Processing and Properties of Liquid Crystalline Polymers and LCP Based Blends


Book Description

Some papers in this book report on the most recent developments in pure liquid crystalline polymers showing that discipline is dynamic and may offer in the future numerous other opportunities not known today. We hope that our selections of papers will be interesting for specialists in polymer chemistry, blends, and their industrial application, and that information included in this book will be stimulating and will favorably impact research currently performed by the readers of this book.




High Temperature Polymer Blends


Book Description

Polymer blends offer properties not easily obtained through the use of a single polymer, including the ability to withstand high temperatures. High Temperature Polymer Blends outlines the characteristics, developments, and use of high temperature polymer blends. The first chapter introduces high temperature polymer blends, their general principles, and thermodynamics. Further chapters go on to deal with the characterization of high temperature polymer blends for specific uses, such as fuel cells and aerospace applications. The book discusses different types of high temperature polymer blends, including liquid crystal polymers, polysulfones, and polybenzimidazole polymer blends and their commercial applications. High Temperature Polymer Blends provides a key reference for material scientists, polymer scientists, chemists, and plastic engineers, as well as academics in these fields. - Reviews characterization methods and analysis of the thermodynamic properties of high temperature polymer blends - Reviews the use of materials such as liquid crystals as reinforcements as well as applications in such areas as energy and aerospace engineering




Advances in Thermotropic Liquid Crystal Polymers


Book Description

Annotation Liquid crystal polymers are sometimes called super polymers--with good reason. Their wide range of exceptional properties and ease of processing make them design candidates for many demanding applications. This new book provides a thorough review of LCP technology with the emphasis on the chemistry, synthesis and characterization of the material in its many variants. Additional chapters cover processing and applications. From the Editor's Preface The field of thermotropic liquid crystalline polymers has grown substantially in the last two decades, with fundamental research, publications, commercial products, and patents. In the 1980's, Dr. Ralph Miano led my colleagues and me at Hoechst Celanese in commercializing the first thermotropic liquid crystalline polymers, based on Dr. Gordon Calundann's composition patents. Today, more than seven companies have produced thermotropic liquid crystalline polymer materials, with at least 50 variants available. Hence, it is timely to compile a comprehensive review on the nature of this type of material and the ongoing progress in this field€. The goals of this book are to summarize previous work, provide new insights into this class of polymers, and add to the understanding of the formation of liquid crystallinity. This book covers a wide range of topics and addresses different disciplines in the field. The chapters are arranged as a learning scheme for the professional, from basic science to applied engineering. The first few chapters summarize the syntheses of various polyester, polyester-amid, and polyimide liquid crystalline polymers. The science and origins of liquid crystal formation are revealed. Next, we introduce the characterizations of these materials by their different chemical and physical aspects. Because most commercially available thermotropic liquid crystalline polymers have been used in the form of composites, we have also incorporated a chapter on polymer blends, detailing blending mechanisms and resultant properties. Two chapters on thermosetting liquid crystalline polymers integrate them with other topics, because of their unique importance and their applications for microelectronics and packaging. The final chapter deals with the engineering and processing aspects of thermoplastic liquid crystalline polymers for a variety of applications.




Rheology and Processing of Liquid Crystal Polymers


Book Description

Liquid crystal polymers (LCPs) have many strange properties that may be utilized to advantage in the processing of products made from them and their blends with isotropic polymers. This volume (volume 2 in the series Polymer Liquid Crystals) deals with their strange flow behaviour and the models put forward to explain the phenomena that occur in such polymers and their blends. It has been known for some time that small ad ditions of a thermotropic LCP to isotropic polymers not only gives an improvement in the strength and stiffness of the blend but improves the processability of the blend over that of the isotropic polymer. In the case of lyotropic LCPs, it is possible to create a molecular composite in which the reinforcement of an isotropic polymer is achieved at a molecular level by the addition of the LCP in a common solvent. If the phenomena can be fully understood both the reinforcement and an increase in the proces sability of isotropic polymers could be optimized. This book is intended to illustrate the current theories associated with the flow of LCPs and their blends in the hope that such an optimization will be achieved by future research. Chapter 1 introduces the subject of LCPs and describes the ter minology used; Chapter 2 then discusses the more complex phenomena associated with these materials. In Chapter 3, the way in which these phe nomena may be modelled using hamiltonians is fully covered.




Mechanical and Thermophysical Properties of Polymer Liquid Crystals


Book Description

may never overcome the effects of hysteresis and stress (see Chapters 6 and 12). The first sentence of the reference work, Handbook of Liquid Crystals, reads: The terms liquid crystals, crystalline liquid, mesophase, and mesomorphous state are used synonymously to describe a state of aggregation that exhibits a molecular order in a size range similar to that of a crystal but acts more or less as a viscous liquid: [2] In other words, molecules within a liquid crystalline phase possess some orientational order and lack positional order; furthermore, the shape of a liquid crystalline sample is determined by the vessel in which it is contained rather than by the orientational order of its aggregated molecules. The authors recognized the limitations and imprecision of this definition but, like others preceding them, could not devise a simple and generally applicable one that is better. Regardless, the terms 'liquid crystal' and 'mesophase' should not be used interchangeably. As mentioned above, all liquid crystals are mesophases, but all mesophases are not liquid crystals. Recent studies, employing elaborate and sophisticated analytical techniques, have permitted finer distinctions between classical crystals and mesophases. At the same time, they have made definitions like that from the Handbook of Liquid Crystals somewhat obsolete for reasons other than terminology. One part of the problem arises from the use of a combination of bulk properties (like flow) and microscopic properties (like molecular ordering) within the same definition.




Rheology of Polymer Blends and Nanocomposites


Book Description

Rheology of Polymer Blends and Nanocomposites: Theory, Modelling and Applications focuses on rheology in polymer nanocomposites. It provides readers with a solid grounding in the fundamentals of rheology, with an emphasis on recent advancements. Chapters explore potential future applications for nanocomposites and polymer blends, giving readers a thorough understanding of the specific features derived from rheology as a tool for the study of polymer blends and nanocomposites. This book is ideal for industrial and academic researchers in the field of polymer blends and nanocomposites, but is also a great resource for anyone who wants to learn about the applications of rheology. - Sets out the principles of rheology as it is applied to polymer blends and nanocomposites - Demonstrates how rheological techniques are best applied to different classes of nanocomposites - Assesses the opportunities and major challenges of rheological approaches to polymer blends and nanocomposites




Liquid Crystalline Polymers


Book Description

This book introduces various applications of liquid crystalline polymers as the emerging new class of high performance novel materials. The authors detail the advantageous properties of these LCs including optical anisotropic, transparency and easy control over structure. This interdisciplinary work includes valuable input from international projects with special focus on the use of liquid crystalline polymers and/or nanocomposites.







Science and Technology of Polymers and Advanced Materials


Book Description

This book summarizes the state ofthe art research presented at the Fourth International Conference on Frontiers of Polymersand Advanced Materialsheld in Cairo, Egypt in January 4-9, 1997. This conference follows the successful conferences held in Kuala Lumpur, Malaysia in 1995, in Jakarta, Indonesia in 1993 andin New Delhi, India in 1991. These conferences focussed on the most recent and important advances in a wide range of carefully chosen subject areas dealing with advanced materials, their science and technology and new business opportunities resulting from recent technological advances. As its predecessors, the conference held in Cairo was truly international with strong participation of 488 deiegales representing 37 countries from the USA and Egypt, as weil as Europe, South East Asia, Japan, South Africa and the Middle East. The conference was organized by the Egyptian Academy of Scientific Research and Technology, The Arab Society ofMaterials Science and the State University ofNew Y ork at Butfalo. The stated goals ofthe conference were: • To highlight advances and new. findings in the general area of polymers and advanced materials. - • T o foster global collaboration between the USA, Egypt and other nations in the general field of polymers and advanced materials. • To promote the development of scientific ilifrastructure in this field among the different participating countries, especially in the Middle East. • To create a basisforfuture long-term scientific exchanges between the USA and Egypt, and/or other countries.




Liquid Crystalline Polymers


Book Description

A 2006 edition explaining the underlying science and applications of liquid crystalline polymers.