy resources is typically propelled by three important drivers – security, cost, and environmental impact. The U.S. currently accounts for a quarter of the world’s total oil consumption, with domestic demands necessitating – at an ever growing cost – a net import of more than 50% of the oil used in this country. At the same time, Brazil, because of its forward thinking on energy strategy, is today energy independent. As emerging economies around the world increase their petroleum use by large margins and as large fractions of that new consumption are necessarily supplied from unstable parts of the world, the inevitable repercussions on petroleum-driven economies will continue to escalate. In addition, there is an unequivocal imperative to take immediate and aggressive measures to reduce net greenhouse gas emissions by decreasing fossil fuel consumption and increasing our use of carbon-neutral or carbon-negative fuels as well as improving efficiency of fuel use. Economic growth and development worldwide depend increasingly on secure supplies of reliable, affordable, clean energy. Together with its counterpart societies, was convened the First Pan-American Congress on Plants and BioEnergy, which was held in June, 2008, in Mérida, Mexico. Sponsored by the American Society of Plant Biologists, this congress was designed to initiate Pan-American research collaborations in energy biosciences. At that congress, the organizational committee committed themselves to continue the meeting biennially, resulting in the 2nd Pan-American Congress on Plants and BioEnergy to be held with the endorsement of ASPB, July 6-10, 2010, in São Paulo, Brazil. Whereas the 1st congress covered a broad range of topics that bioenergy impacted, the second congress will focus more on the advances in plant biology: the genetic improvement of energy crop plants, their fit into regional environments, and the development of a sustainable energy agriculture.




Environmentally Benign Photocatalysts


Book Description

Over the past few decades, mankind has observed an unprecedented and remarkable growth in industry, resulting in a more prosperous lifestyle for peoples of many countries. In developing countries, however, explosive industrial growth is just now beginning to raise the living standards of the people. Most industries, especially in these developing countries, are still powered by the burning of fossil fuels; con- quently, a lack of clean energy resources has caused environmental pollution on an unprecedented large and global scale. Toxic wastes have been relentlessly released into the air and water leading to serious and devastating environmental and health problems while endangering the planet and life itself with the effects of global warming. To address these urgent environmental issues, new catalytic and photocatalytic processes as well as open-atmospheric systems are presently being developed that can operate at room temperature while being totally clean and ef?cient and thus environmentally harmonious. Essential to technologies harnessing the abundant solar energy that reaches the earth are the highly functional photocatalytic proce- es that can utilize not only UV light, but also visible light.




Introduction to Green Chemistry


Book Description

The book covers traditional green chemistry topics, including catalysis, benign solvents, and alternative feedstocks. It also discusses relevant but less frequently covered topics with chapters such as Chemistry of Longer Wear and Population and the Environment. This coverage highlights the importance of chemistry to everyday life and demonstrates the benefits the expanded exploitation of green chemistry can have for society. Copiously illustrated with over 800 figures, this second edition provides an update from the frontiers of the field.




Environmental Catalysis


Book Description

The study of environmental interfaces and environmental catalysis is central to finding more effective solutions to air pollution and in understanding of how pollution impacts the natural environment. Encompassing concepts, techniques, and methods, Environmental Catalysis provides a mix of theory, computation, analysis, and synthesis to support the




Natural Polyphenols from Wood


Book Description

Natural Polyphenols from Wood: Tannin and Lignin – An Industrial Perspective is a detailed guide to the sourcing and processing of tannin and lignin for valuable advanced applications across areas such as fuels, chemicals, drugs, and food. Drawing on the latest academic research and patent literature, this book provides strong practical understanding of the use of these valuable materials in novel industrial applications. This book introduces natural polyphenols from wood and the fundamental aspects of carbon management within the tree. In-depth presentation of extraction and characterization methods is followed by an extensive coverage of practical and industrial applications of wood polyphenols. This is an essential resource for researchers and advanced students working with lignin or tannin, and across biopolymer science, biomass, wood chemistry, paper, wood adhesives, polymer materials, renewable resources, and biotechnology. It also supports industrial R&D and scientists working with wood polyphenols or bio-based polymers. - This book re-evaluates wood polyphenols from an industrial perspective, revealing the latest techniques and drawing on patent literature. - It addresses fundamental issues of wood polyphenols, such as carbon cycle, wood fractionation, structure, and properties. - It offers a comprehensive review of practical applications, including lignin depolymerization, wood reconstruction, fuels, chemicals, drugs, and food.




Frontiers of Green Catalytic Selective Oxidations


Book Description

The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.




Green Chemistry in Industry


Book Description

The “greening” of industry processes, i.e. making them more sustainable, is a popular and often lucrative trend which has emerged over recent years. The 3rd volume of Green Chemical Processing considers sustainable chemistry in the context of corporate interests. The American Chemical Society’s 12 Principles of Green Chemistry are woven throughout this text as well as the series to which this book belongs.




Fuels, Chemicals and Materials from the Oceans and Aquatic Sources


Book Description

Fuels, Chemicals and Materials from the Oceans and Aquatic Sources provides a holistic view of fuels, chemicals and materials from renewable sources in the oceans and other aquatic media. It presents established and recent results regarding the use of water-based biomass, both plants and animals,for value-added applications beyond food. The book begins with an introductory chapter which provides an overview of ocean and aquatic sources for the production of chemicals and materials. Subsequent chapters focus on the use of various ocean bioresources and feedstocks, including microalgae, macroalgae, and waste from aquaculture and fishing industries, including fish oils, crustacean and mollusc shells. Fuels, Chemicals and Materials from the Oceans and Aquatic Sources serves as a valuable reference for academic and industrial professionals working on the production of chemicals, materials and fuels from renewable feedstocks. It will also prove useful for researchers in the fields of green and sustainable chemistry, marine sciences and biotechnology. Topics covered include: • Production and conversion of green macroalgae • Marine macroalgal biomass as an energy feedstock • Microalgae bioproduction • Bioproduction and utilization of chitin and chitosan • Applications of mollusc shells • Crude fish oil as a potential fuel